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951.
G Hendrickson R K Anderson P D Clayton J Cimino G M Hripcsak S B Johnson M McCormack S Sengupta S Shea R Sideli 《M.D. computing : computers in medical practice》1992,9(1):35-42
Over the past seven years, Columbia-Presbyterian Medical Center has been planning and implementing an integrated academic information management system. Accomplishments to date include establishing an institutional information architecture, installing a campus-wide network of workstations, recruiting the staff needed to develop and implement the system, and developing various applications. This paper presents the rationale and steps involved in these accomplishments, as well as data on use of the system so far. 相似文献
952.
Summary The cationic polymerization of 2-ethyl-2-oxazoline using CH3I as initiator at different monomer/initiator ratios, temperatures, solvents and times of polymerization was carried out. The effect of these variables on the polymerization yield and viscosity of the polymers was studied. The poly(N-propionyl)iminoethylene was hydrolyzed in acid medium obtaining a linear poly(ethyleneimine) (PEI). All the polymers were characterized by elemental analysis, IR,1H NMR, and13C NMR spectroscopy. 相似文献
953.
A computational survey of the various univariate and multivariate learning curve models that have evolved over the past several years is presented. Discussions are presented to show how the models might be used for cost analysis or productivity assessment in engineering management. A computational experiment comparing a univariate model to a bivariate model is presented. While the bivariate model provides only a slightly better fit than the univariate model, it does provide more detailed information about the factor interactions, and better utilization of available data. The results of the computational experiment can be generalized for the appropriateness of multivariate models 相似文献
954.
Summary Sedimentation experiments and X-ray photoelectron spectroscopy (XPS or ESCA) analyses have been used to study the effect of poly(methylmethacrylate) (PMMA) tacticity on aluminum oxide powder dispersion stability in a common solvent medium. The relative trends from sedimentation densities, and from surface analyses after solvent washing show that (PMMA) adsorption is greatest with isotactic polymer, where isotactic>atactic>syndiotactic adsorption. These results suggest that surface adsorption and hence dispersion stability can be influenced by polymer chain configuration as well as by chain conformation. 相似文献
955.
P Oroszlan S Wicar G Teshima S L Wu W S Hancock B L Karger 《Analytical chemistry》1992,64(14):1623-1631
This paper examines the retention behavior of recombinant DNA-derived human growth hormone (rhGH) in reversed-phase chromatography and its separation from the closely related N-methionyl variant (Met-hGH). It is first shown that retention for rhGH decreases with increasing column temperature when 1-propanol (1-PrOH) is used as organic modifier. On the other hand, retention increases with temperature when acetonitrile (CH3CN) is employed. The differences in behavior for the two organic modifiers could be related to conformational changes in the protein as determined by solution and adsorption intrinsic fluorescence spectroscopy. Specifically, desorption and elution of rhGH using 1-PrOH could be correlated with a solvent-induced conformational change, with retention decreasing with increasing temperature due to the increasing ease of structural alteration. On the other hand for CH3CN the increase in retention correlated with temperature rise was related to a partial structural change yielding a more hydrophobic species. In this case, a surface-driven process is suggested. The work then turned to the separation of rhGH and Met-hGH where it was found for both organic modifiers optimum separation occurred at 45 degrees C and pH 6.5. Separate studies revealed that during the conformational change Met-hGH appeared more hydrophobic than rhGH since protein-protein aggregation was observed at a lower 1-PrOH concentration. It is suggested that this hydrophobic difference, which was optimized under the conditions cited above, resulted in the separation. The study demonstrates the importance of conformational changes in retention behavior and separation of protein samples. 相似文献
956.
The present study was aimed at understanding the response of 2014 Al alloy dispersed with graphite particles in various corrosive environments. Marine (sodium chloride) as well as acidic media were selected for the purpose with a view to widen the range of utility of the composite for applications where such environments may be encountered. Studies were also extended to characterize the corrosion resistance of the composite in fresh as well as used lubricating oils to explore the possibilities of using it in bearing, bushing and such other applications. The corrosion behaviour of the base alloy processed under identical conditions was also examined in the above media to see the influence of graphite addition in the alloy. In order to assess the role of the matrix microstructure, the composite as well as the base alloy was subjected to corrosion in heat-treated as well as-cast conditions. It was observed that the specimens suffered from the maximum rate of corrosion in acid, while sodium chloride produced the minimum corrosion rate. Oil in both used and fresh conditions revealed a negligibly small extent of corrosion. The composite was found to show a higher rate of corrosion than the base alloy under identical test conditions. This was attributed to the dispersoid/matrix interfacial corrosion in the case of the graphitic aluminium alloy. Heat treatment of the composite and the base alloy was found to lower the rate of corrosion in the environments tested. Microstructural modifications of the matrix and possible relief of residual stresses were thought to be responsible for the lower rate of corrosion in the heat-treated condition. 相似文献
957.
