Mechanische Hochtemperatureigenschaften von flugaschebasierten Geopolymerbetonen

Mechanical properties of fly ash‐based geopolymer concretes at high temperature At present, concretes based on alkali‐activated binders, so‐called geopolymer concretes, are investigated intensively in the building materials industry and by the research community as environmentally friendly alternative to Portland cement‐based concretes. These inorganic binders, which are based on industrial by‐products such as fly ash and ground granulated blast furnace slag, exhibit high resistance against corrosive acids and salts, if properly designed. The mechanical properties of fly ash‐based geopolymer concretes at high temperatures are subject of systematic investigations at the Bundesanstalt für Materialforschung und ‐prüfung (BAM) to create a basis for the structural design of fire exposed concrete members based on alkali‐activated binders. The concrete specimens, produced with quartz aggregates or lightweight aggregates and heated to a maximum temperature of 750 °C, exhibited a decrease of compressive strength up to temperatures of ca. 300 °C, attributed to formation of microcracks caused by dehydration. At higher temperatures the compressive strength of the investigated geopolymer concretes recovered partly, due to sintering processes starting from ca. 500 °C. Because of this beneficial property when compared to conventional concretes, geopolymer concretes can potentially be applied in infrastructure facilities where fire resistance is critical. From the results of the thermomechanical tests stress‐strain relationships are derived that can be used for the structural design of members made from geopolymer concretes.     

40 GHz Vertical Transition with a Dual‐Mode Cavity for a Low‐Temperature Co‐fired Ceramic Transceiver Module

A new vertical transition between a substrate integrated waveguide in a low‐temperature co‐fired ceramic substrate and an air‐filled standard waveguide is proposed in this paper. A rectangular cavity resonator with closely spaced metallic vias is designed to connect the substrate integrated waveguide to the standard air‐filled waveguide. Physical characteristics of an air‐filled WR‐22 to WR‐22 transition are compared with those of the proposed transition. Simulation and experiment demonstrate that the proposed transition shows a ?1.3 dB insertion loss and 6.2 GHz bandwidth with a 10 dB return loss for the back‐to‐back module. A 40 GHz low‐temperature co‐fired ceramic module with the proposed vertical transition is also implemented. The implemented module is very compact, measuring 57 mm × 28 mm × 3.3 mm.     

Simulation einer prädiktiven Raumtemperaturregelung unter Verwendung einer idealen Wettervorhersage

Durch die Anwendung von prädiktiven Regelalgorithmen (Model Predictive Control MPC) für die Raumheizung versprechen sich Errichter und Betreiber eine nennenswerte Energieeinsparung. Mittels einer Simulation soll für einen ausgewählten Fall das Energieeinsparpotential eines prädiktiven Regelalgorithmus zur Raumtemperaturregelung unter Verwendung einer idealen Wettervorhersage im Vergleich zu gängigen Algorithmen wie z. B. PI‐Regler oder Zweipunktregler abgeschätzt werden. Als Regelstrecke mit der Regelgröße Raumtemperatur dient ein Raum mit Fußbodenheizung, der in TRNSYS modelliert wurde. Mittels geeigneter Identifikationsmethoden wurde ein lineares Zustandsraummodell der Regelstrecke entworfen, welches vom prädiktiven Regelalgorithmus, der in MATLAB programmiert wurde, verwendet wird. Durch Einbindung eines Referenzwetterdatensatzes aus der TRNSYS‐Bibliothek, welcher dem Regelalgorithmus zur Verfügung gestellt wird, sind alle relevanten Wetterdaten bereits im Voraus bekannt (ideale Wettervorhersage). Für die in diesem Beitrag betrachtete Konfiguration ergab sich ein Energieeinsparpotential von ca. 10 % pro Jahr bei der Verwendung eines MPCReglers, verglichen mit einem PI‐Regler. Simulation of a model predictive room temperature control by use of an ideal weather forecast. Due to the use of MPC (Model Predictive Control) for room heating applications users and constructors expect nameable energy savings. By usage of a simulation for a special case the energy saving potential of predictive control algorithm for room temperature control in connection with an ideal weather forecast, in comparison to established algorithms (PI‐control, two level controller) is estimated. The controlled system with the control variable room temperature is a room with floor heating which was modelled in TRNSYS. A linear state space model of the controlled system was derived with suitable identification methods. This model was used by the predictive control algorithm, which was programmed in MATLAB. The weather data was taken from the TRNSYS library and has been made available also for the control algorithm, so that an ideal weather forecast was established. For the example considered in this paper, the amount of energy saving was 10 % per year with the MPC‐controller compared to a PI‐controller.     

