Gradient “Single-Crystal” Li-Rich Cathode Materials for High-Stable Lithium-Ion Batteries

As one of the high-energy cathode materials of lithium-ion batteries (LIBs), lithium-rich-layered oxide with “single-crystal” characteristic (SC-LLO) can effectively restrain side reactions and cracks due to the reduced inner boundaries and enhanced mechanical stabilities. However, there are still high challenges for SC-LLO with diverse performance requirements, especially on their cycle stability improvement. Herein, a novel concentration gradient “single-crystal” LLO (GSC-LLO), with gradually decreasing Mn and increasing Ni contents from center to surface, is designed and prepared by combining co-precipitation and molten-salt sintering methods, yielding a capacity retention of 97.6% and an energy density retention of 95.8% within 100 cycles at 0.1 C. The enhanced performance is mostly attributed to the gradient-induced stabilized structure, free of cracks and less spinel-like structure formation after long-term cycling. Furthermore, the gradient design is also beneficial to the safety of LLOs as suggested by the improved thermal stability and reduced gas release. This study provides an effective strategy to prepare high-energy, high-stability, and high-safety LLOs for advanced LIBs.     

Hybrid Catalyst Coupling Zn Single Atoms and CuNx Clusters for Synergetic Catalytic Reduction of CO2

Reverse water-gas shift (RWGS) reaction is the initial and necessary step of CO₂ hydrogenation to high value-added products, and regulating the selectivity of CO is still a fundamental challenge. In the present study, an efficient catalyst (CuZnN_x@C-N) composed by Zn single atoms and Cu clusters stabilized by nitrogen sites is reported. It contains saturated four-coordinate Zn-N₄ sites and low valence CuN_x clusters. Monodisperse Zn induces the aggregation of pyridinic N to form Zn-N₄ and N₄ structures, which show strong Lewis basicity and has strong adsorption for *CO₂ and *COOH intermediates, but weak adsorption for *CO, thus greatly improves the CO₂ conversion and CO selectivity. The catalyst calcined at 700 °C exhibits the highest CO₂ conversion of 43.6% under atmospheric pressure, which is 18.33 times of Cu-ZnO and close to the thermodynamic equilibrium conversion rate (49.9%) of CO₂. In the catalytic process, CuN_x not only adsorbs and activates H₂, but also cooperates with the adjacent Zn-N₄ and N₄ structures to jointly activate CO₂ molecules and further promotes the hydrogenation of CO₂. This synergistic mechanism will provide new insights for developing efficient hydrogenation catalysts.     

多姿态图像生成的行人重识别算法研究

不同行人的高度相似性以及相同行人外观姿态的差异性,使得不同摄像头下的行人重识别面临严峻的挑战。生成对抗网络可以合成新的图像,被认为是解决行人姿态变化的主要技术手段。提出一种基于多姿态图像生成的行人重识别算法,利用生成对抗网络生成不同姿态的行人图像,通过归一化消除姿态的影响,从而大幅度提升行人重识别的整体性能。该行人重识别算法包括多姿态行人图像生成、不同姿态的行人特征提取与融合、距离度量和重排序三部分内容。在Market-1501数据集和DukeMTMC-ReID数据集上的实验证实了所提出算法的有效性,通过与state-of-the-art行人重识别方法比较,展示了多姿态图像生成方法在行人重识别任务中的优越性,同时表明生成行人图像的特征与原始图像的特征是相互补充的。     

Adaptive fault-tolerant control for a class of flexible air-breathing hypersonic vehicles

In this paper, a novel adaptive fault-tolerant control (FTC) scheme is proposed for a class of flexible air-breathing hypersonic vehicles with unknown inertial and aerodynamic parameters and even input constraints. The fault model under consideration covers the case that all actuators suffer from unknown time-varying faults. In the controller design and stability analysis, we introduce new Lyapunov functions, some differentiable auxiliary functions, a bound estimation approach, and a Nussbaum function, which help us successfully circumvent the obstacle caused by the faults, input constraints, and flexible modes. In addition to higher reliability, the proposed scheme is able to ensure that all closed-loop signals are globally uniformly bounded and to steer the tracking errors of altitude and velocity into predefined arbitrarily small residual sets. As a result, the tracking accuracy can be designated in advance. Simulation results illustrate the effectiveness of the proposed scheme.     

基于深度学习的航拍光伏板红外图像热斑检测方法研究

针对光伏电站光伏板热斑故障难以检测的问题,结合无人机巡检技术,提出一种基于深度卷积神经网络的光伏板热斑快速检测方法。首先设计了光伏板识别模型,将Yolov4主干特征提取网络替换成轻量级网络MobileNetV2,并将PAnet网络中标准3×3卷积替换为深度可分离卷积,实现了将光伏板快速从红外图像中识别出来。为快速识别热斑并解决光伏板反光噪声问题,将MobileNetV2网络引入DeeplabV3+模型中,改进由于下采样造成的目标缺失,并将交叉熵损失函数修改为Dice损失函数来进一步提高分割精度。试验结果表明,该方法能够准确识别光伏板热斑,光伏板识别准确率为99. 56%,检测速度为22. 1帧/秒。光伏板识别后的热斑分割准确度达到95. 99%,交并比mIou达到85. 58,检测速度为24. 5帧/秒,该方法能够满足光伏板故障检测的需要。     

Reprogrammable Assembly of Molecular Motor on Solid Surfaces via Dynamic Bonds

Controllable assembly of molecular motors on solid surfaces is a fundamental issue for providing them to perform physical tasks. However, it can hardly be achieved by most previous methods due to their inherent limitations. Here, a general strategy is designed for the reprogrammable assembly of molecular motors on solid surfaces based on dynamic bonds. In this method, molecular motors with disulfide bonds can be remotely, reversibly, and precisely attached to solid surfaces with disulfide bonds, regardless of their chemical composition and microstructure. More importantly, it not only allows encoding geometric information referring to a pattern of molecular motors, but also enables erasing and re‐encoding of geometric information via hemolytic photocleavage and recombination of disulfide bonds. Thus, solid surfaces can be regarded as “computer hardware”, where molecular motors can be reformatted and reprogramed as geometric information.     

Testing Transverse Sensitivity of Linear Single-Axis Pendulous Accelerometer with Double Turntable Centrifuge

Current ISO standard methods for testing transverse sensitivity of accelerometers are vibration-based. They have difficulties in producing low-frequency vibration for various reasons. This paper introduces a double turntable centrifuge (DTC) to test the accelerometer transverse sensitivity at low frequencies (from 0.01 to 10 Hz). The proposed method can avoid limitations of traditional vibration-based schemes for transverse sensitivity test. In this paper, a theoretical analysis of the method is followed by a presentation of the experimental set-up, and the measurement procedure of a linear single-axis pendulous accelerometer. According to the theoretical analysis and experimental results, it is practicable to test the low-frequency transverse sensitivity with a DTC. The method proposed here can test accelerometer transverse sensitivity at low-frequency with large amplitudes (up to 700 m/s²), and directly measure the angle of the transverse sensitivity with high resolution. It can be a supplement to the standard methods for testing accelerometer transverse sensitivity at low-frequency.     

加强计量信息化建设,提高企业计量管理水平

网络化的计量管理信息系统在技术上的实用性和维护性上面都有其可靠性,对计量管理工作采用信息化管理可以真正实现完全意义上的信息共享,使我们管理的计量装置、计量器具准确可靠的运行。