Wetland change mapping for the U.S. mid-Atlantic region using an outlier detection technique

Although the impacts of wetland loss are often felt at regional scales, effective planning and management require a comparative assessment of local needs, costs, and benefits. Satellite remote sensing can provide spatially explicit, synoptic land cover change information to support such an assessment. However, a common challenge in conventional remote sensing change detection is the difficulty of obtaining phenologically and radiometrically comparable data from the start and end of the time period of interest. An alternative approach is to use a prior land cover classification as a surrogate for historic satellite data and to examine the self-consistency of class spectral reflectances in recent imagery. We produced a 30-meter resolution wetland change probability map for the U.S. mid-Atlantic region by applying an outlier detection technique to a base classification provided by the National Wetlands Inventory (NWI). Outlier-resistant measures – the median and median absolute deviation – were used to represent spectral reflectance characteristics of wetland class populations, and formed the basis for the calculation of a pixel change likelihood index. The individual scene index values were merged into a consistent region-wide map and converted to pixel change probability using a logistic regression calibrated through interpretation of historic and recent aerial photography. The accuracy of a regional change/no-change map produced from the change probabilities was estimated at 89.6%, with a Kappa of 0.779. The change probabilities identify areas for closer inspection of change cause, impact, and mitigation potential. With additional work to resolve confusion resulting from natural spatial heterogeneity and variations in land use, automated updating of NWI maps and estimates of areal rates of wetland change may be possible. We also discuss extensions of the technique to address specific applications such as monitoring marsh degradation due to sea level rise and mapping of invasive species.     

Maximum-likelihood registration of range images with missing data

Missing data are common in range images, due to geometric occlusions, limitations in the sensor field of view, poor reflectivity, depth discontinuities, and cast shadows. Using registration to align these data often fails, because points without valid correspondences can be incorrectly matched. This paper presents a maximum likelihood method for registration of scenes with unmatched or missing data. Using ray casting, correspondences are formed between valid and missing points in each view. These correspondences are used to classify points by their visibility properties, including occlusions, field of view, and shadow regions. The likelihood of each point match is then determined using statistical properties of the sensor, such as noise and outlier distributions. Experiments demonstrate a high rates of convergence on complex scenes with varying degrees of overlap.     

Fixed-Parameter Complexity of Minimum Profile Problems

The profile of a graph is an integer-valued parameter defined via vertex orderings; it is known that the profile of a graph equals the smallest number of edges of an interval supergraph. Since computing the profile of a graph is an NP-hard problem, we consider parameterized versions of the problem. Namely, we study the problem of deciding whether the profile of a connected graph of order n is at most n−1+k, considering k as the parameter; this is a parameterization above guaranteed value, since n−1 is a tight lower bound for the profile. We present two fixed-parameter algorithms for this problem. The first algorithm is based on a forbidden subgraph characterization of interval graphs. The second algorithm is based on two simple kernelization rules which allow us to produce a kernel with linear number of vertices and edges. For showing the correctness of the second algorithm we need to establish structural properties of graphs with small profile which are of independent interest. A preliminary version of the paper is published in Proc. IWPEC 2006, LNCS vol. 4169, 60–71.     

Thermodynamic modeling of the Na–Al–Ti–H system and Ti dissolution in sodium alanates

Thermodynamic assessments were made to optimize thermodynamic models and parameter fits to selected experimental and first principles hypothetical predicted phase data within the Na–Al–Ti–H system. This enabled thermodynamic modeling of Ti solubility within the sodium alanates: NaAlH₄ and Na₃AlH₆, and the relative stability of Ti-bearing phases. The modeling provides insights into the role of Ti originating from Ti-based activating agents commonly referred to as ‘catalysts’ in promoting reversibility of the Na–Al–H dehydrogenation and rehydrogenation reactions under moderate temperature and pressure conditions relevant to H storage applications. Preliminary assessments were made to evaluate H solubility in bcc-Ti and hcp-Ti, and stability of the hydride δ-TiH₂. To model possible Ti dissolution in NaAlH₄ and α-Na₃AlH₆, sub-lattice models were applied. A repulsive interaction is predicted by first principles calculations when Ti is dissolved in NaAlH₄ or α-Na₃AlH₆, which becomes stronger with increasing temperature. Although Ti is virtually insoluble in NaAlH₄ or α-Na₃AlH₆, a small addition of TiCl₃ will induce a thermodynamic driving force for formation of TiH₂ and/or TiAl₃. The addition of pure Ti shows a weaker effect than TiCl₃ and leads to formation of TiH₂ only. Based on a combined interpretation of present thermodynamic modeling and prior experimental observations, the TiAl₃ and TiH₂ phases are ascribed to have a catalytic effect, not a thermodynamic destabilization effect, on the reversibility of the dehydrogenation/rehydrogenation reactions in the Na–Al–H system.     

