Extraction and analysis of forensic document examiner features used for writer identification

In this paper we present a study of structural features of handwriting extracted from three characters “d”, “y”, and “f” and grapheme “th”. The features used are based on the standard features used by forensic document examiners. The process of feature extraction is presented along with the results. Analysis of the usefulness of features was conducted via searching the optimal feature sets using the wrapper method. A neural network was used as a classifier and a genetic algorithm was used to search for optimal feature sets. It is shown that most of the structural micro features studied, do possess discriminative power, which justifies their use in forensic analysis of handwriting. The results also show that the grapheme possessed significantly higher discriminating power than any of the three single characters studied, which supports the opinion that a character form is affected by its adjacent characters.     

Anti-symmetric motion of a pre-stressed incompressible elastic layer near shear resonance

A two-dimensional model is derived for anti-symmetric motion in the vicinity of the shear resonance frequencies in a pre-stressed incompressible elastic plate. The method of asymptotic integration is used and a second-order solution, for infinitesimal displacement components and incremental pressure, is obtained in terms of the long-wave amplitude. The leading-order hyperbolic governing equation for the long-wave amplitude is observed to be not wave-like for certain pre-stressed states, with time and one of the in-plane spatial variables swapping roles. This phenomenon is shown to be intimately related to the possible existence of negative group velocity at low wave number, i.e. in the vicinity of shear resonance frequencies.     

Quantitative characterization of three-dimensional damage evolution in a wrought Al-alloy under tension and compression

Three-dimensional (3-D) microstructural damage due to cracking of Fe-rich intermetallic particles is quantitatively characterized as a function of strain under compression and tension in an Al-Mg-Si base wrought alloy. The 3-D number fraction of damaged (cracked) particles, their average volume, average surface area, and shape factor are estimated at different strain levels for deformation under uniaxial tension and compression. It is shown that, depending on the type of loading, loading direction, particle shape, and microstructural anisotropy, the two-dimensional (2-D) number fraction of the damaged particles can be smaller or larger than the corresponding true 3-D number fraction. Under uniaxial tension, the average volume and surface area of cracked particles decrease with the strain. However, the average volume and surface area of the cracked particles increase with the increase in the compressive strain, implying that more and more larger elongated particles crack at higher and higher stress levels, which is contrary to the predictions of the existing particle cracking theories. In this alloy, the damage development due to particle cracking is intimately coupled with the particle rotations. The differences in the damage evolution under tension and compression are explained on the basis of the differences in the particle rotation tendencies under these two loading conditions.     

Sources and timing of anthropogenic pollution in the Ensenada de San Simon (inner Ria de Vigo), Galicia, NW Spain: an application of mixture-modelling and nonlinear optimization to recent sedimentation

The Ensenada de San Simon is the inner part of the Ria de Vigo, one of the major mesotidal rias of the Galician coast, NW Spain. The geochemistry of its bottom sediments can be accounted for in terms of both natural and anthropogenic sources. Mixture-modelling enables much of the Cr, Ni, V, Cu, Pb and Zn concentrations of the bottom and subaqueous sediments to be explained by sediment input from the river systems and faecal matter from manmade mussel rafts. The compositions and relative contributions of additional, unknown, sources of anomalous heavy-metal concentrations are quantified using constrained nonlinear optimization. The pattern of metal enrichment is attributed to: material carried in solution and suspension in marine water entering the Ensenada from the polluted industrial areas of the adjacent Ria de Vigo; wind-borne urban dusts and/or vehicular emissions from the surrounding network of roads and a motorway road-bridge over the Estrecho de Rande; industrial and agricultural pollution from the R. Redondela; and waste from a former ceramics factory near the mouth of the combined R. Oitaben and R. Verdugo. Using (137)Cs dating, it is suggested that heavy metal build-up in the sediments since the late 1970s followed development of inshore fisheries and introduction of the mussel rafts (ca. 1960) and increasing industrialisation.     

Influence of autochthonous dissolved organic carbon and nutrient limitation on alachlor biotransformation in aerobic aquatic systems

Much work has suggested that the rate of attenuation of water-soluble organic contaminants in aerobic aquatic systems is dependent on the level of secondary nutrients in the water column. For example, the decay rate of alachlor, a common herbicide, was over 10 times higher under hypereutrophic compared with oligotrophic water conditions. It has been presumed that higher water column nutrient levels produce larger microbial communities, resulting in higher rates of alachlor cometabolism. However, most earlier field studies only assessed alachlor fate in systems with full light exposure (FLE). Therefore, new experiments were performed to assess how variations in light level affect alachlor cometabolism in such systems. Twelve tank mesocosms were maintained using identical nitrogen (N) and phosphorus (P) supply conditions: four units with full light exposure (100% FLE), four with partial shading (19.3% FLE), and four with near complete shading (0.5% FLE). Alachlor half-lives were found to vary broadly, from 50 to 60 days in higher light units to > 180 days in the 0.5% FLE units. Nutrient analysis indicated that the low light units were severely carbon (C)-limited for microbial decomposition, whereas the other units had excess C relative to N and P. Apparently, reduced light levels cause decreased production of bioavailable C for decomposition, which significantly reduces alachlor cometabolism. The data suggest that water column nutrient levels only correlate with the alachlor decay rate when light levels are high, and that the biodegradable carbon supply must be considered when the fate of water-soluble contaminants in aerobic aquatic systems is assessed.     

