Photosensitized free radical polymerization using pyridinium salts

Summary The polymerization of methyl methacrylate (MMA), ethyl acrylate (EA), styrene (St) and 2-vinyl pyridine (VP) is initiated upon irradiation at >350 nm of dichloromethane solutions containing N-ethoxy-2-methylpyridinium hexafluorophosphate (EMP⁺PF₆ ^-) and anthracene or thioxanthone. Initiation mechanisms involving the formation of ethoxyl radicals during the decomposition of EMP⁺ ions via electron transfer are proposed.     

Evaluation of hydrogen bonding ability of liquids and solids by C-13 NMR. Silica gel as a strong hydrogen bond donor

The chemical shift difference between signals of C() and C() of unsaturated ketones, , which we used before to measure acid strengths, has now been used to evaluate the hydrogen bond donor ability of solvents which are not acidic enough to hydronate the indicator. For such solvents there is no general correlation between H-bond donor ability and acid strength: hexa-fluoroisopropanol is a much weaker acid than acetic acid, but it is a stronger H-bond donor. The method can be applied to evaluate the H-bonding properties of solid surfaces, and it was thus found that silica gel has a much stronger H-bond donor ability than methanol or acetic acid.     

On the design considerations of solid-state power amplifiers for satellite communications: A systems perspective

Conventional solid-state power amplifier (SSPA) design approach isolates radio frequency (RF) design from communication theory. In this paper, a unified SSPA design approach is proposed, which optimizes SSPA parameters (bias voltage and input RF signal power) to minimize total DC power consumption while satisfying received SNR constraint specified by the link budget. The effect of SSPA nonlinearity is quantified by the error vector magnitude measured at its output and the corresponding received SNR degradation is analyzed. Using the quantitative metrics for received SNR, it is possible to evaluate highly nonlinear SSPA classes such as Class-B or deep-Class AB, which are normally not considered in conventional SSPA design approach to be used in satellite communication applications.     

The Training of Pi-Sigma Artificial Neural Networks with Differential Evolution Algorithm for Forecasting

Computational Economics - Looking at the artificial neural networks’ literature, most of the studies started with feedforward artificial neural networks and the training of many feedforward...     

Electrical and Dielectric Properties of Y<Superscript>3+</Superscript>-Substituted Barium Hexaferrites

In this study, Y³⁺ ion-substituted M-type barium hexaferrites (BaM; BaFe₁₂O₁₉) were fabricated via facile ceramic route. As-prepared powders were characterized by X-ray powder diffractometry (XRD), Fourier transform infrared (FT-IR) spectroscopy, and impedance spectroscopy. XRD (Rietveld) analyses confirmed the presence of a single characterization of all samples (except x = 0.0 and 0.1 samples). The crystallite sizes of products are found in the range of 47.2–63.2 nm. Spectral analysis (FT-IR) also presented the formation of spinel structure for all products. The ac conductivity of the substituted samples was found to initially decrease slightly with increase in Y³⁺ compared with unsubstituted, and then variation tendency changes at the medium substitution ranges are observed with a different attitude against temperature. In the end, the lower conductivity for high substitutions is recorded and increases as functions of frequency while it also increases with the elevation of temperature. It was observed that ac conductivities of products increased by increasing frequency which indicate that observed ac conductivity is due to both electronic and polaron hopping mechanism.     

Investigating the influence of tool shape during FSW of aluminum alloy via CFD analysis

This paper describes the application of the CFD code, Comsol Multiphysics, to modeling the 3-D metal flow in friction stir welding of AA 2024-T3 aluminum alloy in order to investigate the influence of tool shape over the metal flow. Heat transfer and non-Newtonian flow equations were solved simultaneously. The results from the benchmark experiments found in the literature were used for validation purposes. Scrolled shoulders and threaded pins were given as kinematic boundary conditions. This made the computational problem an easy one. A welding engineer can predict the metal flow around the tool with different scrolls and threads under any welding conditions without making expensive experiments. Investigation of the velocity field before actual welding can save a lot of engineering hours.     

Integrated Risk of Progress-Based Costs and Schedule Delays in Construction Projects

This article aims to explore the impact of the integration of risk factors into delayed milestones for construction projects. A simulation model was developed to determine the impact of schedule variability on cost estimation. To generate random scenarios a Monte Carlo Simulation (MCS) technique was applied. The developed model computes the cost impact of delayed milestone in the expected budget. Using a risk integration approach revealed the critical time frame that may lead to a budget deficit for a project. As a result, a number of cost-sensitive risk factors and schedule delays were identified for the critical time period where the risk of budget deficit increases. The method of integration proposed in this article highlights the priority of risk factors and schedule delays for construction contracts involving Payments at Event Occurrences (PEO). Consequently, the developed method can be useful for practitioners in anticipation of potential increase of costs, hence, prevention of failure due to budget deficit.     

Dynamic material properties of wood subjected to low-velocity impact

This article studied the effects of low-velocity impact on the failure stresses and stiffness using a pendulum test. The specimens were of variable depth (20, 30, and 40 mm), a width of 50 mm, length of 650 mm, and span-length of 480 mm. The smallest specimen depth was similar to specimen sizes tested in the literature used to create the duration of load curve, while the largest specimen depth are considered structural size specimens. The impact was predicted using a numerical approach with Euler–Bernoulli beam, as well as Timoshenko beam theory, with a plastic contact law. The models were validated for impact from a low release-angle (where the beam remained elastic), but could use improvement for the force prediction at a high incidence velocity. The measured force signals were used as forcing functions to obtain the dynamic failure stresses for all of the evaluated specimens, and the Timoshenko–Goens–Hearmon Method to derive the dynamic E. The resulting strain rates ranged from 9.11?×?10^?5 s^?1 for the quasi-static specimens up to 25 s^?1 for the greatest incidence velocity. The results from this study suggest different duration of load factors than the Madison Curve, influencing the design of structures subjected to dynamic loading.