An <Emphasis Type="Italic">ex post</Emphasis> criticism,based on stakeholders’ preferences,of a residential sector’s energy master plan: the case study of the Sicilian region

Energy master plans are important tools for an effective and sustainable land governance. On the other hand, the stakeholder role in setting priorities for planning energy interventions is dramatically increasing, also in the light of recently issued European directives. The priorities of energy-saving measures of the Sicilian energy and environmental master plan were originally established with the application of typical economic indicators (the cost of saved energy and the cost of avoided pollutant emissions). During the prioritization process, there was a minor contribution from stakeholders who were not directly involved in the priority-setting process but were only asked to express their opinions according to the in-force regulations. Based on more active stakeholder involvement in hierarchizing a given set of actions, as required by the recently issued directives, the University of Palermo, which participated in the development of this master plan, assessed an ex post evaluation of these established economy-based priorities, by means of the application of a multi-criteria decision analysis (MCDA) tool. The resulting changed priorities, which lead to a better policy allocation of the regional budget for energy efficiency in the building sector, confirm the preeminent role played by the stakeholders in the development of energy plans, further supported by a sensitivity analysis.     

Polycyclic aromatic hydrocarbons in frying oils and snacks

The high incidence of lung cancer observed among Chinese women has been associated with exposure to fumes from cooking oil. Polycyclic aromatic hydrocarbons (PAHs) are a class of potentially mutagenic substances emitted from cooking oils heated at high temperatures. The objective of this study was to investigate whether deep frying with different oils under different conditions leads to the development of PAHs either in the oil or in the fried product (snacks). PAH analysis was carried out with solid-phase extraction followed by reverse-phase high-performance liquid chromatography and spectrofluorometric detection. Different oils were used to fry chips and extruded snacks in different industrial plants (continuous frying) at temperatures between 170 and 205 degrees C, and peanut oil was used to fry French fries and fish (discontinuous frying) at temperatures between 160 and 185 degrees C. No appreciable differences in PAH load was observed in the same oil before and after frying. Both before and after frying, the benzo[a]pyrene concentration in oils ranged from trace to 0.7 ppb. All the analyzed samples, including oils from fried snacks, had benzo[a]pyrene concentrations well below the 2 ppb limit recently proposed by the European Community.     

Functionalized carbon nanotubes are non-cytotoxic and preserve the functionality of primary immune cells

Carbon nanotubes are emerging as innovative tools in nanobiotechnology. However, their toxic effects on environment and health have become an issue of strong concern. In the present study, we address the impact of functionalized carbon nanotubes (f-CNTs) on cells of the immune system. We have prepared two types of f-CNTs, following the 1,3-dipolar cycloaddition reaction (f-CNTs 1 and 2) and the oxidation/amidation treatment (f-CNTs 3 and 4), respectively. We have found that both types of f-CNTs are uptaken by B and T lymphocytes as well as macrophages in vitro, without affecting cell viability. Subsequently, the functionality of the different cells was analyzed carefully. We discovered that f-CNT 1, which is highly water soluble, did not influence the functional activity of immunoregulatory cells. f-CNT 3, which instead possesses reduced solubility and forms mainly stable water suspensions, preserved lymphocytes' functionality while provoking secretion of proinflammatory cytokines by macrophages.     

Effect of cross sectional shape during condensation in a single square minichannel

The objective of this work is to present new condensation heat transfer coefficients measured inside a single square cross section minichannel, having a 1.18 mm side length, and compare them to the ones previously measured in a circular minichannel. Tests have been performed with R134a at 40 °C saturation temperature, at mass velocity ranging between 200 and 800 kg m^?2 s^?1. As compared to the heat transfer coefficients measured in the circular cross section channel, for the same hydraulic diameter, in the square minichannel the authors find a heat transfer enhancement at the lowest value of mass velocity, which must be due to the effect of surface tension. No heat transfer coefficient increase has been found at the highest values of the mass velocity where condensation is shear stress dominated.     

Iodine Value and Fatty Acids Determination on Pig Fat Samples by FT-NIR Spectroscopy: Benefits of Variable Selection in the Perspective of Industrial Applications

In this work, FT-NIR spectroscopy was employed to determine iodine value (IV) and fatty acids (FA) content of pig fat samples, through the combined use of signal preprocessing, multivariate calibration, and variable selection methods. In particular, the main focus was on the use of variable selection methods, both in order to improve the predictive performance of the calibration models, and to identify relevant wavelengths that could be subsequently used for the development of simple, fast, and cheap hand-held devices, able to measure IV and FA content directly on the fat without the need of any sample pretreatment. Firstly, for each property of interest, partial least squares (PLS) multivariate calibration models were calculated considering the whole spectral range and testing different signal preprocessing methods. Then, once chosen the optimal signal preprocessing method, a two-step variable selection procedure was applied. In the first step, the interval-PLS variable selection algorithm was used to calculate a set of calibration models, whose outcomes were considered altogether in the second step, in order to select the optimal calibration model. The variable selection procedure allowed to lower the number of spectral variables retained by the model, and often led to an increase of the performance in prediction of the external test set samples.     

Determination of plasticisers and BPA in Sicilian and Calabrian nectar honeys by selected ion monitoring GC/MS

Twenty-six plasticisers and bisphenol A (BPA) in 39 Sicilian and Calabrian nectar honeys of different botanical south Italian origin were determined by GC-MS. Di-(2-ethylhexyl)phthalate was the most abundant plasticiser in all samples, reaching up 202.7 ± 153.1 µg kg^–1, followed by di-butylphthalate with a concentration of 40.3 ± 9.3 µg kg^–1, whereas the concentration of the other phthalates varied from not detectable to 68.2 µg kg^–1. Trace levels of adipate, sebacate and BPA were not detected in any samples. Among the different floral origin honeys, di-ethylphthalate levels were above the limit of quantification (LOQ) in orange blossom, wildflower and chestnut honey samples. Among the honeys of different geographical origin, di-methylphthalate, di-butylphthalate and di-(2-ethylhexyl)phthalate concentrations were similar. Calabrian honeys showed levels of di-ethylphthalate always lower than the LOQ, moreover di-(2-methylpropyl)phthalate levels were lower than the Sicilian ones. On the contrary, in Sicilian honeys di-(2-methylpropyl)phthalate levels were higher and di-ethylphthalate was present in 37% of samples.     

Flow Boiling of R245fa in a Single Circular Microchannel

This paper describes an experimental setup for the investigation of two-phase heat transfer inside microchannels and reports local heat transfer coefficients measured during flow boiling of HFC-245fa in a 0.96-mm-diameter single circular channel. The test runs have been performed during vaporization at around 1.85 bar, corresponding to 31°C saturation temperature. As a peculiar characteristic of the present technique, the heat transfer coefficient is not measured by imposing the heat flux; instead, the boiling process is governed by controlling the inlet temperature of the heating secondary fluid. In the data, mass velocity ranges between 200 and 400 kg m^?2 s^?1, with heat flux varying from 5 to 85 kW m^?2 and vapor quality from 0.05 up to 0.8. Since these data are not measured at uniform heat flux conditions, a proper analysis is performed to enlighten the influence of the different parameters and to compare the present data to those obtained when the heat flux is imposed. Besides, the test runs have been carried out in a double mode: by increasing the water-to-refrigerant temperature difference and by decreasing it. Finally, the experimental data are compared to models available in the literature for predicting the heat transfer coefficients inside microchannels.