Transition temperature dependence in perovskite ceramics as a function of grain size

Simple effective field arguments assuming an non isotropic layer of thickness L, covering the ferroelectric bulk grain of perovskite ceramics are used to determine an expression for the transition temperature TJL) as a function of grain linear size L. The surface to volume ratio increases as L decreases reducing the value of TJL). Experimental data for BaTiO₃ ceramics as a function of grain size are described reasonably well by the expression of T_c(L) obtained this way.     

SAW COM-parameter extraction in AlN/diamond layered structures

Highly c-axis oriented aluminum nitride (AlN) thin piezoelectric films have been grown on polycrystalline diamond substrates by pulsed direct current (DC) magnetron reactive sputter-deposition. The films were deposited at a substrate temperature below 50/spl deg/C (room temperature) and had a typical full width half maximum (FWHM) value of the rocking curve of the AlN-002-peak of 2.1 degrees. A variety of one-port surface acoustic wave (SAW) resonators have been designed and fabricated on top of the AlN films. The measurements indicate that various SAW modes are excited. The SAW phase velocities of up to 11.800 m/s have been measured. These results are in agreement with calculated dispersion curves of the AlN/diamond structure. Finally, the coupling of modes parameters have been extracted from S/sub 11/ measurements using curve fitting for the first SAW mode, which indicate an effective coupling K/sup 2/ of 0.91% and a Q factor of about 600 at a frequency of 1050 MHz.     

Flow Intensity Parameter in Pier Scour Experiments

Technical note discusses a detailed approach to dimensional analysis for the bridge pier scour phenomenon and the introduction of flow intensity. It demonstrates the dependence of critical upstream velocity on the rest of the parameters describing the process and its implications on dimensional analysis. Assuming that the viscous effects are negligible in the local scour phenomenon, it is concluded that the flow intensity of the approaching undisturbed flow is not an adequate parameter to describe the process in usual laboratory conditions. A new proposal is established.     

Searching in metric spaces by spatial approximation

We propose a new data structure to search in metric spaces. A metric space is formed by a collection of objects and a distance function defined among them which satisfies the triangle inequality. The goal is, given a set of objects and a query, retrieve those objects close enough to the query. The complexity measure is the number of distances computed to achieve this goal. Our data structure, called sa-tree (“spatial approximation tree”), is based on approaching the searched objects spatially, that is, getting closer and closer to them, rather than the classic divide-and-conquer approach of other data structures. We analyze our method and show that the number of distance evaluations to search among n objects is sublinear. We show experimentally that the sa-tree is the best existing technique when the metric space is hard to search or the query has low selectivity. These are the most important unsolved cases in real applications. As a practical advantage, our data structure is one of the few that does not need to tune parameters, which makes it appealing for use by non-experts. Edited by R. Sacks-Davis Received: 17 April 2001 / Accepted: 24 January 2002 / Published online: 14 May 2002     

New cardo silylated poly(azomethine)s containing 9,9′‐diphenylfluorene units as materials with Brønsted acid‐dependent fluorescence

Aromatic poly(azomethine)s have been studied due to their attractive properties such as high thermal stability, semiconducting behavior and the ability to coordinate species with their imine units (C?N). In this paper, the synthesis and characterization of two novel silylated poly(azomethine)s containing cardo units are reported. These materials were highly soluble in organic solvents such as chloroform and m‐cresol and were thermally stable, and PAzMC1 exhibited a high glass transition temperature value (287 °C), while that for PAzMC2 was not observed. UV–visible spectrophotometry revealed absorption bands related to the aromatic backbone of both PAzMCs, 300–285 nm in tetrahydrofuran and 310–301 nm in dimethylsulfoxide, and bands attributed to the conjugated imine unit at around 350 nm. In order to investigate the phenomenon of the emission of fluorescence promoted by dopant agents with regard to potential optoelectronic applications, the materials were doped with H₂SO₄ and their optical and electrochemical properties investigated. Thus, the absorption band of the imine group was suppressed due to the nitrogen atoms being protonated. Fluorescence spectroscopy analysis developed in dilute solutions of polymers showed no emission from the undoped polymers, whereas the acid‐doped species emitted fluorescence in the UV and violet regions (322 nm). Cyclic voltammetry measurements were carried out and HOMO–LUMO energies were estimated. This study provides a starting point for the development of new poly(azomethine)s with doping‐dependent emission. © 2019 Society of Chemical Industry     