Cyclic voltammetry on electrode surfaces covered with porous layers: An analysis of electron transfer kinetics at single-walled carbon nanotube modified electrodes

Cyclic voltammetry is recorded of the oxidation of ferrocyanide on a glassy carbon electrode modified with multiple layers of single-walled carbon nanotubes. The current response is interpreted in terms of semi-infinite planar diffusion towards the macro-electrode surface and in terms of oxidation of the electroactive species trapped in pockets in between the nanotubes. A thin layer model is used to illustrate the effects of diffusion within a porous layer. It is found that a semi-infinite planar diffusion model alone is not appropriate for interpreting the kinetics of the electron transfer at this electrode surface. In particular, caution should be exercised in respect of comparing voltammetric peak-to-peak potential separations between naked electrodes and nanotube-modified electrodes for the inference of electrocatalysis via electron transfer via the nanotubes.     

Topology optimization of structures with integral compliant mechanisms for mid-frequency response

The purpose of this paper is to present a method for developing new truss-like sandwich structures that exhibit desirable mid-frequency vibratory characteristics. Specifically, a genetic algorithm optimization routine is used to determine candidate small scale structural topologies, i.e. unit cells, that may be used in the design of larger scale periodic sandwich structures. This multi-scale procedure is demonstrated starting with several unit cell topology optimization examples. From these examples a specific optimal unit cell is selected for further investigation and integration into a periodic sandwich beam. Computational results indicate that the proposed optimization approach is effective when used to design new structures for reduced mid-frequency vibratory response.     

Influence of grain boundary weak links on the nonequilibrium response of YBaCuO thin films to short laser pulses

The transient voltage response in both epitaxial and granular YBaCuO thin films to 80 ps pulses of YAGNd laser radiation of wavelength 0.63 and 1.54 m was studied. In the normal and resistive states both types of films demonstrate two components: a nonequilibrium picosecond component and a bolometric nanosecond one. The normalized amplitudes are almost the same for all films. In the superconducting state we observed a kinetic inductive response and two-component shape after integration. The normalized amplitude of the response in granular films is up to five orders of magnitude larger than in epitaxial films. We interpret the nonequilibrium response in terms of a suppression of the order parameter by the excess of quasiparticles followed by the change of resistance in the normal and resistive states or kinetic inductance in the superconducting state. The sharp rise of inductive response in granular films is explained both by a diminishing of the cross section for current percolation through the disordered network of Josephson weak links and by a decrease of condensate density in neighboring regions.     

Preslaughter handling, stunning and slaughter

This paper reviews some of the recent developments in scientific research into preslaughter handling, transport, stunning and slaughter. Particular emphasis has been placed on work published within the past 2 years, and on the welfare and meat quality aspects of the subject.     

Engineering linear F(ab')2 fragments for efficient production in Escherichia coli and enhanced antiproliferative activity

We developed a novel bivalent antibody fragment, the linear(L-) F(ab')₂, comprising tandem repeats of a heavy chain fragmentV_H–C_H1–V_H–C_H1 cosecreted with a light chain.Functional humanized L-F(ab')₂ directed against p185^HER2 wassecreted from Escherichia coli at high titer (100 mg/l) andpurified to homogeneity. The L-F(ab')₂ binds two equivalentsof antigen with an apparent affinity (K_d = 0.46 nM) that iswithin 3-fold of the corresponding thioether-linked F(ab')₂fragment The N-terminal site binds antigen with an affinity(K_d = 1.2 nM) that is 4-fold greater than that for the C-terminalsite, as shown by the comparison of L-F(ab')₂ variants containinga single functional binding site. L-F(ab')₂ has greater antiproliferativeactivity than the thioether-linked F(ab')₂ against the p185^HER2-overexpressingtumor cell line BT474. Linear and thioether-linked F(ab')₂ havevery similar pharmacokinetic properties in normal mice, andtheir serum permanence times are respectively 7- and 8-foldlonger than the corresponding Fab fragment L-F(ab')₂ offersa facile route to bivalent antibody fragments that are potentiallysuitable for clinical applications, and that may have improvedbiological activity compared with thioether-linked F(ab')₂ fragments.     

Welfare of calves - 2. Increase in vertebral artery blood flow following exsanguination by neck sticking and evaluation of chest sticking as an alternative slaughter method

The role of the vertebral arteries in delaying loss of sensibility following neck sticking in slaughter calves was investigated. Vertebral artery blood flow was measured using probes before, during and after electrical stunning and slaughter. Systemic blood pressure, electrocorticogram, visually evoked responses and the occurrence of carotid occlusions were also recorded. When carotid occlusion occurred, the time to onset of brain failure was delayed based on the development of an isoelectric state. In addition, when carotid occlusion occurred the mean arterial blood pressure was sustained for longer following slaughter, and concurrently vertebral artery blood flow could be maintained at about 30% of its initial level for up to 3 min. In some animals vertebral artery flow increased substantially following sticking. When chest sticking was used no occlusion of vessels occurred, mean arterial blood pressure fell promptly (within 8 s) and the onset of an isoelectric state did not extend beyond one minute. In addition, visually evoked responses were not present after 5 s following chest sticking.