材料的表面能与粘接界面的酸碱作用

综述了作者对材料表面能与粘接界面的酸碱作用的研究简况,主要内容包括：（１） 　聚合物表面能的测算;（２） 　金属与无机非金属材料表面能的测算;（３） 　丙烯酰胺（ 丙烯酸） － 天然橡胶接枝聚合物的酸碱作用;（４） 　界面酸碱作用对聚合物抗凝血性能的影响;（５） 　硅烷偶联剂酸碱作用的研究;（６） 　 Ｅ Ｖ Ａ 泡沫材料粘接界面的酸碱作用等。介绍了各有关的研究方法及主要研究结果。     

Particle size distribution effects on gas-particle mass transfer within electrostatic precipitators

Varying degrees of mercury capture and transformation have been reported across electrostatic precipitators (ESPs). Previous analyses have shown that the dominant mass transfer mechanism responsible for mercury capture within ESPs is gas-particle mass transfer during particulate collection. Whereas previous analyses assumed dispersions of uniform size, the present analysis reveals the effects of polydispersity on both gas-particle mass transfer and particle collection within an ESP. The analysis reveals that the idealized monodisperse particle size distribution provides the highest gas-particle mass transfer but results in the lowest particle collection efficiency (% mass). As the particle size distribution broadens, gas-particle mass transfer decreases and particle collection efficiency increases. The results suggest that more than just reporting mean particle diameter provided by the sorbent manufacturer, pilot- and field-tests of sorbent injection for mercury emissions control need to experimentally measure the particle size distribution of the sorbent as it is injected in order to facilitate interpretation of their results.     

A nonlinear model for context-dependent modulation of the binocular VOR

Studies on the behavior of the vestibulo-ocular reflex (VOR) reveal that the monocular reflex gain is adjusted according to target position relative to each eye. In this paper, we present a nonlinear approach in modeling the viewing-context dependency of the slow-phase angular VOR. We show that including appropriate nonlinearities in the responses of premotor neurons in the brainstem is sufficient to account for the online modulation of the VOR with target position. This approach allows very complex behaviors in response to sensory patterns without resorting to currently assumed cortical computations. A local premotor topology with nonlinear properties has repercussions in the study of all ocular reflexes, since it implies context dependent dynamics in all behavioral responses (pursuit, optokinetic, VOR, saccades, etc.) that share this network. Local nonlinearities in spinal circuits could similarly influence the context dependence of other motor systems (such as stretch reflex modulation during rhythmic walking).     

Microsphere templating as means of enhancing surface activity and gas sensitivity of CaCu(3)Ti(4)O(12) thin films

Chemical and physical synthesis routes were combined to prepare macroporous CaCu(3)Ti(4)O(12) thin films by pulsed laser deposition onto poly(methyl methacrylate) (PMMA) microsphere templated substrates. These films showed remarkably enhanced gas sensitivity compared with control films deposited on untreated substrates, demonstrating the virtues of combining thin film physical vapor deposition (PVD) techniques in concert with colloidal templates to produce macroporous structures of inorganic films with enhanced surface activity for applications in chemical sensors, catalysts, and fuel cells.     

Nano-hydroxyapatite/β-tricalcium phosphate ceramics scaffolds loaded with cationic liposomal ceftazidime: preparation, release characteristics in vitro and inhibition to Staphylococcus aureus biofilms

In the current study, nano-hydroxyapatite/β-tricalcium phosphate (HA/β-TCP) ceramics scaffolds loaded with cationic liposomal ceftazidime (CLCs) prepared by modified reverse phase evaporation method, the investigations of their release characteristics were performed by the dissolution tests, in vitro anti-biofilm activity of the scaffolds was studied by the determination of bacterial susceptibility with ELISA. The mean particle size, zeta potential, pH and entrapment efficiency of the CLCs studied were 161.5?±?5.37?nm, 60.60?±?5.24 mV, 6.90?±?0.07 and 16.57?±?0.13%, respectively. Electron microscopic images of the samples indicated that the liposomes were well preserved in the scaffolds and that it was the CLCs rather than free ceftazidime releasing from the scaffolds. The minimal inhibitory concentrations (MICs) to Staphylococcus aureus of free ceftazidime and its liposomal formulation were 6.00 μg/mL and the release behaviors of both CLCs and free ceftazidime from scaffolds were based on the dissolution/diffusion processes, Fick's law. These results demonstrated that CLCs could inhibit remarkably the formation of S. aureus biofilm more effectively than free ceftazidime (P?相似文献   