The influence of the rate of pH decline on the rate of ageing for pork. I: interaction with method of suspension

The influence of the rate of pH decline post slaughter on the rate of ageing of pork was investigated. The rate of pH decline on 24 finisher pigs was manipulated by altering the method of stunning (carbon dioxide or electrical head to heart) and by the use of electrical stimulation (none or low voltage electrical stimulation (LVES) at 4 min post slaughter). To investigate the effect of pH decline rate on ageing rate independently of the effect on possible muscle shortening, sides were suspended by either the pelvis (to minimize shortening) or conventionally by the Achilles tendon. The data indicated that the rate of pH decline did not influence the rate of ageing but the use of LVES did improve tenderness at 1, 2 and 10 days post slaughter due to the prevention of muscle shortening. Electrical stunning improved tenderness at 1 and 2 days post-slaughter but had a detrimental effect on drip loss. Pelvic suspension improved tenderness at rigor, 1, 2 and 6 days post slaughter due to prevention of muscle shortening. The conditions employed however were not severe enough to induce protein denaturation.     

A high-throughput method for the conversion of CO2 obtained from biochemical samples to graphite in septa-sealed vials for quantification of 14C via accelerator mass spectrometry

The growth of accelerator mass spectrometry as a tool for quantitative isotope ratio analysis in the biosciences necessitates high-throughput sample preparation. A method has been developed to convert CO(2) obtained from carbonaceous samples to solid graphite for highly sensitive and precise (14)C quantification. Septa-sealed vials are used along with commercially available disposable materials, eliminating sample cross contamination, minimizing complex handling, and keeping per sample costs low. Samples containing between 0.25 and 10 mg of total carbon can be reduced to graphite in approximately 4 h in routine operation. Approximately 150 samples per 8-h day can be prepared by a single technician.     

Gas adsorption gates based on ultrathin composite polymer films

High surface area alumina coatings were prepared on surface acoustic wave (SAW) mass balances. These coatings were fabricated by anodic etching of evaporated aluminum films. The coatings consisted of roughly collinear pores penetrating through the monolithic alumina film. The nanoporous (NP) coatings were characterized by scanning electron microscopy, and the pore number density and diameter were found to be (3.8 +/- 0.5) x 10(3) pores/microm2 and 6.8 +/- 4.8 nm, respectively. The mass of volatile organic compounds that adsorbed onto naked and chemically modified NP alumina coatings was measured using SAW mass balances and compared to the mass absorbed onto SAW devices having planar aluminum coatings. Thirty-four times more heptane adsorbed to the naked NP coating than to the planar coating. The mass loading response was also measured after modification with organic thin films (3-12 nm thick) that spanned the pores of the NP coating. These organic thin films were composed of sixth-generation, amine-terminated poly(amido amine) dendrimers and poly(maleic anhydride)-c-poly(methyl vinyl ether) (Gantrez). The key result of this study is that these organic thin films modulate adsorption of VOCs onto the pore walls of the NP alumina. Specifically, a single 3-nm-thick monolayer of the dendrimer reduces permeability of the VOCs by approximately 17%, whereas a 12-nm-thick G6-NH2/Gantrez composite reduces permeability by 100%. Thus, the polymer composite acts as a nonselective gate that controls access of VOCs to the underlying surface area of the pores.     

Production and performance of multilayer-coated conical x-ray mirrors

A method of fabricating replica figured x-ray optics with integral multilayer coatings is presented. With the intact electroforming multilayer process (IEMP) technique, we sputter multilayers onto a reusable superpolished mandrel, electroform nickel over the multilayers, and remove the multilayer-coated nickel shell intact from the mandrel. This approach offers advantages over more traditional, original, and segmented-replica fabrication techniques, including low cost; compatibility with a wide range of mirror designs, diameters, and focal lengths; simple integration with multilayer sputtering processes; and the ability to produce complete shells of revolution. The fabrication of W/Si multilayer-coated 10-cm-diameter conical x-ray mirrors is described, as are reflectivity measurements at 10 and 30 keV. The measured reflectivity of the IEMP multilayers at the 10-keV primary Bragg peak was 17%. Measurements of multiple points on the cone showed multilayer uniformity to within a few percent around the mirror.     

Optical acoustic detector based on a fiber Fabry-Perot interferometer

We describe a novel optical acoustic detector based on a bias-controlled fiber Fabry-Perot interferometer. The detector has a broad bandwidth from 10 Mhz to a few gigahertz and higher sensitivity than conventional systems, which are useful for noncontact characterization of microsamples based on laser ultrasound.