Using association rules to assess purchase probability in online stores

The paper addresses the problem of e-customer behavior characterization based on Web server log data. We describe user sessions with the number of session features and aim to identify the features indicating a high probability of making a purchase for two customer groups: traditional customers and innovative customers. We discuss our approach aimed at assessing a purchase probability in a user session depending on categories of viewed products and session features. We apply association rule mining to real online bookstore data. The results show differences in factors indicating a high purchase probability in session for both customer types. The discovered association rules allow us to formulate some predictions for the online store, e.g. that a logged user who has viewed only traditional, printed books, has been staying in the store from 10 to 25 min, and has opened between 30 and 75 pages, will decide to confirm a purchase with the probability of more than 92 %.

     

Influence of aluminium electrode preparation on PCE values of polymeric solar cells based on P3HT and PCBM

The main goal of the paper was investigation of influence of aluminum electrode preparation via thermal evaporation (TE) and the magnetron sputtering (MS) on power conversion efficiency (PCE) of polymeric solar cells. The photovoltaic properties of such three kinds devices based on poly(3-hexylthiophene-2,5-diyl) (P3HT) as ITO/P3HT/Al, ITO/P3HT:PCBM (1:1, w/w)/Al and ITO/PEDOT:PSS/P3HT:PCBM (1:1, w/w)/Al were investigated. For the constructed devices impedance spectroscopy were analyzed. For devices lack of PEDOT:PSS layer or lack of PCBM, photovoltaic parameters were very low and similar to the parameters obtained for device with Al electrode prepared by magnetron sputtering. The devices comprising PEDOT:PSS with P3HT:PCBM showed the best photovoltaic parameters such as a V_OC of 0.60 V, J_SC of 4.61 mA/cm², FF of 0.21, and PCE of 5.7 × 10^?1%.     

Fabrication of nanoporous TiO2 by electrochemical anodization

The formation of self-organized porous titania is achieved by electrochemical anodization under a potentiostatic regime. Anodic titanium oxide (ATO) was fabricated by a three-step self-organized anodization of the Ti foil in an ethylene glycol electrolyte containing 0.38 wt% of NH₄F and 1.79 wt% of H₂O. Anodizing was carried out at the constant cell potential ranging from 30 to 70 V at the temperature of 20 °C. It was found that nanoporous TiO₂ arrays can be obtain only after a short duration of the third step (10 min). The influence of anodizing potential on the structural parameters of porous anodic titania including pore diameter, interpore distance, wall thickness, porosity and pore density was extensively studied. The linear dependencies between interpore distance, pore diameter and wall thickness upon the anodizing potential were found. The regularity of pore arrangement was monitored qualitatively by fast Fourier transforms (FFTs) of top-view FE-SEM images. It was found that the best arrangement of nanopores is observed at 40 V. This finding was confirmed by the analysis of pore circularity. The highest circularity of pores was observed once again at 40 V.     

The Particle Image Velocimetry Experimental Study of Flame Extinction in Standard Square Flammability Column Resulting From Stretching

The main goal of this work is to determine experimentally local stretching rate distribution along the limits of methane/air and propane/air flames, using particle image velocimetry (PIV). This method allows obtaining necessary moving flame velocity fields in a standard flammability column and also recognition of the flame structures. For this purpose each mixture was seeded with MgO particles (of known size) before entering the tube (column), using a special system. The amount of seeds in the mixture, their dispersion system, and the laser power producing a sheet of light penetrating the column were carefully chosen (so as not to disrupt the combustion or flame propagation in it). After a learning process, this finally it allowed us obtain good-quality velocity field images in the region of concern, images acceptable for further processing. The methodology developed for these experiments proved to be reliable and able to supply analyses with repeatable data. On the basis of performed experiments it was possible to derive the flame stretching rate that causes its extinction in both mixtures.     

Anti‐corrosion additive for concrete

The Building Research Institute in Warsaw has developed an organic concrete additive, known as Dikszopt, which is derived from tanning oak extract. Tests, mostly in the laboratory but some in application trials, show that it has a remarkable ability to protect reinforcing steel against corrosion, notably in carbonized concrete. It also appears to improve the consistency of the concrete mix and retard the setting time, as discussed in this article from the Institute.     

