N‐Type Organic Thermoelectrics: Improved Power Factor by Tailoring Host–Dopant Miscibility

In this contribution, for the first time, the polarity of fullerene derivatives is tailored to enhance the miscibility between the host and dopant molecules. A fullerene derivative with a hydrophilic triethylene glycol type side chain (PTEG‐1) is used as the host and (4‐(1,3‐dimethyl‐2,3‐dihydro‐1H‐benzoimidazol‐2‐yl)phenyl)dimethylamine n ‐DMBI) as the dopant. Thereby, the doping efficiency can be greatly improved to around 18% (<1% for a nonpolar reference sample) with optimized electrical conductivity of 2.05 S cm^?1, which represents the best result for solution‐processed fullerene derivatives. An in‐depth microstructural study indicates that the PTEG‐1 molecules readily form layered structures parallel to the substrate after solution processing. The fullerene cage plane is alternated by the triethylene glycol side chain plane; the n ‐DMBI dopants are mainly incorporated in the side chain plane without disturbing the π–π packing of PTEG‐1. This new microstructure, which is rarely observed for codeposited thin films from solution, formed by PTEG‐1 and n ‐DMBI molecules explains the increased miscibility of the host/dopant system at a nanoscale level and the high electrical conductivity. Finally, a power factor of 16.7 µW m^?1 K^?2 is achieved at 40% dopant concentration. This work introduces a new strategy for improving the conductivity of solution‐processed n‐type organic thermoelectrics.     

Scaling Organic Electrochemical Transistors Down to Nanosized Channels

The perspective of downscaling organic electrochemical transistors (OECTs) in the nanorange is approached by depositing poly(3,4‐ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) on electrodes with a nanogap designed and fabricated by electromigration induced break junction (EIBJ) technique. The electrical response of the fabricated devices is obtained by acquiring transfer characteristics in order to clarify the specific main characteristics of OECTs with sub‐micrometer‐sized active channels (nanogap‐OECTs). On the basis of their electrical response to different scan times, the nanogap‐OECT shows a maximum transconductance unaffected upon changing scan times in the time window from 1 s to 100 µs, meaning that fast varying signals can be easily acquired with unchanged amplifying performance. Hence, the scaling down of the channel size to the nanometer scale leads to a geometrical paradigm that minimizes effects on device response due to the cationic diffusion into the polymeric channel. A comprehensive study of these features is carried out by an electrochemical impedance spectroscopy (EIS) study, complemented by a quantitative analysis made by equivalent circuits. The propagation of a redox front into the polymer bulk due to ionic diffusion also known as the “intercalation pseudocapacitance” is identified as a limiting factor for the transduction dynamics.     

Stability of difference Volterra equations: Direct Liapunov method and numerical procedure

A procedure to construct Liapunov functionals for discrete Volterra equations is proposed. Using this procedure stability conditions are derived for general Volterra difference equations. Some applications of the proposed procedure for obtaining stability conditions for linear multistep methods for Volterra integro-differential equations are presented.     

DC Link Current Control for High-Performance CSIM Drives

A novel scheme is formulated to control the dc link current of a current source inverter induction motor (CSIM) drive which greatly enhances the current response with substantial benefits on the overall dynamic performance of the drive. In addition to conventional closed-loop control with a PI regulator, the novel scheme incorporates a function generator to compensate for the motor back-EMF seen by the dc link. Application of this scheme to an indirect field-oriented CSIM drive is presented, and improvement in the drive performance is documented.     

PHANTOM: A Monte Carlo event generator for six parton final states at high energy colliders

PHANTOM is a tree level Monte Carlo for six parton final states at proton-proton, proton-antiproton and electron-positron colliders at and including possible interferences between the two sets of diagrams. This comprehends all purely electroweak contributions as well as all contributions with one virtual or two external gluons. It can generate unweighted events for any set of processes and it is interfaced to parton shower and hadronization packages via the latest Les Houches Accord protocol. It can be used to analyze the physics of boson-boson scattering, Higgs boson production in boson-boson fusion, and three boson production.

