Nonmarket cobenefits and economic feasibility of on-farm biogas energy production

Standard analysis of the economic feasibility of on-farm biogas energy production tend to emphasize primarily on direct financial benefits to farmers, and abstracts from the nonmarket cobenefits associated with anaerobic digestion of livestock manure and other biomass feedstock. This shortcoming of the standard feasibility analysis raises a fundamental question: How is the economic feasibility of on-farm anaerobic biogas energy production affected by the associated nonpecuniary cobenefits? Incorporating key nonmarket cobenefits from biogas energy production extends the standard economic feasibility analysis, and provides important insights. When nonmarket cobenefits were excluded, on-farm biogas energy production was generally not financially feasible for the dairy and swine farm size ranges studied (except for 600- and 800-sow farms). Overall, results of the financial feasibility analysis did not change compared to a base scenario (without nonmarket cobenefits) when an estimated annual total nonmarket cobenefits of CND$5000 was incorporated into the analysis, for both dairy and swine farms. Biogas energy production was generally financially viable for small-size dairy (i.e., 50-cow) and swine (i.e., 200-sow) farms when the nonmarket cobenefits were valued at CND$15,000 (or higher). Improvements in financial feasibility were more dramatic for dairy than for swine farms.     

Control of morphology in inert-gas condensation of metal oxide nanoparticles

We report preparation conditions to obtain different morphologies of as-deposited refractory metal-oxide nanoparticles using inert-gas condensation with CO₂ laser heating. The micrometer-scale morphology of the nanoparticles depends on the specific metal oxide, the buffer gas composition and pressure, and the target-to-substrate distance. These parameters control the extent to which a plume of nonagglomerated nanoparticles can reach a deposition substrate. Buffer gas pressure has the largest influence for a given material, with lower pressures producing a dense columnar morphology and higher pressures resulting in an open networked morphology. An estimate based on the geometry of the gas-phase plume and experimental results for Y₂O₃ nanoparticles produced in 4 Torr N₂ gives a critical concentration of tens of nanoparticles per μm³ for the transition of agglomerates versus isolated nanoparticles reaching a deposition substrate.     

Imaging one-dimensional and two-dimensional planar photodiode detectors fabricated by ion milling molecular beam epitaxy CdHgTe

Imaging one-dimensional (1-D) and two-dimensional (2-D) arrays of mid-wavelength infrared (MWIR) and long-wavelength infrared (LWIR) planar photodiodes were fabricated by ion milling of vacancy-doped molecular beam epitaxy Cd_xHg_1−xTe layers. Sixty-four-element 1-D arrays of 26×26 μm² or 26×56 μm² diodes were processed. Zero-bias resistance-area values (R₀A) at 77 K of 4×10⁶ Θcm² at cutoff wavelength λ_CO=4.5 μm were measured, as well as high quantum efficiencies. To avoid creating a leakage current during ball bonding to the 1-D array diodes, a ZnS layer was deposited on top of the CdTe passivation layer, as well as extra electroplated Au on the bonding pads. The best measured noise equivalent temperature difference (NETD) on a LWIR array was 8 mK, with a median of 14 mK for the 42 operable diodes. The best measured NETD on a MWIR array was 18 mK. Two-D arrays showed reasonably good uniformity of R₀A and zero-bias current (I₀) values. The first 64×64 element 2-D array of 16×16 μm² MWIR diodes has been hybridized to read-out electronics and gave median NETD of 60 mK.     

Prediction of environmental stress cracking resistance in linear low density polyethylenes

Recently it has been shown that the strain hardening modulus (G_p) at 80°C can be used to predict the environmental stress cracking (ESC) resistance of polyethylenes. The advantage of using strain hardening to determine ESC resistance is that the data may be obtained relatively easily and quickly using simple tensile test equipment. In this article, the strain hardening modulus has been used to predict the ESC resistance of three grades of linear low‐density polyethylene. Unlike in the previous research, the measurements were conducted at room temperature enabling tests to be performed without the need of a temperature‐controlled oven. This was achieved by reducing the strain rate to increase the sensitivity of the technique and increasing the thickness of the specimens to improve the repeatability. The strain hardening modulus data were found to correlate well with the ESC results obtained from long‐term full notch creep tests and are consistent with the known molecular structure of the polyethylene grades. POLYM. ENG. SCI., 2008. © 2007 Society of Plastics Engineers     