Calcium Ions Regulate K+ Uptake into Brain Mitochondria: The Evidence for a Novel Potassium Channel

The mitochondrial response to changes of cytosolic calcium concentration has a strong impact on neuronal cell metabolism and viability. We observed that Ca²⁺ additions to isolated rat brain mitochondria induced in potassium ion containing media a mitochondrial membrane potential depolarization and an accompanying increase of mitochondrial respiration. These Ca²⁺ effects can be blocked by iberiotoxin and charybdotoxin, well known inhibitors of large conductance potassium channel (BK_Ca channel). Furthermore, NS1619 – a BK_Ca channel opener – induced potassium ion–specific effects on brain mitochondria similar to those induced by Ca²⁺. These findings suggest the presence of a calcium-activated, large conductance potassium channel (sensitive to charybdotoxin and NS1619), which was confirmed by reconstitution of the mitochondrial inner membrane into planar lipid bilayers. The conductance of the reconstituted channel was 265 pS under gradient (50/450 mM KCl) conditions. Its reversal potential was equal to 50 mV, which proved that the examined channel was cation-selective. We also observed immunoreactivity of anti-β₄ subunit (of the BK_Ca channel) antibodies with ~26 kDa proteins of rat brain mitochondria. Immunohistochemical analysis confirmed the predominant occurrence of β₄ subunit in neuronal mitochondria. We hypothesize that the mitochondrial BK_Ca channel represents a calcium sensor, which can contribute to neuronal signal transduction and survival.     

Numerical modelling of radiative heat transfer in an internal indirect reforming-type SOFC

The present paper describes numerical modelling of the radiative heat transfer process in the module chamber of an internal indirect reforming-type SOFC. The ability to do internal reforming is one of the characteristics of high-temperature fuel cells, SOFC. As in any high-temperature system, radiative heat transfer is important. In this article, heat transfer between the fuel reformer surface and all other surfaces facing the reformer surfaces is modelled. Governing equations for radiative heat transfer are described using Hottel's zone method. The resulting radiation–conduction conjugate heat transfer problems are numerically solved with a combination of Gauss–Seidel and Newton–Raphson methods. The steam reforming reaction occurring inside the fuel reformer is described using Achenbach model. The obtained results indicate that, for the development of effective indirect internal reforming, the position of the reformer in the module chamber and emissivity of the surfaces of the reformer, cell and other elements in the SOFC module all play a key role.     

Structure and properties of 6061 + 26 mass% Si aluminum alloy produced via coupled rapid solidification and KOBO-extrusion of powder

Experiments on mechanical consolidation of rapidly solidified (RS) powder of 6061 + 26 mass% Si alloy were performed using the oscillating-die extrusion method. The RS powder was wrapped in thin-wall 6061-alloy cup 35 mm in diameter and vacuum-compressed by means of 100 ton press. Bars 8 mm in diameter were extruded with cross-section reduction of λ = 19 without any preheating of the charge. Tubes with a diameter/wall thickness of 14 mm/1 mm and cross-section reduction of λ = 33 were also manufactured with success. TEM/STEM observations revealed a very fine structure of as-extruded material and bimodal distribution of quasi-spherical silicon particles. Statistical analysis revealed a silicon fine fraction of 0.1–0.7 μm and a coarse fraction 2.1–2.5 μm in diameter. Examination by means of TEM did not reveal any significant changes in the morphology of the silicon particles, even when a high extrusion ratio and the material annealing after deformation were used. Hot compression tests on as-extruded rods (λ = 19) and preliminary annealed samples were performed at a constant true strain rate of 5 × 10^?3 s^?1 within the temperature range of 293–823 K. High strength of the material and relatively high ductility of samples deformed by compression up to ?_t ? 0.4 were observed. The maximum flow stress value for as-extruded material was reduced with deformation temperature from ～390 to ～3.5 MPa for 293 and 823 K, respectively. Annealing of the samples at 773 K/30 min was found to reduce the maximum flow stress by 30–40%. Tensile strengths of similar as-cast alloys and materials manufactured by means of other powder metallurgy methods were shown for the purpose of comparison.