基于zigbee技术的智能家居控制系统的设计

在ZigBee技术的基础上,设计了一种基于STC12C5A60S2的手持便携式简便智能家居控制终端,并作出底层控制模块的详细硬件设计方案。主ZigBee(coordinator)模块与手持终端连接,从ZigBee(rounter)模块与底层单片机通讯,控制照明系统、窗帘系统、风扇系统和空调系统等。其中着重设计窗帘系统和风扇系统的闭环控制,能够根据光照度和实时温度调节家居内的明暗和温度。该套智能家居模型已搭建并正常运行,通过测试15m之内系统能够较好地通讯,系统硬件成本低,方便使用并具有较好的实用性。     

增强腔在大失谐原子光刻中的应用

对增强腔在大失谐光场原子光刻中的实现进行了详细的讨论 ,通过增强腔对激光光束的压缩和功率的增强可达到近共振原子光刻的要求。数值结果显示相对于近共振原子刻印结果 ,在增强腔下光束中心处沉积的原子条纹宽度将更细 ,为原子刻印提供了一种实现条纹精细度较高的新型方案。     

Surface Oxygen Coordination of Hydrogen Bond Chemistry for Aqueous Ammonium Ion Hybrid Supercapacitor

Aqueous ammonium ion hybrid supercapacitor (A-HSC) combines the charge storage mechanisms of surface adsorption and bulk intercalation, making it a low-cost, safe, and sustainable energy storage candidate. However, its development is hindered by the low capacity and unclear charge storage fundamentals. Here, the strategy of phosphate ion-assisted surface functionalization is used to increase the ammonium ion storage capacity of an α-MoO₃ electrode. Moreover, the understanding of charge storage mechanisms via structural characterization, electrochemical analysis, and theoretical calculation is advanced. It is shown that NH₄⁺ intercalation into layered α-MoO₃ is not dominant in the A-HSC system; rather, the charge storage mainly depends on the adsorption energy of surface “O” to NH₄⁺. It is further revealed that the hydrogen bond chemistry of the coordination between “O” of surface phosphate ion and NH₄⁺ is the reason for the capacity increase of MoO₃. This study not only advances the basic understanding of rechargeable aqueous A-HSC but also demonstrates the promising future of surface engineering strategies for energy storage devices.     

1-氯-1,1-二硝基-2-(N-氯脒基)乙烷的合成、表征和晶体结构

采用高锰酸钾/盐酸体系氧化氨基的方法获得了1-氯-1,1-二硝基-2-(N-氯脒基)乙烷,收率为70%,用核磁、红外、质谱、元素分析等方法对该产物进行了结构表征.以二氯甲烷为溶剂制备出了其单晶,用X射线单晶衍射仪测定了晶体结构.结果表明,该化合物的分子式为C2H2Cl2N4O4,相对分子质量为216.98,该晶体为正交...     

高收率合成3-氨基-4-偕氨肟基呋咱研究

以丙二腈为原料,采用“两段法”合成了3-氨基-4-偕氨肟基呋咱(AAOF),利用红外光谱、核磁共振及元素分析等进行了结构表征;探讨了影响反应的关键因素,发现AAOF在碱性体系易生成钠盐是造成收率偏低的根本原因;优化了合成工艺条件,确定了适宜的反应条件为:亚硝化温度为5 ～10℃,肟化温度为25℃,脱水环化温度为105℃...     

弹道修正弹修正执行机构综述

针对目前我国在弹道修正技术方面的情况,概述了弹道修正弹的修正机构技术,对主要的修正技术进行了分析比较,提出了我国弹道修正机构技术基本的发展思路。     

Understanding Boosted Selective CO2-to-CO Photoreduction with Pure Water Vapor over Hierarchical Biomass-Derived Carbon Matrix

Solar-driven CO₂ reduction reaction (CO₂RR) with water into carbon-neutral fuels is of great significance but remains challenging due to thermodynamic stability and kinetic inertness of CO₂. Biomass-derived nitrogen-doped carbon (N-C_b) have been considered as promising earth-abundant photocatalysts for CO₂RR, although their activities are not ideal and the reaction mechanism is still unclear. Herein, an efficient catalyst is developed for CO₂-to-CO conversion realized on diverse N-C_b materials with hierarchical pore structures. It is demonstrated that the CO₂-to-CO conversion preferentially takes place on positively charged carbon atoms next to pyridinic-N using two representatives treated pollens with the largest difference in pyridinic-N density and N content as model photocatalysts. Systematic experimental results indicate that surface local electric field originating from charge separation can be boosted by hierarchical pore structures, doped N, as well as pyridinic-N. Mechanistic studies reveal that positively charged carbon atoms next to pyridinic-N serve as active sites for CO₂RR, reduce the energy barrier on the formation of CO*, and facilitate the CO₂RR performance. All these benefits cooperatively contribute to treated chrysanthemum pollen catalyst exhibiting excellent CO formation rate of 203.2 µmol h⁻¹ g⁻¹ with 97.2% selectivity in pure water vapor. These results provide a new perspective into CO₂RR on N-C_b, which shall guide the design of nature-based photocatalysts for high-performance solar-fuel generation.     

几种发射分集OFDM系统信道估计方法性能评估

给出了3种基于发射分集的OFDM系统信道估计方法,分别从训练序列对算法的影响、估计准确度、算法复杂度和算法适用性等方面对各自性能作了分析比较,并进行了仿真.分析比较和仿真结果表明,训练序列对3种算法的影响很大,通过训练序列的正交化设计,LS和EM算法可以得到很大程度的简化;EM算法与LS算法估计精度相当,信噪比较大时,多项式模型算法估计精度要远远高于LS和EM算法;总体上来说,多项式模型算法复杂度最高,EM算法复杂度最低.     

铜蒸气激光器的改进及稳定

通过改变放电管中铜粒的位置、放电管外层保温材料的性质和厚度以及对放电产生的电磁辐射进行屏蔽等措施,进一步提高了25W铜蒸气激光器的可靠性和稳定性。     

并行人工蜂群算法研究

针对人工蜂群算法在处理高维度问题时收敛速度慢的问题,利用OpenMP多线程技术和规约机制,并根据已改进的观察蜂来选择雇佣蜂的方式,提出了基于OpenMP的并行人工蜂群算法（PCABC）。仿真实验分别在问题维度为100和200下进行来评估算法性能,在4个逻辑处理器环境下,基于静态调度的并行人工蜂群算法的加速比最高可以达到3.95,效率可达98.65%。实验结果表明,PCABC并行人工蜂群算法在处理高维度复杂函数时,收敛速度和算法运行时间都有较大的提升。