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231.
The copolymerization of carbazole (CZ) and 3‐methylthiophene (3MeT) was successfully performed electrochemically in freshly distilled boron trifluoride diethyl etherate by direct anodic oxidation of the monomer mixtures, although the oxidation potentials of CZ and 3MeT were quite different. The electrochemical properties of the copolymers were studied with cyclic voltammetry. The influence of the applied polymerization potential on the synthesis of the copolymers was investigated. The higher potential favored the incorporation of 3MeT units into the copolymers. The insertion of 3MeT units into polycarbazole (PCZ) was helpful in improving the conductivity of PCZ. The novel copolymers had the advantages of both PCZ and poly(3‐methylthiophene), that is, good redox activity, good thermal stability, and high conductivity. The structure and morphology of the copolymers were investigated with ultraviolet–visible, infrared spectroscopy, thermal analysis, and scanning electron microscopy. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 1877–1885, 2006 相似文献
232.
针对企业电力负荷随机性强、稳定性低、预测精度不理想等问题,提出了一种基于最大偏差相似性准则的BP神经网络短期电力负荷预测算法。首先对最大偏差相似性准则算法进行修改,并提出使用预测日的负荷特征向量与最大偏差相似性准则算法聚类之后的类中心负荷特征的距离来确定预测日的相似日类别;然后将聚类后的相似日类别负荷数据作为BP网络的训练数据,输出预测日起始的连续三天96整点负荷值。实验表明,该方法提出的短期电力负荷预测方法在精度和网络训练时间上都有较大的提升,具有较高的有效性和实用性。 相似文献
233.
稀土BR/SBR共混胶的性能 总被引:1,自引:0,他引:1
研究了4种共混比的LnBR/SBR共混生胶、混炼胶及硫化胶的性能,并与NiBR/SBR共混胶进行了对比。结果表明,共混生胶的ML均低于LnBR及SBR;当LnBR/SBR共混混炼胶的ML、剪切应力、出口膨胀及硫化速度均低于NiBR/SBR共混胶,挤出物外观优于后者;共混硫化胶的拉伸强度、热空气老化、拉伸疲劳、湿滑、耐磨等性能均明显优于后者,生热和透气率高于后者。 相似文献
234.
Pengbao Lian Qiang Liu Lizhen Chen Cai Cao Jiaxiang Zhao Jianlong Wang 《中国化学工程学报》1982,28(10):2634-2639
In this paper, the solubility of 4-nitroimidazole in twelve pure solvents (toluene, benzene, 1,4-dioxane, acetonitrile, ethyl acetate, acetone, GBL, ethanol, methanol, n-butanol, DMF and NMP) were determined by using the laser monitoring system from 278.15 K to 323.15 K under 101.1 kPa, which are 0.00018-0.00070, 0.00021-0.00073, 0.00034-0.00092, 0.00038-0.00142, 0.00047-0.00120, 0.00126-0.00303, 0.00225-0.00517, 0.00310-0.00724, 0.00467-0.00982, 0.00453-0.01940, 0.01947-0.04652, and 0.04670-0.07452, respectively. At constant temperature, the mole fraction solubility of 4-nitroimidazole were increased as the following order: toluene < benzene < 1,4-dioxane < (ethyl acetate or acetonitrile) < acetone < GBL < ethanol < (methanol or nbutanol) < DMF < NMP, and the solubility of 4-nitroimidazole in (ethyl acetate, acetonitrile) and (methanol, n-butanol) had an intersection point at 297.55 K and 281.85 K, respectively. The solubility of 4-nitroimidazole could be increased with increasing temperature in twelve pure solvents. The ideal model, modified Apelblat equation, polynomial empirical equation, and λh equation were used to correlate the experimental values. The experimental solubility values were employed to calculate the standard dissolution enthalpy, standard dissolution entropy and Gibbs energy. The dissolution of 4-nitroimidazole could be an endothermic process in twelve pure solvents. The determination and fitting solubility of 4-nitroimidazole have important guiding significance for the purification and crystallization of its preparation process. 相似文献
235.
Ye Cai ré Zimmermann Arndt Bauer Fritz Aldinger 《Journal of the American Ceramic Society》2003,86(9):1598-1600
Precursor-derived Si-C-N ceramics after creep testing in air were characterized using X-ray diffractometry (XRD) and transmission electron microscopy (TEM). XRD analysis showed that the crept Si-C-N ceramics were covered by an α-cristobalite layer. TEM observations revealed that the precipitated nanocrystallites in the crept Si-C-N ceramics were β-SiC. Between α-cristobalite and crept Si-C-N ceramic, there was an intermediate zone in which Si2 N2 O nanocrystallites were distributed homogeneously. Moreover, Si2 N2 O nanocrystallites were often found covering the surface of nanosized gas channels in the crept Si-C-N ceramics, where no α-cristobalite phase was detected. Based on these observations, a two-step oxidation mechanism of Si-C-N ceramics during creep testing in air was proposed. 相似文献
236.
Flaky monoclinic La2Ti2O7 was prepared via a hydrothermal method based on the reaction of Ti(SO4)2 and La(NO3)3. Relative to the solid-state reaction sample, the flaky La2Ti2O7 showed higher surface areas, much smaller crystal size and more efficient light absorption. All these factors led to the
higher photoactivity to produce H2 from water splitting under UV irradiation. 相似文献
237.
油田废水电解杀菌研究 总被引:1,自引:0,他引:1
采用电解杀菌技术处理油田废水,研究了电解时间、电流强度、极板间距以及电极联结方式等因素对废水中硫酸盐还原菌杀灭效果的影响。结果表明,油田废水经3min电解杀菌,硫酸盐还原菌杀灭率高达99.90%。随着电解时间的增加,硫酸盐还原菌的杀菌率进一步提高;电流强度增加,硫酸盐还原菌的杀灭率升高。在电流强度保持不变的情况下,随着极板间距增加,极板之间电压升高,更有利于杀灭硫酸盐还原菌。在极板间电流强度相同的条件下,两种电极联结方式的杀菌率差别不大,杀菌率均在99.9%以上。 相似文献
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