Bioleaching of metal from waste stream using a native strain of Acidithiobacillus isolated from a coal mine drainage

In this study, the feasibility of using a biohydrometallurgical technique for selective metals recovery from electronic waste (e‐waste) by bacterial bioleaching was investigated. Acidithiobacillus was identified in coal mining acid mine drainage (AMD). The microorganism was studied using specific sequencing of a 16s rDNA fragment. The potential for the dissolution of copper from waste printed wire boards (PWBs) using the isolated Acidithiobacillus ferrooxidans (A. ferroxidans) was evaluated. The bioleaching experiments were performed in an orbital shaker at 30 °C and 170 rpm, with 10 % (v/v) inoculum and a pulp density of 30 g/L. The copper concentration was determined by energy dispersive x‐ray fluorescence (XRF). The result shows that copper recovery from PWBs using our A. ferrooxidans strain was 95 % after 8 days, which showed the feasibility of this process.     

Fixed Queries Array: A Fast and Economical Data Structure for Proximity Searching

Pivot-based algorithms are effective tools for proximity searching in metric spaces. They allow trading space overhead for number of distance evaluations performed at query time. With additional search structures (that pose extra space overhead) they can also reduce the amount of side computations. We introduce a new data structure, the Fixed Queries Array (FQA), whose novelties are (1) it permits sublinear extra CPU time without any extra data structure; (2) it permits trading number of pivots for their precision so as to make better use of the available memory. We show experimentally that the FQA is an efficient tool to search in metric spaces and that it compares favorably against other state of the art approaches. Its simplicity converts it into a simple yet effective tool for practitioners seeking for a black-box method to plug in their applications.     

Preparation and characterisation of silica‐based nanoparticles for cisplatin release on cancer brain cells

In the present work, the preparation, characterisation, and efficiency of two different silica nanostructures as release vehicles of Cisplatin are reported. The 1‐hexadeciltrimethyl‐ammonium bromide templating agent was used to obtain mesoporous silica nanoparticles which were later loaded with Cisplatin. While sol–gel silica was very fast prepared using an excess of acetic acid during the hydrolysis–condensation reactions of tetraethylorthosilicate and at the same time the Cisplatin was added. Several physicochemical techniques including spectroscopies, electronic microscopy, X‐ray diffraction, N₂ adsorption–desorption were used to characterise the silica nanostructures. An in vitro Cisplatin release test was carried out using artificial cerebrospinal fluid. Finally, the toxicity of all silica nanostructures was tested using the C6 cancer cell line. The spectroscopic results showed the suitable stabilisation of Cisplatin into the two different silica nanostructures. A large surface area was obtained for the mesoporous silica nanoparticles, while low areas were obtained in the silica nanoparticles. Cisplatin was released faster from mesoporous silica channels than from inside of aggregates nanoparticles silica. Cisplatin alone, as well as, cisplatin released from both silica nanostructures exerted a toxic effect on cancer cells. In contrast, both silica structures without the drug did not exert any toxic effect.Inspec keywords: cellular biophysics, desorption, adsorption, biomedical materials, sol‐gel processing, silicon compounds, cancer, toxicology, nanofabrication, brain, condensation, mesoporous materials, nanoparticles, X‐ray diffraction, nanomedicine, drugs, aggregates (materials)Other keywords: mesoporous silica channels, silica‐based nanoparticles, cancer brain cells, silica nanostructures, 1‐hexadeciltrimethyl‐ammonium bromide, mesoporous silica nanoparticles, sol‐gel silica, C6 cancer cell line, in vitro cisplatin release test, C6 cancer cell line, acetic acid, hydrolysis‐condensation reactions, tetraethylorthosilicate, physicochemical techniques, electronic microscopy, X‐ray diffraction, N₂ adsorption‐desorption, artificial cerebrospinal fluid, toxicity, toxic effect, N₂ , SiO₂