Les phases SrLa2Al2O7 et SrGd2Al2O7

SrLa₂Al₂O₇ and SrGd₂Al₂O₇ belong to the structural type Sr₃Ti₂O₇. In SrGd₂Al₂O₇ strontium and gadolinium occupy respectively the 12 and 9 coordinated sites, whereas in SrLa₂Al₂O₇ the homologous cations are statistically distributed. The fluorescence spectra of both phases activated by Eu³⁺ ions show that the only possible position of Eu³⁺ is the 9 coordinated site.     

Resonator stability subject to dynamic random-tilt aberration

We derive the behavior of the average exit time (i.e., the number of reflections before escape) of a ray path traveling between two perfect mirrors subject to dynamic random-tilt aberrations. Our calculation is performed in the paraxial approximation. When small random tilts are taken into account, we may consider an asymptotic regime that generically reduces the problem to the study of the exit time from an interval for a harmonic, frictionless oscillator driven by Gaussian white noise. Despite its apparent simplicity, the exact solution of this problem remains an open mathematical challenge, and we propose here a simple approximation scheme. For flat mirrors, the natural frequency of the oscillator vanishes, and, in this case, the average exit time is known exactly. It exhibits a 2/3 scaling-law behavior in terms of the variance of the random tilts. This behavior also follows from our approximation scheme, which establishes the consistency of the scaling law. Our mathematical results are confirmed with simulation experiments.     

Long-range detection and length estimation of light filaments using extra-attenuation of terawatt femtosecond laser pulses propagating in air

High-energy femtosecond laser pulses propagating in the atmosphere undergo self-focusing resulting in the appearance of the phenomenon of filamentation. We observed an extra-attenuation of such (terawatt) femtosecond laser pulses propagating in the atmosphere when compared with long pulses (200 ps) with the same energy. This is because, in contrast to the linear propagation of the long pulse, the input femtosecond laser pulse is attenuated owing to either absorption through multiphoton ionization/tunnel ionization or to scattering on the laser-induced plasma; self-phase-modulation and self-steepening further convert partially the energy initially contained in the fundamental bandwidth into the broad side bands of the laser, becoming eventually a white-light laser pulse (supercontinuum). The experimental data allow us to extract an effective extra-attenuation coefficient for an exponential decay of the input pulse energy with the propagation distance. Such a coefficient allows us to estimate an upper bound of the filament length under the experimental conditions used. More generally, our observation leads to a new technique to remotely detect light filaments in the atmosphere.     

Crystal growth of bullet-shaped magnetite in magnetotactic bacteria of the Nitrospirae phylum

Magnetotactic bacteria (MTB) are known to produce single-domain magnetite or greigite crystals within intracellular membrane organelles and to navigate along the Earth''s magnetic field lines. MTB have been suggested as being one of the most ancient biomineralizing metabolisms on the Earth and they represent a fundamental model of intracellular biomineralization. Moreover, the determination of their specific crystallographic signature (e.g. structure and morphology) is essential for palaeoenvironmental and ancient-life studies. Yet, the mechanisms of MTB biomineralization remain poorly understood, although this process has been extensively studied in several cultured MTB strains in the Proteobacteria phylum. Here, we show a comprehensive transmission electron microscopy (TEM) study of magnetic and structural properties down to atomic scales on bullet-shaped magnetites produced by the uncultured strain MYR-1 belonging to the Nitrospirae phylum, a deeply branching phylogenetic MTB group. We observed a multiple-step crystal growth of MYR-1 magnetite: initial isotropic growth forming cubo-octahedral particles (less than approx. 40 nm), subsequent anisotropic growth and a systematic final elongation along [001] direction. During the crystal growth, one major {111} face is well developed and preserved at the larger basal end of the crystal. The basal {111} face appears to be terminated by a tetrahedral–octahedral-mixed iron surface, suggesting dimensional advantages for binding protein(s), which may template the crystallization of magnetite. This study offers new insights for understanding magnetite biomineralization within the Nitrospirae phylum.     

Multistability of signal transduction motifs

Protein domains are the basic units of signalling processes. The mechanisms they are involved in usually follow recurring patterns, such as phosphorylation/dephosphorylation cycles. A set of common motifs was defined and their dynamic models were analysed with respect to number and stability of steady states. In a first step, Feinberg's chemical reaction network theory was used to determine whether a motif can show multistationarity or not. The analysis revealed that, apart from double-step activation motifs including a distributive mechanism, only those motifs involving an autocatalytic reaction can show multistationarity. To further characterise these motifs, a large number of randomly chosen parameter sets leading to bistability was generated, followed by a bifurcation analysis of each parameter set and a statistical evaluation of the results. The statistical results can be used to explore robustness against noise, pointing to the observation that multistationarity at the single-motif level may not be a robust property; the range of protein concentrations compatible with multistationarity is fairly narrow. Furthermore, experimental evidence suggests that protein concentrations vary substantially between cells. Considering a motif designed to be a bistable switch, this implies that fluctuation of protein concentrations between cells would prevent a significant proportion of motifs from acting as a switch. The authors consider this to be a first step towards a catalogue of fully characterised signalling modules.     

SMC composites waste management as reinforcing fillers in polypropylene by combination of mechanical and chemical recycling processes

A new process of management of waste of composite materials from Sheet Moulding Compounds (SMC), as reinforcing fillers for thermoplastic materials, including both mechanical and chemical processes is proposed in this paper. Communited SMC being composed of coated glass fibres intimately mixed with calcium carbonate powder, their reinforcing power is low. First, the fibrous part was increased by partial dissolution of calcium carbonate present in the crushed products SMC. Second, a process of partial solvolysis was developed aiming at strong increasing the interfacial mechanical properties by functionalising of SMC load incorporated into polypropylene/grafted maleic anhydride polypropylene (PP/PP_gma). At this effect, we investigated a treatment with a hot triamine (diethylenetriamine, DETA) in order to create a functionalisation, after scission of the bond ester of unsaturated polyester, as bridging amino-succinimide.The effect of this recycling way by partial solvolysis was checked from the mechanical properties of the resulting reinforced PP/PP_gma material: Although a lower of Young modulus, better yield stress and especially resilience were observed.     

A Computational Damage Micromodel of Laminated Composites

A new computational damage micromodel for laminates, which takes into account classical experimental micro- and macro-observations for various stacking sequences, is described. The first computational examples are shown.     

Multigrid preconditioned conjugate-gradient method for large-scale wave-front reconstruction

We introduce a multigrid preconditioned conjugate-gradient (MGCG) iterative scheme for computing open-loop wave-front reconstructors for extreme adaptive optics systems. We present numerical simulations for a 17-m class telescope with n = 48756 sensor measurement grid points within the aperture, which indicate that our MGCG method has a rapid convergence rate for a wide range of subaperture average slope measurement signal-to-noise ratios. The total computational cost is of order n log n. Hence our scheme provides for fast wave-front simulation and control in large-scale adaptive optics systems.