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101.
Santosh K. Gupta Maya Abdou Partha S. Ghosh Jose P. Zuniga Ezhilarasan Manoharan HyeongJun Kim Yuanbing Mao 《Journal of the American Ceramic Society》2020,103(1):235-248
Unveiling the underlying mechanisms of properties of functional materials, including the luminescence differences among similar pyrochlores A2B2O7, opens new gateways to select proper hosts for various optoelectronic applications by scientists and engineers. For example, although La2Zr2O7 (LZO) and La2Hf2O7 (LHO) pyrochlores have similar chemical compositional and crystallographic structural features, they demonstrate different luminescence properties both before and after doped with Eu3+ ions. Based on our earlier work, LHO-based nanophosphors display higher photo- and radioluminescence intensity, higher quantum efficiency, and longer excited state lifetime compared to LZO-based nanophosphors. Moreover, under electronic O2−→Zr4+/Hf4+ transition excitation at 306 nm, undoped LHO nanoparticles (NPs) have only violet blue emission, whereas LZO NPs show violet blue and red emissions. In this study, we have combined experimental and density functional theory (DFT) based theoretical calculation to explain the observed results. First, we calculated the density of state (DOS) based on DFT and studied the energetics of ionized oxygen vacancies in the band gaps of LZO and LHO theoretically, which explain their underlying luminescence difference. For Eu3+-doped NPs, we performed emission intensity and lifetime calculations and found that the LHOE NPs have higher host to dopant energy transfer efficiency than the LZOE NPs (59.3% vs 24.6%), which accounts for the optical performance superiority of the former over the latter. Moreover, by corroborating our experimental data with the DFT calculations, we suggest that the Eu3+ doping states in LHO present at exact energy position (both in majority and minority spin components) where oxygen defect states are located unlike those in LZO. Lastly, both the NPs show negligible photobleaching highlighting their potential for bioimaging applications. This current report provides a deeper understanding of the advantages of LHO over LZO as an advanced host for phosphors, scintillators, and fluoroimmunoassays. 相似文献
102.
Novel near white light emitting Y2CaZnO5 (YCZ) nanocrystalline powders doped with Dy3+ ions were synthesized via the citrate gel combustion method. The structure of the compound is found to be triclinic with a particle size in the range of 20–30 nm. Luminescence properties have been characterized using photoluminescence (PL), excitation spectra and decay time measurements. The PL spectra have shown a broad blue band due to 4F9/2→6H15/2 transition and sharp yellow band corresponding to 4F9/2→6H13/2 transition of Dy3+ ions. From the concentration dependent PL studies, the optimum concentration of Dy3+ ions in YCZ is found to be 1.0 mol%, where intense near white light emission was observed. The Dy3+:YCZ nanophosphor has shown relatively better white color properties than the reported Dy3+:Y2O3 nanophosphor. The yellow to blue intensity ratios, CIE chromaticity coordinates and correlated color temperature studies have shown the possibility of using this compound for white light emission. 相似文献
103.
Habtamu Deresso Venkata Ramayya Anch Ramesh Babu Nallamothu Balkeshwar Singh Bisrat Yoseph 《哈尔滨工业大学学报(英文版)》2023,30(3):85-94
This paper embraces the key points of unpolluted internally combusted engine emissions. Core objective is focused on the recent effort to improve compression ignition(CI) and spark ignition(SI) engine to have fuel-efficient and minimized pollutant emissions. There are many advanced internal combustion engines to overcome the challenges of conventional compression ignition engines of the high level of particulate matter(PM) and oxides of nitrogen emission. One of the latest options on which many ... 相似文献
104.
The preparation of high‐dielectric poly(styrene‐b‐(ethylene‐co‐butylene)‐b‐styrene) (SEBS) composites containing functionalized single‐walled carbon nanotubes (f‐SWCNTs) noncovalently appended with dibutyltindilaurate are reported herein. Transmission electron microscopy and X‐ray photoelectron and Raman spectroscopy confirmed the noncovalent functionalization of the SWCNTs. The SEBS‐f‐SWCNT composites exhibited enhanced mechanical properties as well as a stable and high dielectric constant of approximately 1000 at 1 Hz with rather low dielectric loss at 2 wt% filler content. The significantly enhanced dielectric property originates from the noncovalent functionalization of the SWCNTs that ensures good dispersion of the f‐SWCNTs in the polymer matrix. The f‐SWCNTs also acted as a reinforcing filler, thereby enhancing the mechanical properties of the composites. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
105.
106.
S. Narendra Babu A. Siddeshwar K. Srinivas S. V. Suryanarayana T. Bhimasankaram 《Journal of Materials Science》2009,44(15):3948-3951
A composite material when placed under the external magnetic/electric fields exhibits voltage/induced magnetization is known
as magnetoelectric (ME) composite. Such composite materials should have ferroelectric and ferro/ferri magnetic phases as constituents.