We report on first computations considering effects of a rough wall on the counterflow state in superfluid 3He-B for high flow velocities. Using the quasiclassical Green's-function formalism supplemented by the boundary conditions for a diffusive wall, we calculate the order-parameter field and the supercurrent near a container wall for various pressures and temperatures. One of our results is that the current density at the wall as a function of the flow has a maximum at the velocity which is about half of the pair breaking velocity. 相似文献
958.
Choosing a standard speed for visual inspection is difficult using standard work measurement techniques. This paper uses a different approach, taking a model of human functioning in inspection and deriving an optimum speed of working so as to balance the cost of time against the cost of errors. Random search is used as the model and both self-paced and externally-paced conditions are derived for multiple fault types. Optimization using a Golden Section search is used to provide optimum inspection speed. 相似文献
959.
W. Chen S. -H. Wang R. Chu F. King T. R. Jack R. R. Fessler 《Metallurgical and Materials Transactions A》2003,34(11):2601-2608
A study was carried out to understand the effect of precyclic loading on stress-corrosion-crack initiation in an X-65 pipeline
steel exposed to a near-neutral-pH soil environment. The test specimens were precyclically loaded before corrosion exposure
to represent a service history of up to about 20 years, depending on the severity of pressure fluctuation. Microcracks had
initiated on the polished surface of the X-65 pipeline steel after long-time exposure at open-circuit potential (OCP) in a
near-neutral-pH synthetic soil solution. These microcracks were mostly initiated from pits at metallurgical discontinuities
such as grain boundaries, pearlitic colonies, and banded phases in the steel. Strong preferential dissolution was observed
along planes of the banded structures in the steel. The selective corrosion attack at these metallurgical discontinuities
is attributed to the galvanic nature of those areas to their neighbors. Cyclic loading prior to corrosion exposure had significant
effects on microcrack initiation and propagation during subsequent corrosion exposure. Cyclic loading prior to corrosion exposure
either reduced or increased the probability of crack initiation and the rate of crack propagation, depending upon the magnitude
of the stress cycles. The largest reduction was seen at a peak cyclic stress of about 0.8 of the yield strength. This cyclic-loading-dependent
cracking behavior might be related to the alteration of the substructures and the residual stress in the steel as a result
of precyclic loading. 相似文献
960.
Deterioration of concrete or reinforcing steel through excessive contaminant concentration is often the result of repeated
wetting and drying cycles. At each cycle, the absorption of water carries new contaminants into the unsaturated concrete.
Nuclear Magnetic Resonance (NMR) is used with large concrete samples to observe the shape of the wetting profile during a
simple one-dimensional wetting process. The absorption of water by dry concrete is modelled by a nonlinear diffusion equation
with the unsaturated hydraulic diffusivity being a strongly nonlinear function of the moisture content. Exponential and power
functions are used for the hydraulic diffusivity and corresponding solutions of the diffusion equation adequately predict
the shape of the experimental wetting profile.
The shape parameters, describing the wetting profile, vary little between different blends and are relatively insensitive
to subsequent re-wetting experiments allowing universal parameters to be suggested for these concretes.
Résumé La détérioration du béton ou du béton armé à travers la concentration excessive de contaminant est souvent le résultat de cycles humides et secs répétés. A chaque cycle, l'absorption de l'eau amène de nouveaux contaminants à l'intérieur du béton non saturé en eau. Pour observer le profil du processus d'humidification, on peut utiliser la Résonance Magnétique Nucléaire (RMN) sur de grands échantillons de béton dans le cadre d'une simple étude unidimensionnelle de ce profil. Il est démontré que l'absorption d'eau par du béton sec peut être précisément modélisée par une équation de diffusion non linéaire où la diffusivité hydraulique non saturée est fonction hautement non linéaire de l'humidité du contenant. Des fonctions exponentielles et puissances peuvent définir la diffusivité hydraulique. Les solutions résultant de l'équation modélisant cette diffusion permettent de prédire avec précision la forme du profil de l'humidification expérimentale. Les paramètres de forme qui décrivent le profil de l'humidification varient peu entre les différents mélanges de béton et sont relativement insensibles à des expériences de réhumidification ultérieures. Cela permet de suggérer que ces bétons suivent des paramètres d'humidification universels.相似文献