Three-dimensional core-shell hybrid solar cells via controlled in situ materials engineering

Three-dimensional core-shell organic-inorganic hybrid solar cells with tunable properties are demonstrated via electropolymerization. Air-stable poly(3,4-ethylenedioxythiophene) (PEDOT) shells with controlled thicknesses are rapidly coated onto periodic GaAs nanopillar arrays conformally, preserving the vertical 3D structure. The properties of the organic layer can be readily tuned in situ, allowing for (1) the lowering of the highest occupied molecular orbital level (|ΔE| ～ 0.28 eV), leading to the increase of open-circuit voltage (V(OC)), and (2) an improvement in PEDOT conductivity that results in enhanced short-circuit current densities (J(SC)). The incorporation of various anionic dopants in the polymer during the coating process also enables the tailoring of the polymer/semiconductor interface transport properties. Systematic tuning of the device properties results in a J(SC) of 13.6 mA cm(-2), V(OC) of 0.63 V, peak external quantum efficiency of 58.5%, leading to a power conversion efficiencies of 4.11%.     

Variability of intact rock mechanical properties for some metamorphic rock types and its implications on the number of test specimens

Intact rock strength and stiffness properties are commonly used in rock mass mechanical characterization, and their evaluation is usually based on laboratory tests. Due to the variability that affects strength and stiffness parameters, the determination of the number of laboratory-tested specimens required to obtain a reliable reference value is very useful. However, many studies reported in apposite literature focused only on the variability of strength parameters. This study investigates the variability of some of the most important strength and stiffness properties (unconfined compressive strength, indirect tensile strength, tangent and secant Young’s moduli, Poisson’s ratio) by applying statistical methods (statistical decision theory and statistical inference theory). A data set of 451 laboratory tests was used, performed on three rock types. The statistical analyses were applied with the aim of assessing how closely intact rock laboratory data follow a normal distribution and determining the minimum number of specimens required to obtain a reliable average value of the parameters in relation to a targeted precision index for a confidence level of 95 %. The results indicate that the minimum number of samples needed varies depending on rock and test types. Among the stiffness properties, tangent Young’s modulus has a lower variability than both the secant modulus and the Poisson’s ratio, whereas in terms of strength parameters, unconfined compressive strength is subject to greater variability than indirect tensile strength.     

Innovative lay-up system in plywood manufacturing process

In the traditional plywood manufacturing process, the lay-up stage absorbs approximately 24% of the total manufacturing costs. It usually requires a large amount of manpower and produces a significant amount of waste material. Therefore, the authors have developed an innovative system based on a new idea that reduces these values drastically. The solution is characterized by intensive use of flexible automation, and this breakthrough lay-up system technology is specifically discussed in relation to plywood manufacture. Since the new system was tested, it has been adopted and used by the European leader in poplar plywood manufacturing. Interesting results include productivity increases of up to 20%, a decrease in lay-up costs of approximately 19% and a consumption of area reduced about 42%. Moreover, by reducing manpower requirements, the new system generates a significant reduction in the number of problems relating to product quality and operator safety, which is certainly not a trivial question in the traditional lay-up system.     

Saliva improves Streptococcus mitis protective effect on human gingival fibroblasts in presence of 2-hydroxyethyl-methacrylate

This study aimed to investigate the effect of saliva on Streptococcus mitis free cells and on S. mitis/human gingival fibroblasts (HGFs) co-culture model, in presence of 2-hydroxyethyl-methacrylate (HEMA). The bacterial aggregation both in the planktonic phase and on HGFs, as well as the apoptotic and necrotic eukaryotic cells amount were analyzed, in presence of saliva and/or HEMA. The aggregation test revealed a significant saliva aggregation effect on S. mitis strains compared to the untreated sample. No significant differences were recorded in the amount of culturable bacteria in all studied conditions; however, from microscopy images, the saliva/HEMA combining effect induced a significant bacterial aggregation and adhesion on HGFs. HEMA treatment decreased viable eukaryotic cell number with a parallel increment of necrotic cells, but when saliva was added to the co-culture, the viable cells percentage increased to a value comparable to the control sample.     

Composition of meat and offal from weaned and fattened rabbits and results of stereospecific analysis of triacylglycerols and phosphatidylcholines

BACKGROUND: Rabbit meat has excellent nutritive properties. The purpose of this study was to characterize rabbit meat and offal; in particular, the lipid fraction was studied in order to evaluate total and positional fatty acid (FA) compositions of triacylglycerol (TAG) and phosphatidylcholine (PC) fractions. Eight samples of weaned and eight of fattened rabbits were considered. RESULTS: Fattened rabbit meat contained slightly higher protein percentage content (P < 0.05) in comparison to weaned (20.1% versus 18.0%). Calcium content was higher in meat than in offal, unlike sodium, iron, zinc, manganese and copper. The cholesterol content in offal was much higher than in meat. FA profiles of total lipid showed a high percentage of unsaturated fatty acids and an n‐6/n‐3 ratio of 10.3 for fattened rabbit meat. Stereospecific analysis of TAG and PC was carried out on an eight‐sample pool of each meat and offal from weaned and fattened rabbits. In all samples the sn‐2‐position was prevalently esterified with oleic and linoleic acids in TAG, with polyunsaturated fatty acids in PC. CONCLUSION: Lipids from rabbit meat presented higher content of monounsaturated FA and lower n‐6/n‐3 ratio in comparison to offal, which was characterized by higher cholesterol and mineral levels. Copyright © 2011 Society of Chemical Industry     

Patterned radial GaAs nanopillar solar cells

Photovoltaic devices using GaAs nanopillar radial p-n junctions are demonstrated by means of catalyst-free selective-area metal-organic chemical vapor deposition. Dense, large-area, lithographically defined vertical arrays of nanowires with uniform spacing and dimensions allow for power conversion efficiencies for this material system of 2.54% (AM 1.5 G) and high rectification ratio of 213 (at ±1 V). The absence of metal catalyst contamination results in leakage currents of ～236 nA at -1 V. High-resolution scanning photocurrent microscopy measurements reveal the independent functioning of each nanowire in the array with an individual peak photocurrent of ～1 nA at 544 nm. External quantum efficiency shows that the photocarrier extraction highly depends on the degenerately doped transparent contact oxide. Two different top electrode schemes are adopted and characterized in terms of Hall, sheet resistance, and optical transmittance measurements.