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141.
    
In this research two grades of polysulfide resin with low and high molecular weight (respectively G4 and G112) as reactive modifier was used to toughen epoxy resin. The effect of modifier molecular weight on impact resistance, thermal expansion coefficient, storage and loss modulus, decomposition temperature and adhesion properties of toughened epoxy was investigated. The impact strength and the thermal expansion coefficient (CTE) of epoxy resin was increased with increasing polysulfide but the G112 modified epoxy samples showed higher CTE values and impact resistance than those of modified with G4. Comparing of the same weight percent inclusion of G4 and G112 effect on decomposition temperature show that G4 modified epoxy resin has lower decomposition temperature than the G112 modified epoxy resin. Also addition of G112 up to 10 weight percent leads to higher bond strength with aluminum sheets. According to the DMTA graphs, glass transition temperature (Tg) of the modified epoxy was decreased with increasing polysulfide weight percent in composition. At the same time G4 modified epoxies have lower Tg and storage modulus than that of modified with G112.  相似文献   
142.
    
In this study, simultaneous production of ultrapure hydrogen and gasoline via a novel catalytic fixed‐bed double‐membrane reactor with co‐current flow was investigated, mathematically. The thermally coupled double‐membrane reactor (TCDMR) consists of two Pd/Ag membranes, one for separation of pure hydrogen from endothermic side and another one for permeation of hydrogen from endothermic into exothermic side. Ammonia decomposition reaction is coupled with the Fischer–Tropsch Synthesis (FTS) reaction to improve the heat transfer between endothermic and exothermic sides. Some of the produced hydrogen via ammonia decomposition reaction is utilized in FTS reaction, and the other is extracted and stored. A steady‐state heterogeneous model of the two fixed beds predicts the performance of this novel configuration. The achieved results of this simulation have been compared with the results of the conventional fixed‐bed reactor (CR) at identical process conditions. The simulation results show 67.34% hydrogen production in the permeation side and 32.66% hydrogen utilization in the exothermic side for compensates of hydrogen lack in the FTS reaction through the TCDMR configuration. Moreover, the gasoline yield in TCDMR increases about 18.42% because of a favorable profile of temperature along the TCDMR in comparison with the one in CR. Therefore, this approach utilizes and produces large amounts of pure hydrogen and decreases environmental impacts owing to ammonia emission. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
143.
In this work, a novel fluidized-bed thermally coupled membrane reactor has been proposed for simultaneous hydrogen, methanol and benzene production. Methanol synthesis is carried out in exothermic side which is a fluidized-bed reactor and supplies the necessary heat for the endothermic side. Dehydrogenation of cyclohexane is carried out in endothermic side with hydrogen-permselective Pd/Ag membrane wall. Selective permeation of hydrogen through the membrane in endothermic side is achieved by co-current flow of sweep gas through the permeation side. A steady-state fixed-bed heterogeneous model for dehydrogenation reactor and two-phase theory in bubbling regime of fluidization for methanol synthesis reactor is used to model and simulate the integrated proposed system. This reactor configuration solves some observed drawbacks of new thermally coupled membrane reactor such as internal mass transfer limitations, pressure drop, radial gradient of concentration and temperature in both sides. The proposed model has been used to compare the performance of a fluidized-bed thermally coupled membrane reactor (FTCMR) with thermally coupled membrane reactor (TCMR) and conventional methanol reactor (CR) at identical process conditions. This comparison demonstrates that fluidizing the catalytic bed in the exothermic side of reactor caused a favorable temperature profile along the FTCMR. Furthermore, the simulation results represent 5.6% enhancement in the yield of hydrogen recovery in comparison with TCMR.  相似文献   
144.
145.
    