On the role of cavitation in particle collection in flotation – A critical review. II

Research in applying hydrodynamic cavitation to recovery of natural resources during the last decade is reviewed. The existence and formation of tiny bubbles or gas nuclei (with diameter from microns down to nano sizes) in natural water were verified from both direct and in-direct measurements, thus providing a foundation for applying hydrodynamic cavitation to flotation systems. The interactions between tiny bubbles and fine particles in aqueous slurry were analysed based on particle surface properties and types of gas nuclei present in water. Tiny bubbles generated by hydrodynamic cavitation were found to increase contact angle of solids and hence attachment force, bridge fine particles to form aggregates, minimize slime coating, remove oxidation layers on particle surfaces, and in consequence reduce reagents consumption. Experiments on generating tiny bubbles by hydrodynamic cavitation revealed that the energy dissipation levels for cavity formation in a flowing liquid could be much lower than predicted, depending on the content of dissolved gases, presence of free gas nuclei and design of cavitation tubes. Application of hydrodynamic cavitation to fine and coarse particle flotation, high intensity conditioning, oil agglomeration of fine coal, and oil sands processing has confirmed the role of tiny bubbles formed by cavitation in improving recovery efficiency. Based on the characteristics of vapor cavity bubbles, increased flotation kinetics by hydrodynamic cavitation could be attributed to a dual role: some collapsing cavity bubbles serving to break interfacial layers on particle surfaces, while other cavity bubbles attaching to those freshly exposed mineral surfaces. The role of water vapor and other gases within cavity bubbles in particle–bubble attachment remains to be explored, as does the action of frothers. Incorporating hydrodynamic cavitation into flotation systems to take advantage of its unique features is expected to develop the next generation of flotation machines.     

Combined enzymatic and colorimetric method for determining the uronic acid and methylester content of pectin: Application to tomato products

A simple procedure for determining the galacturonic acid and methanol contents of soluble and insoluble pectins, relying on enzymatic pectin hydrolysis and colorimetric quantification, is described. Pectin samples are incubated with a commercial pectinase preparation, Viscozyme, then the galacturonic acid content of the hydrolyzed pectin is quantified colorimetrically using a modification of the Cu reduction procedure originally described by Avigad and Milner. This modification, substituting the commonly used Folin–Ciocalteau reagent for the arsenic containing Nelson reagent, gives a response that is linear, sensitive, and selective for uronic acids over neutral sugars. This method also avoids the use of concentrated acids needed for the commonly used m-phenylphenol method. Methanol, released by the action of the pectin methylesterase found in the Viscozyme, is quantified using alcohol oxidase and Purpald. This combined enzymatic and colorimetric procedure correctly determined the galacturonic acid and methanol content of purified, soluble citrus pectin. Application of the procedure to water insoluble pectins was evaluated with water insoluble material from apples and oranges. In both cases good agreement was obtained between this method and commonly used methods based on chemical pectin hydrolysis. Good agreement between these procedures was also found in the analysis of both soluble and insoluble pectins from several tomato products.     

A new acceleration factor for the testing of corrosion protective coatings: flow-induced coating degradation

For corrosion protective coatings that are designed to give lifetimes of protection that may extend to 50 years, valid accelerated test methods are necessary to develop improved systems and validate performance. Fluid flow over metals has long been believed to influence the corrosion process. Studies have been focused on the effects of flow rate on the corrosion of bare metals. The influence of fluid flow on the degradation of metal-protective coatings has received less attention. This paper describes a preliminary study on the influence of laminar flow on organic coatings. A Hele-Shaw cell and its associated fluid control apparatuses are incorporated into the electrochemical cell setup. The barrier properties of the coating as a function of immersion time and flow rate have been monitored by electrochemical impedance spectroscopy. We observe that the barrier properties of the coating measured electrochemically decrease exponentially with the increasing flow rate. We propose that the flowing electrolyte solution could be used in acceleration tests for the lifetime prediction of organic coatings as the acceleration of failure we have observed does not appear to change the mechanism of failure. Further analysis is proposed to validate immersion flow rate as a universal accelerating parameter for coating failure.     