Atomic-resolution spectroscopic imaging of ensembles of nanocatalyst particles across the life of a fuel cell

The thousand-fold increase in data-collection speed enabled by aberration-corrected optics allows us to overcome an electron microscopy paradox: how to obtain atomic-resolution chemical structure in individual nanoparticles yet record a statistically significant sample from an inhomogeneous population. This allowed us to map hundreds of Pt-Co nanoparticles to show atomic-scale elemental distributions across different stages of the catalyst aging in a proton-exchange-membrane fuel cell, and relate Pt-shell thickness to treatment, particle size, surface orientation, and ordering.     

Negligible particle-specific antibacterial activity of silver nanoparticles

For nearly a decade, researchers have debated the mechanisms by which AgNPs exert toxicity to bacteria and other organisms. The most elusive question has been whether the AgNPs exert direct "particle-specific" effects beyond the known antimicrobial activity of released silver ions (Ag(+)). Here, we infer that Ag(+) is the definitive molecular toxicant. We rule out direct particle-specific biological effects by showing the lack of toxicity of AgNPs when synthesized and tested under strictly anaerobic conditions that preclude Ag(0) oxidation and Ag(+) release. Furthermore, we demonstrate that the toxicity of various AgNPs (PEG- or PVP- coated, of three different sizes each) accurately follows the dose-response pattern of E. coli exposed to Ag(+) (added as AgNO(3)). Surprisingly, E. coli survival was stimulated by relatively low (sublethal) concentration of all tested AgNPs and AgNO(3) (at 3-8 μg/L Ag(+), or 12-31% of the minimum lethal concentration (MLC)), suggesting a hormetic response that would be counterproductive to antimicrobial applications. Overall, this work suggests that AgNP morphological properties known to affect antimicrobial activity are indirect effectors that primarily influence Ag(+) release. Accordingly, antibacterial activity could be controlled (and environmental impacts could be mitigated) by modulating Ag(+) release, possibly through manipulation of oxygen availability, particle size, shape, and/or type of coating.     

Solution-gated graphene field effect transistors integrated in microfluidic systems and used for flow velocity detection

Solution-gated graphene field effect transistors (SGGT) were integrated in microfluidic systems. The transfer characteristics of a SGGT with an Ag/AgCl gate electrode shifted horizontally with the change of the ionic concentration of KCl solution in the microchannel and the relationship can be fitted with the Nernst equation, which was attributed to the change of the potential drop at the Ag/AgCl electrode. Therefore the gate electrode is one important factor for the ion sensitive property of the SGGT. Then SGGTs were used as flow velocity sensors, which were based on measuring the streaming potentials in microfluidic channels. A linear relationship between the shift of the transfer curve of the SGGT and the flow velocity was obtained, indicating that the SGGT is a promising transducer for measuring flow velocity in a microchip. Since the streaming potential is influenced by the three physical quantities, including the flow velocity, the ionic strength of the fluid and the zeta potential of the substrate, the device can be used for sensing any one of the three quantities when the other two were known. It is noteworthy that SGGTs have been used for various types of chemical and biological sensors. Array of the devices integrated in multichannel microchips are expected to find many important applications in the lab-on-a-chip systems in the future.     

A strategy for simultaneously realizing the cubic-to-hexagonal phase transition and controlling the small size of NaYF4:Yb3+,Er3+ nanocrystals for in vitro cell imaging

Hexagonal-phase NaYF(4):Yb(3+),Er(3+) up-conversion nanocrystals (UCNCs) are synthesized by a combination of refluxing and hydrothermal treatment. This strategy leads to only a slight increase in particle size, from 4.5 to ca. 10 nm, during the cubic-to-hexagonal phase transition. The hexagonal UCNCs can be internalized by HeLa cells and exhibit visible emission in the cells under near-infrared excitation.