Geschichtliche Entwicklung und aktuelle Praxis der Probebelastung — Teil 2: Entwicklung von Normen und heutige Anwendung

Im Zuge des massenhaften Einsatzes von Probebelastungen im 19. und zu Beginn des 20. Jahrhunderts zeigte sich die Notwendigkeit, deren Planung, Durchführung und Auswertung durch allgemeine Richtlinien und Normen zu stützen. Im Beitrag wird das Ringen um erste zaghafte Festlegungen beschrieben, die im Laufe der Jahre immer konkreter zu einer verwendbaren Handlungsgrundlage ausgearbeitet wurden. Unter Kritikern blieb jedoch immer die Frage über die Sicherheit und vor allem die Aussagekraft von Belastungsversuchen auf der Grundlage der verwendeten Bewertungskriterien offen. Mit der Weiterentwicklung der Berechnungsverfahren auch durch den Einsatz von Computertechnik wurden Probebelastungen von Neubauten ab den 1970‐er Jahren entbehrlich. Für auffällig gewordene bestehende Tragwerke stellt die Probebelastung jedoch auch heute noch eine — und manchmal die einzige — Methode zum Nachweis einer ausreichenden Tragfähigkeit dar. Die hierfür angewendete moderne Belastungs‐ und Messtechnologie bietet jedoch im Unterschied zur traditionellen Vorgehensweise ein hohes Maß an Sicherheit und Informationsgewinn. Historical Development and current practise of load tests in situ — Part 2: Development of standards and current practise. Because of the large demand and use of load testing in the 19th and at the beginning of the 20th century, there was the necessity to standardise the planning, execution and analysis in general guidelines and codes. This article describes the struggling and first tentative specification, which were more and more specified to an useful basis in the following years. The used criterions for the assessment have often been a reason for critics on the value and the safety of loading tests. The further development of calculation methods especially the computer technology made the load testing of new structures superfluous in the 1970s. But for existing structures loading tests are today often a — and sometimes the only — method to proof a sufficient load bearing capacity. The today used modern loading‐ and measuring technology provides, in contrast to the traditional method, a high degree of safety and structural information.     

Eine Anmerkung zur exakten Nachbildung von Aktienindizes mittels einer Multiplikator-Rundungsmethode

Um einen Aktienindex exakt nachzubilden, mu? man die Gewichtungsfaktoren des Indexes mit dem gewünschten Index-Vielfachen multiplizieren und erh?lt so die Anzahlen der jeweils zu haltenden Aktien. Rundet man diese Anzahlen auf herk?mmliche Art, so weicht man vom gewünschten Nachbildungsergebnis h?ufig weiter als n?tig ab. In dieser Arbeit wird ein leicht zu implementierender Algorithmus vorgestellt, der dieses Problem auf Basis einer Multiplikator-Rundungsmethode l?st. Als konkretes Anwendungsbeispiel wird gezeigt, wie man dieses Verfahren beim Nachbilden des Deutschen Aktien-Indexes (DAX) anwenden kann. Dabei finden auch im Xetra-Handel übliche Stückzahlrestriktionen Berücksichtigung. Der Algorithmus reduziert den Nachbildungsfehler und damit auch den daraus resultierenden Tracking-Error auf einen Bruchteil des Wertes, den man bei herk?mmlicher Rundung erh?lt.     