Program summary

Program title:PHANTOM (V. 1.0)Catalogue identifier: AECE_v1_0Program summary URL:http://cpc.cs.qub.ac.uk/summaries/AECE_v1_0.htmlProgram obtainable from: CPC Program Library, Queen's University, Belfast, N. IrelandLicensing provisions: Standard CPC licence, http://cpc.cs.qub.ac.uk/licence/licence.htmlNo. of lines in distributed program, including test data, etc.: 175 787No. of bytes in distributed program, including test data, etc.: 965 898Distribution format: tar.gzProgramming language: Fortran 77Computer: Any with a UNIX, LINUX compatible Fortran compilerOperating system: UNIX, LINUXRAM: 500 MBClassification: 11.1External routines: LHAPDF (Les Houches Accord PDF Interface, http://projects.hepforge.org/lhapdf/), CIRCE (beamstrahlung for e⁺e⁻ ILC collider).Nature of problem: Six fermion final state processes have become important with the increase of collider energies and are essential for the study of top, Higgs and electroweak symmetry breaking physics at high energy colliders. Since thousands of Feynman diagrams contribute in a single process and events corresponding to hundreds of different final states need to be generated, a fast and stable calculation is needed.Solution method:PHANTOM is a tree level Monte Carlo for six parton final states at proton-proton, proton-antiproton and electron-positron colliders. It computes all amplitudes at and including possible interferences between the two sets of diagrams. The matrix elements are computed with the helicity formalism implemented in the program PHACT [1]. The integration makes use of an iterative-adaptive multichannel method which, relying on adaptivity, allows the use of only a few channels per process. Unweighted event generation can be performed for any set of processes and it is interfaced to parton shower and hadronization packages via the latest Les Houches Accord protocol.Restrictions: All Feynman diagrams are computed al LO.Unusual features: Phantom is written in Fortran 77 but it makes use of structures. The g77 compiler cannot compile it as it does not recognize the structures. The Intel, Portland Group, True64 HP Fortran 77 or Fortran 90 compilers have been tested and can be used.Running time: A few hours for a cross section integration of one process at per mille accuracy. One hour for one thousand unweighted events.References:

[1]

A. Ballestrero, E. Maina, Phys. Lett. B 350 (1995) 225, hep-ph/9403244; A. Ballestrero, PHACT 1.0, Program for helicity amplitudes Calculations with Tau matrices, hep-ph/9911318, in: B.B. Levchenko, V.I. Savrin (Eds.), Proceedings of the 14th International Workshop on High Energy Physics and Quantum Field Theory (QFTHEP 99), SINP MSU, Moscow, p. 303.

     

The power of verification for one-parameter agents

We initiate the study of mechanisms with verification for one-parameter agents. We give an algorithmic characterization of such mechanisms and show that they are provably better than mechanisms without verification, i.e., those previously considered in the literature. These results are obtained for a number of optimization problems motivated by the Internet and recently studied in the algorithmic mechanism design literature. The characterization can be regarded as an alternative approach to existing techniques to design truthful mechanisms. The construction of such mechanisms reduces to the construction of an algorithm satisfying certain “monotonicity” conditions which, for the case of verification, are much less stringent. In other words, verification makes the construction easier and the algorithm more efficient (both computationally and in terms of approximability).     

On the effect of twist angle on nonlinear galloping of suspended cables

A nonlinear model of cable, able to twist, is formulated. For small sag-to-length ratios (e.g. 1/10) and technical parameter values proper to electrical transmission lines, the motion is ruled by the classical equations of the perfectly flexible cable, plus a further equation governing the twist evolution. A two degree-of-freedom system is successively obtained via a Galerkin procedure. The relevant nonlinear ODE’s are dealt with a Multiple Scale approach, under 2:1 internal resonance condition and no resonance conditions, in order to investigate Hopf bifurcations and post-critical behaviors. All the numerical results are compared with those furnished by the flexible model, and the influence of twist is discussed.     

Bio-optical relationships for the northern Adriatic Sea

The first three years of a time-series of marine bio-optical measurements performed from an oceanographic tower in the northern Adriatic Sea are used to derive empirical relationships for ocean colour applications in coastal waters. The site presents bio-optical characteristics pertaining to Case 1 and to Case 2 waters. Log linear relationships allow the diffuse attenuation coefficient for downwelling irradiance, K_{E d}, at different wavelengths to be derived from its value at 490?nm. A local empirical algorithm making use of the remote sensing reflectance ratio R _rs(490)/R _rs(555) is shown to provide lower surface chlorophyll-a values (by a factor of 2 to 4) in the range 0.1–1.0?mg?m^?3 than the SeaWiFS OC2v4 algorithm.