In this paper, we concatenated of three‐dimensional parity check (3D‐PC) block and polar codes for improving error correction performance and bit error rate (BER). Three different sizes of 3D parity check blocks (4 × 4 × 4, 8 × 8 × 8, and 16 × 16 × 16) are used for polar code concatenation. The 4 × 4 × 4 block returns the best performance, but higher complexity of decoder is needed unlikely. The 8 × 8 × 8 has returned acceptable complexity and good performacne. The complexity of decoder is less in the case of 16 × 16 × 16 with slight performance. The performance of the 3D‐PC is reduced when the codewords length is increased. The experiment considered the presence of additive white Gaussian noise (AWGN) with Rayleigh and Rician fading environments. 3D‐PC and polar code concatenation is more precise with codewords of short length, whereas there is insufficient concatenation accuracy with longer codewords. The outcomes of this study contain comparison between AWGN, Rayleigh, and Rician environments. The AWGN is noticed to have a lesser negative impact on the performance of code. Furthermore, increasing the code length may slightly fill the gap of performance between the concatenated and none concatenated polar codes due to the impact of code length on parity check code performance. Simulation results showed the coding performance in case of the polar code with concatenation and without concatenation for different code lengths. Generally, the 3D‐PC polar code concatenation is drawn the optimal result in AWGN environments.  相似文献   
146.
    
Tandem mass spectrometry involves isolation of specific precursor ions and their subsequent excitation through collision-, photon-, or electron-mediated activation techniques in order to induce unimolecular dissociation leading to formation of fragment ions. These powerful ion activation techniques, typically used in between mass selection and mass analysis steps for structural elucidation, have not only found a wide variety of analytical applications in chemistry and biology, but they have also been used to study the fundamental properties of ions in the gas phase. In this tutorial paper, a brief overview is presented of the theories that have been used to describe the activation of ions and their subsequent unimolecular dissociation. Acronyms of the presented techniques include CID, PQD, HCD, SORI, SID, BIRD, IRMPD, UVPD, EPD, ECD, EDD, ETD, and EID. The fundamental principles of these techniques are discussed in the context of their implementation on ultra-high resolution tandem mass spectrometers. © 2020 John Wiley & Sons Ltd. Mass Spec Rev  相似文献   
147.
148.
    
This paper addresses the robust explicit model predictive control scheme for linear systems with input and output constraint in the presence of disturbances and noise. Conditions for disturbance rejection are established by incorporating a full state/disturbance observer. The separation principle is applied to design an optimal observer in the unconstrained problem. Then, an efficient algorithm is developed to explicitly design observer gains by minimizing a quadratic performance criterion. It is shown that the solution includes a set of regions with piecewise affine functions of the state and reference vectors and a set of regions with optimal observers. In the proposed method, two sets of partitions associated with the control law and the observer gains are obtained. Therefore, the online computation includes finding the active regions of both observer and control law partitions in which the current state is located. The proposed technique is particularly attractive for a wide range of practical problems where the exact model of the actual system is not available.  相似文献   
149.
    
In this paper, the problem of exponential stability analysis and the design of sampled‐data nonlinear systems have been studied using a polytopic linear parameter‐varying approach. By means of modeling a new double‐layer polytopic formulation for nonlinear sampled‐data systems, a modified form of piecewise continuous Lyapunov‐Krasovskii functional is proposed. This approach provides less conservative robust exponential stability conditions by using Wirtinger's inequality in terms of linear matrix inequalities. The distances between the real continuous parameters of the plant and the measured parameters of the controller are modeled by convex sets, and the analysis/design conditions are given at the vertices of some hyper‐rectangles. In order to get tractable linear matrix inequality conditions for the stabilization problem, we performed relaxation by introducing a slack variable matrix. Under the new stability criteria, an approach is introduced to synthesize a sampled‐data polytopic linear parameter‐varying controller considering some constraints on the location of the closed‐loop poles in the presence of uncertainties on the varying parameters. It is shown that the proposed controller guarantees the exponential stability of the closed‐loop system for aperiodic sampling periods smaller than a known value, ie, maximum allowable sampling period. Finally, the effectiveness of the proposed approach is verified and compared with some state‐of‐the‐art existing approaches through numerical simulations.  相似文献   
150.
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