Biodegradation of diesel oil in a baffled roller bioreactor

BACKGROUND: Ex situ bioremediation is a feasible and economical way to remove petroleum pollutants from contaminated soil or water. A baffled roller bioreactor was shown to be effective for biodegradation of diesel oil as a model petroleum pollutant. Microorganisms enriched from an industrially contaminated soil with heavy hydrocarbons were shown to be the best inoculum source for diesel biodegradation. RESULTS: The baffled roller bioreactor demonstrated better performance than control (roller bioreactor without baffles) or bead mill roller (control bioreactor filled partially with spherical beads) bioreactors. Biodegradation consisted of both fast and slow stages for degradation of light and heavy compounds, respectively. Among the tested temperatures ranging from 15 to 35 °C, room temperature (23 °C) was found to be the optimum temperature for biodegradation. The values of maximum specific growth rate and substrate yield (µ_max and Y_XS) for the indigenous microorganisms in the baffled roller bioreactor at room temperature were found to be 0.72 ± 0.08 h^?1 and (7.0 ± 1.0) × 10⁷ cells mg^?1 diesel, respectively. Biodegradation of diesel concentrations up to 200 g L^?1 was achieved with the highest biodegradation rate of 266 mg L^?1 h^?1 at the highest rotation rate of 45 rpm in the baffled roller bioreactor. CONCLUSION: Using indigenous bacteria enriched from industrial contaminated soil at room temperature, a baffled roller bioreactor is able to biodegrade high diesel oil concentrations at high biodegradation rates. Copyright © 2008 Society of Chemical Industry     

Axisymmetric extrusion through adaptable dies—Part 3: Minimum pressure streamlined die shapes

In Part 1 of this series of papers, six kinematically admissible velocity fields, as well as the power terms, were developed for use in upper bound models for arbitrarily shaped dies for axisymmetric extrusion. Part 2 compared the results obtained in upper bound models for the six velocity fields through a spherical die shape and demonstrated that the sine-based velocity field was the best. In this final part, the application of the sine-1 field to extrusion through streamlined dies is developed. By fixing the values of two additional constants in the radial flow flexibility function, the two surfaces of velocity discontinuity, which separate the deformation zone from the incoming and outgoing material, will have no shear. In effect, the analysis for streamlined dies can be modeled without the surface of velocity discontinuity power terms. The results for an arbitrarily curved streamlined die, as proposed by Yang and Han, using the sine-1 velocity field and the cylindrical velocity field from the work by Yang and Han are compared. It is found that the upper bound model using the sine-1 velocity field predicts lower values for the extrusion pressure. A method to determine a streamlined die shape is proposed. The method allows flexibility between the entrance and exit by the use of a Legendre polynomial series for representation of the die surface. The method is termed an adaptable die design. The adaptable die design method is used to determine streamlined die shapes, which will minimize the pressure required for the extrusion process.     

Biomolecules as selective dispersants for carbon nanotubes

Both single-wall or multi-wall nanotube growth result in a soot-like material that contains the desired product. The selective recovery of the nanotube product from this soot still represents a challenge. Methods to date either result in chemical modification of the nanotubes themselves, are time consuming or use expensive to produce polymers. Using a variety of biomolecules, we have been able to selectively suspend multi-wall carbon nanotubes in aqueous solutions while leaving behind the extraneous by-products in the precipitate. At comparable biomolecule to soot ratios, all biomolecules selectively retained more nanotubes than an organic polymer previously used to purify multi-wall nanotubes (PmPV—poly m-phenylene-co-2,5-dioctoxy-p-phenylenevinylene). The highest recovery as determined by Electron Paramagnetic Resonance was 56% of the available nanotubes. The method provides a simple, one-step, non-destructive purification process that facilitates the formation of pure multi-wall carbon nanotube containing biodispersions.