Use of waste materials--Bottom Ash and De-Oiled Soya, as potential adsorbents for the removal of Amaranth from aqueous solutions

Bottom Ash, a power plan t waste material and De-Oiled Soya, an agriculture waste product were successfully utilized in removing trisodium 2-hydroxy-1-(4-sulphonato-1-naphthylazo)naphthalene-3,6-disulphonate--a water-soluble hazardous azo dye (Amaranth). The paper incorporates thermodynamic and kinetic studies for the adsorption of the dye on these two waste materials as adsorbents. Characterization of each adsorbent was carried out by I.R. and D.T.A. curves. Batch adsorption studies were made by measuring effects of pH, adsorbate concentration, sieve size, adsorbent dosage, contact time, temperature etc. Specific rate constants for the processes were calculated by kinetic measurements and a first order adsorption kinetics was observed in each case. Langmuir and Freundlich adsorption isotherms were applied to calculate thermodynamic parameters. The adsorption on Bottom Ash takes place via film diffusion process at lower concentrations and via particle diffusion process at higher concentrations, while in the case of De-Oiled Soya process only particle diffusion takes place in the entire concentration range.     

Acousto-optic tunable filter sidelobe analysis and reduction with telecentric confocal optics

The acousto-optic tunable filter (AOTF) has optical sidelobes that are due to the acoustic field produced by the transducer. These sidelobes were analyzed by wave-vector phase matching between the optical and acoustic fields, which correlated with measurements made with a TeO2 AOTF. A white-light point source was filtered and imaged, showing reasonably large and slowly decreasing sidelobes covering a large spectral range. This effect reduces the image quality of an AOTF system by producing faint secondary images of bright objects. The image quality can be improved with a telecentric confocal optical arrangement in which the angular shift of the sidelobes is greatly reduced, producing a much sharper image. This effect was also demonstrated experimentally with the point source.     

Detection of photothermal deflection signals with conjugate masks

A new detection technique for photothermal deflection spectroscopy and photoacoustic deflection spectroscopy is presented. The technique uses a pair of matched multiple slits placed in the path of the probe beam and oriented to block the probe light from the detector in the absence of a deflection signal. Significant improvement in the signal-to-noise ratio and in the frequency bandwidth compared with those available with current techniques is demonstrated.     

Novel carbon nanotube-polystyrene foam composites for electromagnetic interference shielding

A novel carbon nanotube-polystyrene foam composite has been fabricated successfully. The electromagnetic interference (EMI) shielding effectiveness measurements indicated that such foam composites can be used as very effective, lightweight shielding materials. The correlation between the shielding effectiveness and electrical conductivity and the EMI shielding mechanism of such foam composites are also discussed.     

Quantitation of carbenicillin disodium, cefazolin sodium, cephalothin sodium, nafcillin sodium, and ticarcillin disodium by high-pressure liquid chromatography

High-pressure liquid chromatographic (HPLC) methods for the quantitation of carbenicillin, cefazolin, cephalothin, nafcillin, and ticarcillin were developed. The stability of 2% solutions of the antibiotics in normal saline and in 5% dextrose in water were studied at 24 and 5 degrees. The assays were conducted using a previously reported colorimetric method, and some assays also were performed using HPLC. For discolored solutions of cephalothin, the colorimetric method was not stability indicating. The percent relative standard deviations by HPLC based on six injections were 1.69, 0.94, 1.30, 1.59, and 1.6 for carbenicillin, cefazolin, cephalothin, nafcillin, and ticarcillin, respectively. Both carbenicillin and ticarcillin apparently may be mixtures of two isomers at equilibrium with each other. The shelflives recommended by the manufacturers at 5 degrees may be too conservative.     

Structure and properties of acrylonitrile-[(2-methacryloyloxy)alkoxy]trimethyl silane copolymers

Dielectric, x-ray diffraction, density, thermomechanical, and thermogravimetric studies on polyacrylonitrile (PAN), poly[acrylonitrile-(2 methacryloyloxy)ethoxytrimethylsilane] [poly(AN-2MAETMS)], and poly[acrylonitrile-(2 methacryloyloxy)propoxytrimethylsilene] [poly(AN-2MAPTMS)] copolymers have been carried out for investigating their structure. The glass transition temperature as indicated from the dielectric and thermomechanical analysis data are lower for the copolymers as compared to PAN. Crystallinity is influenced by the introduction of the silylated acrylic comonomer units but the crystalline lattice remains similar to that of PAN. The changes obseved in the various properties of these coplymers clearly suggest a more closely packed structure of poly(AN-2MAETMS) than poly(AN-2MAPTMS), and the uninterrupted PAN sequences are longer in the former. Thermal stability of copolymers has also been investigated.     

Effect of intragranular porosity of initial permeability and coercive force in a manganese zinc ferrite

Initial permeability and coercive force are structure sensitive properties which depend upon intragranular porosity. It has been found that in a manganese zinc ferrite the initial permeability varies directly as the separation between intragranular pores and the coercive force varies inversely as the square root of this distance. Assuming reversible motion of the domain wall pinned at the pores, the behaviour of initial permeability with respect to the distance between the pores can be adequately explained. It is not possible to give an explanation for the observed relationship between coercive force and the distance between the pores.     

Simulation of reversible nylon-66 polymerization in homogeneous continuous-flow stirred tank reactors

Experimental data of Ogata¹ has been curve-fitted to obtain the forward and reverse rate constants for nylon-66 polymerization. Its molecular weight distribution (MWD) has been simulated in homogeneous continuous-flow stirred tank reactors (HCSTR) for 11 h of residence time when the reaction mass is very close to equilibrium. The set of algebraic equations have been solved using Brown's algorithm,² which was found to be more efficient compared to the Gauss-Jordon techniques of solution. The MWD thus obtained is compared with our earlier simulation of the molecular weight distribution from batch reactors³ and was found to differ significantly. In HCSTR, the weight fraction distribution does not undergo a maximum and the polydispersity index ρ of the polymer formed is much higher than that obtained from batch reactors. The number and weight average of the polymer formed in HCSTR is found to be significantly lower.