X-ray diffraction line broadening of shock-modified titanium carbide

Titanium carbide powder compact samples have been subjected to controlled high-pressure shock loading with well-characterized peak pressures between 17 and 27 GPa and preserved for post-shock study. The broadened X-ray diffraction peak profiles have been analyzed with the Warren—Averbach technique to determine the residual lattice strain and the coherent crystallite sizes. Although residual strain values in the powders shock-modified to 27 GPa are similar to those reported for wet-milled powders, the shocked powders show less anisotropy in strain, more anisotropy in crystallite shape and larger strain gradients near dislocation cores than milled powders.     

Predictors of individual differences in mail-coding skills and their variation with ability level.

Personality and cognitive predictors of mail coding were investigated in 2 samples, 1 of high coding ability (N?=?56) and 1 of mixed ability (N?=?158). Two approaches to predicting correlates of skill within groups of differing ability were compared: P. L. Ackerman's (1988) ability theory and D. A. Norman and T. Shallice's (1985) account of levels of action control. The predictors of mail-coding skill varied with ability: Personality variables were more predictive among higher ability Ss, and cognitive measures were more predictive among lower ability Ss. Implications of the findings for theories of individual differences in skill are discussed. There were 2 main practical conclusions. First, the measures used were more predictive than a standard psychometric selection test. Second, correlates of skill may be different among unselected job applicants and among the subset of applicants hired for subsequent operational training. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Surface-mediated effects on porous polymer monolith formation within capillaries

The formation of a porous polymer monolith (PPM) is influenced by the physico-chemical properties of the wall surface of its container. This influence can have a dramatic effect on the resulting monolith morphology depending on the nature and composition of the wall. Indeed, a dense polymer layer or “sheath”, distinct from the bulk porous material, has been observed at the wall surface of capillaries, and thus a study was undertaken to explore the dependence of this layer on the hydrophobicity of the surface. A range of silanizing reagents were used to modify the surface of the fused silica capillary, including aminopropyl, trimethylsilyl, octadecyl and perfluorooctyl functionalities. Crosslinked butyl acrylate-based PPM was formed in the modified capillaries and extruded. SEM images of the monoliths were used to examine the sheath morphology and thickness, which are discussed with respect to surface hydrophobicity.     

Garner interference reveals dependencies between emotional expression and gaze in face perception.

The relationship between facial expression and gaze processing was investigated with the Garner selective attention paradigm. In Experiment 1, participants performed expression judgments without interference from gaze, but expression interfered with gaze judgments. Experiment 2 replicated these results across different emotions. In both experiments, expression judgments occurred faster than gaze judgments, suggesting that expression was processed before gaze could interfere. In Experiments 3 and 4, the difficulty of the emotion discrimination was increased in two different ways. In both cases, gaze interfered with emotion judgments and vice versa. Furthermore, increasing the difficulty of the emotion discrimination resulted in gaze and expression interactions. Results indicate that expression and gaze interactions are modulated by discriminability. Whereas expression generally interferes with gaze judgments, gaze direction modulates expression processing only when facial emotion is difficult to discriminate. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

It's a sign of the kind: Gestures and words guide infants' inductive inferences.

The role of words and gestures in guiding infants' inductive inferences about nonobvious properties was examined. One hundred seventy-two 14-month-olds and 22-month-olds were presented with novel target objects followed by test objects that varied in similarity to the target. Objects were introduced with a novel word or a novel gesture or with no label. When target and test objects were highly similar in shape, both 14- and 22-month-olds inferred that these objects shared a nonobvious property, regardless of whether the objects were labeled with a word or a gesture or with no label. When objects were labeled with the same word, both 14- and 22-month-olds generalized the nonobvious properties to objects that shared minimal perceptual similarity. Finally, when objects were labeled with the same gesture, 14-month-olds, but not 22-month-olds, generalized the nonobvious properties to objects that shared minimal perceptual similarity. These results indicate that 14-month-olds possess a more generalized symbolic system as they will rely on both words and gestures to guide their inferences. By 22-months of age, infants treat words as a privileged referential form when making inductive inferences. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Effect of stepper lens operating conditions on proximity effects in DUV optical lithography down to 250nm

Reduction of optical proximity effects (OPE), at deep uv wavelength of 248nm, caused by the variation of stepper lens operating conditions is investigated. It is shown that many of these effects, which increase as the Rayleigh limit is approached, can be minimised, and in many cases eliminated, by suitable choice of lens numerical aperture (NA) and partial coherence (sigma, σ).

Application of these results should enable the user of advanced wafer steppers to carry out high resolution lithography with a minimum of time consuming optical proximity correction (OPC).     

Assessment of abdominal lymph nodes in a normal paediatric population: an ultrasound study

During a 9 month period, 50 consecutive children were evaluated by ultrasound to determine the size, location (mesenteric vs para-aortic), number, shape and texture of abdominal lymph nodes in a normal paediatric population. High resolution linear array transducers were used with graded compression. Nodes ranging from 10 to 20 mm were recorded in the majority of subjects. In all cases mesenteric lymph nodes were larger and more numerous than para-aortic nodes. Para-aortic lymph nodes were not seen in isolation.     

Predictive modelling of the 3-D structure of interleukin-13

Several atomic structures are now available for the family ofhelical cytokines, which includes growth hormone as well asmany of the interleukins. Using structural information fromfive members of this family, two alternative models of interleukin(IL)-13 are proposed. IL-13 has biological properties similarto those of IL-4 and, like the other interleukins, is a potentiallyimportant pharmaceutical target. The model of IL-13 is discussedand compared with the known interleukin structures.     

Comparison of supports for the direct synthesis of hydrogen peroxide from H2 and O2 using Au–Pd catalysts

The direct synthesis of hydrogen peroxide from H₂ and O₂ using a range of supported Au–Pd alloy catalysts is compared for different supports using conditions previously identified as being optimal for hydrogen peroxide synthesis, i.e. low temperature (2 °C) using a water–methanol solvent mixture and short reaction time. Five supports are compared and contrasted, namely Al₂O₃, -Fe₂O₃, TiO₂, SiO₂ and carbon. For all catalysts the addition of Pd to the Au only catalyst increases the rate of hydrogen peroxide synthesis as well as the concentration of hydrogen peroxide formed. Of the materials evaluated, the carbon-supported Au–Pd alloy catalysts give the highest reactivity. The results show that the support can have an important influence on the synthesis of hydrogen peroxide from the direct reaction. The effect of the methanol–water solvent is studied in detail for the 2.5 wt% Au–2.5 wt% Pd/TiO₂ catalyst and the ratio of methanol to water is found to have a major effect on the rate of hydrogen peroxide synthesis. The optimum mixture for this solvent system is 80 vol.% methanol with 20 vol.% water. However, the use of water alone is still effective albeit at a decreased rate. The effect of catalyst mass was therefore also investigated for the water and water–methanol solvents and the observed effect on the hydrogen peroxide productivity using water as a solvent is not considered to be due to mass transfer limitations. These results are of importance with respect to the industrial application of these Au–Pd catalysts.