The magnetoelectric output is exhibited as a product property. Magnetoelectric composites are being used for variety of applications
including resonators, filters, phase shifters, optical isolators, actuators and magnetic field sensors. Metal/ferroelectric/metal
magnetoelectric composite using Ni and PZT as constituent phases has been fabricated in 2-2 composite pattern to study its
product property. The paper presents magnetoelectric studies of Ni/PZT/Ni composite using low dc magnetic field magnetoelectric
set-up. Using this ME set-up ME output of Ni/PZT/Ni composite is studied as a function of dc magnetic field. The results were
analyzed to identify the useful magnetic field (dc and ac) range in which Ni/PZT/Ni sensor can be utilized for applications. 相似文献
107.
Sagar Shankar Jagtap Rupali B. Awhad B. Santosh Pandit B. Vidyasagar 《Microgravity science and technology》2011,23(1):41-48
Microgravity, as a different environment, has been shown to affect plant growth and development (Sievers et al. 1996; Sack 1997). In the present study, effects of slow clinorotation (2 rpm) on growth and chlorophyll content in rice (variety: PRH-10)
seedlings were investigated. Rice seeds were clinorotated continuously for 3, 5 and 7 days under ambient conditions. Root
and shoot lengths and weights of rice seedlings were measured on the third, fifth and seventh day. Chlorophyll was extracted
using N, N-Dimethylformamide (DMF). Absorption and fluorescence spectra of chlorophyll were recorded. Chlorophyll a, chlorophyll
b and total chlorophyll contents were calculated from absorption spectra using Arnon’s method. Results showed an increase
in root and shoot lengths in clinorotated samples. Similar results were obtained for root and shoot weights. Absorption spectra
of chlorophyll showed no shift in the absorption peaks. Chlorophyll content was increased in clinorotated samples as compared
to the controls. Interestingly, the difference between chlorophyll content in control and clinorotated samples decreased as
the number of days of clinorotation increased. Chlorophyll a/b ratio was lowered in clinorotated samples as compared to the
controls. These results suggest that slow clinorotation (2 rpm) affects plant growth and chlorophyll content in rice seedlings. 相似文献
108.
Phase separation has been recognized as important properties of manganite to create colossal magnetoresistance (CMR). Frequency dependence of AC susceptibility and electron spin resonance (ESR) studies confirm the phase separated glassy magnetism in the La0.9Pb0.1MnO3 crystals. ESR spectra exhibit a gradual narrowing of the asymmetric FMR signals upon increasing the temperature and approaching the Curie temperature (Tc). The temperature dependence of line width (ΔHpp), g-factor, double integrated (I) intensity of the resonance signals and frequency dependence peak temperatures are discussed in this paper to explain inhomogeneity in the La0.9Pb0.1MnO3 single crystals. 相似文献
109.
S.A.Saleem B.C.Jamalaiah A.Mohan Babu K.Pavani L.Rama Moorthy 《中国稀土学报(英文版)》2010,28(2):189-193
Glasses with chemical composition of (in mol.%): 26 RF-20 PbO-10 TeO2-43 H3BO3-1 EuO3 (RLTB) were prepared by conventional melt quenching method. The Judd-Ofelt intensity parameters Ω2 and Ω6 were obtained from the absorption intensities of 7F0→5D2 and 7F0→5L6 transitions, respectively. In order to overcome the problem of applicability of Judd-Ofelt analysis at room temperature due to the overlapping of the transitions originating from 7F0 and 7F1 levels of Eu3+ ion, the effect of the thermalization on the population of energy levels was taken into account. The photoluminescence spectra contained five emission bands originating from the 5D0 metastable state to 7FJ (J=0, 1, 2, 3, 4) lower lying states. The decay profiles were found to be single exponential in all the three glasses. The measured lifetimes (τmes) were in good agreement with the calculated lifetimes (τcal) obtained by using the thermally corrected Judd-Ofelt intensity parameters. 相似文献
110.
The sheet‐molding process for the production of poly(methyl methacrylate) (PMMA) involves an isothermal batch reactor followed by polymerization in a mold (the latter is referred to as a “sheet reactor”). The temperature at the outer walls of the mold varies with time. In addition, due to finite rates of heat transfer in the viscous reaction mass, spatial temperature gradients are present inside the mold. Further, the volume of the reaction mass also decreases with polymerization. These several physicochemical phenomena are incorporated into the model developed for this process. It was found that the monomer conversion attains high values of near‐unity in most of the inner region in the mold. This is because of the high temperatures there, since the heat generated due to the exothermicity of the polymerization cannot be removed fast enough. However, the temperature of the mold walls has to be increased in the later stages of polymerization so that the material near the outer edges can also attain high conversions of about 98%. This would give PMMA sheets having excellent mechanical strength. The effects of important operating (decision) variables were studied and it was observed that the heat‐transfer resistance in the mold influences the spatial distribution of the temperature, which, in turn, influences the various properties (e.g., monomer conversion, number‐average molecular weight, and polydispersity index) of the product significantly. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 1951–1971, 2001 相似文献