含氮、磷有机配体对(CdSe)_2量子点结构和电子性质的影响

使用密度泛函理论方法研究了量子点(CdSe)2与配体L(L=PH3、PH2Me、PHMe2、PMe3、NH3、NH2Me、NHMe2、NMe3)之间的相互作用及其产物的结构和性质。配体中的P或N原子与Cd原子上分别形成较强的Cd—P和Cd—N配位键,从而影响(CdSe)2的结构和电子性质。配体作用下,(CdSe)2的几何结构、电荷分布、轨道能级、吸收光谱等均发生变化,但2类配体的影响,尤其是甲基数目的影响,存在较大差异。     

家长式领导风格对组织变革影响研究

领导风格理论受到越来越多国内外学者的关注,家长式领导风格理论受到本土学者的认可和华人企业的重视,本文在基于学者对家长式领导风格理论研究的基础上,通过问卷调查的形式,实证研究了家长式领导风格对组织变革的影响,最终得出结论：家长式风格中的权威领导对文化多样性具有显著的负向预测效果;仁慈领导对风险创新性、动态整合性和文化多样性具有显著的正向预测效果。这一结论可在实践中为中国企业进行组织变革提供管理咨询的建议。     

Engineering all-aromatic polyamide surface from hydrophilic to superhydrophobic and the accelerated strategy

Being a new kind of nanomaterials, aromatic polyamide nanofibers (ANF) have been much highlighted in recent studies. We here demonstrate an isopropyl alcohol (IPA) accelerated chemical cleavage on poly (p-phenylene terephthalamide) chopped fibers, which provides an efficient preparation method of ANF. The comprehensive study on the processes accelerated by different alcohols revealed that the preparation time of ANF in the mixed medium of dimethyl sulfoxide (DMSO)-alcohol (20:1 in volume) was shorten to 45 min and 75 min for methanol (ethanol) and isopropanol, respectively. However, the nanofibers prepared in DMSO-IPA exhibited the minimum in axial and radial dimensions, providing the finest and most uniform diameter of 16 nm. The corresponding ANF films through vacuum assisted filtration also showed the highest tensile strength of 150 MPa, in comparison with those of the ANF films prepared using other alcohols, which were about 110 MPa. Furthermore, ANF/silicon hybrid films were prepared by the ionic ring-opening reaction followed by the alkoxysilane condensation and nanoparticle fabrication. By changing the organo functional groups in the alkoxysilane, the surface of the films were adjustable in a wide contact angle range from 56° (hydrophilic) to 150° (superhydrophobic), suggesting the amendable interfacial properties potential applicable to composite fabrication with most of the resin matrix.     

医用钴基合金的组织结构及耐腐蚀性能

以锻造CoNiCrMo，CoCrMo和CoCrMoC台会为研究对象，通过金相观察，XRD分析和耐腐蚀试验，研究了3组合金在不同热处理条件下的显微结构，相成分及在Hi同溶液中的耐腐蚀性能。结果表明：2组锻造合金的再结晶温度都是1000℃，且晶粒尺寸随着固溶温度升高和时效时间延长而逐渐变大。3组试样在NaCl溶液中为钴基合金典型的阳极极化曲线；在Hanks’溶液中均有一个二次钝化行为，且锻造CoNiCrMo合金的二次钝化区域较窄，而其他2组合金则较宽；在含柠檬酸三钠的溶液中过钝化电位降低，柠檬酸盐的存在降低了含金的耐腐蚀性能。热处理对合金的耐腐蚀性能影响不大。     

Formation and thermal stability of amorphous Ni-Mo-P alloys

The experimental researches on the chemical deposition of Ni-Mo-P amorphous alloys were carried out by adding Na2 MoO4 into acidic solutions. The optimum technology conditions were obtained by orthogonal design experiments. The structures and the relationship between compositions and their thermal stability were studied by energy spectrum (EC), scanning electron micrograph and X-ray diffraction spectrum. Compared with Ni-P amorphous alloys, the Ni-Mo-P amorphous alloys have high crystallization temperature and thermal stability, and the hardness reaches its peak when the annealing temperature is 500 ℃. With the increase of the heat treatment temperature, the surface morphology of the alloys changes.     

一种新型气硬冷芯盒树脂砂工艺试验及其在生产中的应用

原砂加入2．5％水溶性酚醛树脂，固化剂为甲酸甲脂，加入量占树脂的30％～40％。先把甲酸甲脂在气体发生器中气化，然后再与40％的压缩空气混合，吹气硬化制芯，最高抗拉强度1．2MPa，抗压强度0．32MPa，发气量12mL／g。生产浇注试验表明：砂芯表面光洁，轮廓清晰，尺寸精确，铸件缺陷少，无毒或低毒，和一般冷硬树脂砂比较，成本降低30％。     

表面氧化层对TiMn1.25Cr0.25储氢合金活化性能的影响

通过TiMn1.25Cr0.25合金粉活化前在空气中暴露不同的时间,探讨了表面氧化层的形成对其活化性能的影响。活化测试结果表明：合金的活化难度随着合金在空气中暴露时间的延长而加大。俄歇电子能谱(AES)结果表明,在空气中暴露后的合金表面形成了一层大约6nm-10nm厚的表面氧化层,正是这层氧化层的形成加大了合金的活化难度。扫描电镜(SEM)结果表明合金的活化过程与合金的碎化有着密切的联系。     

Multifocus image fusion method of Ripplet transform based on cycle spinning

The curvelet transform can represent images at both different scales and different directions. Ripplet transform, as a higher dimensional generalization of the curvelet transform, provides a new tight frame with sparse representation for images with discontinuities along C² curves. However, the ripplet transform is lack of translation invariance, which causes the pseudo-Gibbs phenomenon on the edges of image. In this paper, the cycle spinning method is adopted to suppress the pseudo-Gibbs phenomena in the multifocus image fusion. On the other hand, a modified sum-modified-laplacian rule based on the threshold is proposed to make the decision map to select the ripplet coefficient. Several experiments are executed to compare the presented approach with other methods based on the curvelet, sharp frequency localized contourlet transform and shearlet transform. The experiments demonstrate that the presented fusion algorithm outperforms these image fusion works.     

一种内嵌导磁槽的圆感应同步器

圆感应同步器是一种高精度角度传感器,传统的圆感应同步器的转子需外引激励线以驱动其工作,鉴于圆感应同步器在使用过程中需要连续旋转,这将使得外引激励线存在绞线的问题,本文提出一种新的设计方法,在圆感应同步器的定、转子基体上嵌有环状的金属导磁槽,导磁槽内放入环状金属导线.通过给定子导磁槽内的环状金属导线施加激励信号,此激励信号可耦合到转子导磁槽内的环状金属导线中以驱动转子工作,这使得转子无需外引激励线,进而提高了系统应用的便利性以及可靠性.     

网络机房的故障诊断与排除

目前,计算机网络课程已成为职业院校各专业的必修课。为了加强实践教学,培养实用型人才,网络机房使用的频率越来越高,随之产生的故障也越来越多。只有通过机房管理员及时发现故障,准确定位故障,彻底排除故障,才能延长网络机房使用寿命,确保实践教学高效、顺利进行。本文从实践出发,分析了网络机房的故障、原因、诊断和排除。此外,本文还介绍了网络常用命令和仪器。