Microenvironment of the high affinity ATP-binding site of Na+/K+-ATPase is slightly acidic

Fluorescein-5'-isothiocyanate (FITC) was used to study the high-affinity ATP-binding site of Na+/K+-ATPase. The molar ratio of specifically bound FITC per alpha-subunit of Na+/K+-ATPase was found to be 0.5 as followed from pretreatment experiments with another specific E1ATP-inhibitor Cr(H2O)4AdoPP[CH2]P. This indicated an existence of one high affinity ATP-binding site (E1ATP-binding site) in the native (alphabeta)2-diprotomer of Na+/K+-ATPase. Fluorescence dual-excitation ratio of specifically bound FITC revealed that at external pH 7.5, the pH value inside the E1ATP-binding site is 6.95 +/- 0.18. In addition, FITC fluorescence quenching by anti-fluorescein and by iodide choline indicated the limited access of water into the small pocket of the E1ATP-binding site.     

Casting process and comparison of the properties of adapted load-sensitive magnesium alloys

Magnetic magnesium alloys can be utilized as a load sensitive material, in which the inverse magnetostrictive effect is used in order to measure the actual loads in structural components manufactured from such lightweight sensor alloys. To achieve a material which exhibits magnetic properties, Mg is alloyed with ferromagnetic materials like cobalt or samarium-cobalt. Alloying elements commonly used with Mg are utilized to improve the mechanical properties of these alloys, which however may have a slight negative impact on the magnetic sensitivity. In this work, two separate magnetic Mg alloys are compared, each with properties matched to the opposing requirements: (a) high load sensitivity and (b) satisfactory mechanical properties, respectively. The precipitation behavior of the ferromagnetic constituent Co in Mg together with other alloying elements is shown on the basis of SEM images. In addition, the dissolving behavior of the Co powder during the casting process of a binary Mg–Co alloy is investigated. Cyclic loading tests employing harmonic analyses of eddy current signals are utilized in order to verify the alloys’ sensory properties. The mechanical properties are investigated using tensile tests.     

An empirical examination of application frameworks success based on technology acceptance model

Framework-based development is currently regarded as one of the most promising software development approaches when it comes to improvements in lead time, productivity and quality. However, many frameworks and projects based on frameworks still report failures, which indicate that there are problems related to both frameworks technology and frameworks usage. The objective of our research was to examine the major drivers that have an impact on a framework’s acceptance and a framework’s success. We used the technology acceptance model (TAM) and Seddon’s information systems success model as our underlying theory. Data collected from an online survey of 389 active framework users was used to test hypothesized models. Data analysis was performed via structural equation modeling. Our findings support the post-adoption version of TAM and the relationship between continuous use and the successful use of systems, where more use also means more net benefits. We found that the successful use of frameworks is mainly dependent on two factors: continuous framework usage intention and the perceived usefulness of the framework. Several practical and theoretical implications can be foreseen including advances in framework development guidelines and insight into the relationship between the acceptance and success of frameworks.     

Impact of Condensates Containing Chloride and Sulphate on the Corrosion in Automotive Exhaust Systems

The chemical composition of condensates recovered from a test car was systematically analysed in this study. It was found that most condensates contain a higher concentration of chloride than that of sulphate. In order to understand the effect of sulphate on the pitting behaviour of 436SS and to predict whether pitting will occur in these condensates, pitting potentials were determined in a 0.2M sulphate solution with varying chloride concentration by using the potentiodynamic cyclic polarization curve method. The results demonstrate that sulphate prevents pitting initiation of 436SS when the concentration of sulphate is higher than that of chloride. However, no inhibitory effect of sulphate was observed when the sulphate concentration is lower than the chloride concentration. As the condensate recovered from the muffler contains more chloride than sulphate, the muffler is most likely suffering from pitting. This was confirmed by the microscopic observation of the corroded muffler from the test car.