The effect of the reduction conditions of iron-copper catalysts on their physicochemical characteristics

Conclusions An increase in reduction temperature leads to a decrease in the specific surface area of a catalyst and an increase in the pore radius of deposited iron-copper catalysts. For synthesis at 30 atm a catalyst reduced at 415°C to a 33–35% metallic iron content has the greatest activity and selectivity.     

Thickness dependence of magnetic properties of Co90Fe10 nanoscale thin films

Ferromagnetic monolayers Co90Fe10 thin films with individual layer thicknesses 2, 6, and 8 nm were grown on thermally oxidized Si substrate and magnetic properties of these were investigated with Ferromagnetic resonance (FMR) technique at room temperature. The magnetoresistance (MR) of the samples were measured as a function of applied DC magnetic field and the thickness dependence of the MR was plotted. The FMR spectra were recorded for both parallel and perpendicular geometry. The X-band (9.5 GHz) FMR spectra and resonance field of samples were analyzed and fitted theoretically by using the Landau-Lifshits dynamic equation of motion for magnetization with the Bloch-Bloembergen type damping term. The computer programs have been written to extract the effective magnetization (M), g-values and spin-spin relaxation time (T2) fitting parameters. The thickness dependence of magnetic parameters has been obtained from experimental data by mean of a theoretical model.     

Properties of na‐montmorillonite and cellulose nanocrystal reinforced poly(butyl acrylate‐co‐methyl methacrylate) nanocomposites

Poly(butyl acrylate‐co‐methyl methacrylate) (BA‐co‐MMA) nanocomposite latexes were synthesized in the presence of sodium montmorillonite (Na‐MMT) and cellulose nanocrystal (CNC) as fillers. Nanocomposite preparation with 3 wt% Na‐MMT based upon the total monomer amount was conducted by semi‐batch emulsion polymerization. Furthermore, direct blending of neat copolymer latex with Na‐MMT was performed for comparison. CNC/BA‐co‐MMA nanocomposites were obtained via blending process with varying CNC content (1, 2, and 3 wt %). Good dispersion of both Na‐MMT and CNC within the copolymer matrix was achieved as demonstrated by X‐ray diffraction and transmission electron microscope. Particle size of the nanocomposite latexes was around 120 nm. Thermal, mechanical, and barrier properties of the copolymer showed great improvement with the addition of both Na‐MMT and CNC. CNC nanocomposites displayed enhanced properties with increasing CNC level. Tensile strength of copolymer latex with 3 wt% CNC reached 262.5% of the pristine latex, while tensile strength of Na‐MMT nanocomposite at the same content was 187.5% of the pristine latex. POLYM. ENG. SCI., 55:2922–2928, 2015. © 2015 Society of Plastics Engineers     

Effect of ultrasonic activation on dentinal tubule penetration of calcium silicate‐based cements

This study investigated the dentinal tubule penetration of mineral trioxide aggregate (MTA), NeoMTA Plus and Biodentine placed by either manual condensation or ultrasonic activation in simulated open apex model. Standardized divergent open apex models were created using palatal roots of 60 human maxillary molars and divided into six groups according to the used cements and activation methods (n = 10): MTA‐manual condensation, MTA‐ultrasonic activation, NeoMTA Plus‐manual condensation, NeoMTA Plus‐ultrasonic activation, Biodentine‐manual condensation, Biodentine‐ultrasonic activation. For the measurement of penetration, the cements were mixed with 0.1% Rhodamin B and 6‐mm apical portions of each root canal were obturated in an orthograde direction. The roots were embedded into acrylic blocks, and 1‐mm‐thick sections were obtained at 3 mm from the apex. Specimens were mounted onto glass slides and scanned under a confocal laser scanning microscope (CLSM) and stereomicroscope. Dentinal tubule penetration areas, depth and percentage were measured using LSM and ImageJ software. The data were analyzed using two‐way analysis of variance (anova ) with Bonferroni correction (α = 0.05). No correlation was found between stereomicroscope and CLSM analyses (p > .05). CLSM analysis showed no significant differences between MTA, NeoMTA Plus, and Biodentine groups when manual condensation was used (p > .05). Ultrasonic activation did not increase the tubular penetration of MTA, NeoMTA Plus or Biodentine as compared to manual condensation of each material (p > .05). MTA, NeoMTA Plus and Biodentine showed similar tubular penetration when manual condensation was used. Ultrasonic activation of these cements had no effect on tubular penetration of each material as compared to the manual condensation counterparts.     

Thickness and Temperature Dependence of Exchange Bias in Co/CoO Bilayers

The effects of the ferromagnetic (FM) Co layer thickness on magnetic anisotropies and exchange bias (EB) properties of Co/CoO bilayers have been investigated by using ferromagnetic resonance (FMR) and vibrating sample magnetometer (VSM) techniques. The temperature and thickness dependence of EB were studied in temperature range of 4?C320?K. FMR and VSM measurements show that Co/CoO bilayers exhibit negative exchange bias just below the blocking temperature (T _B). Room-temperature in-plane FMR measurements reveal that the Co layer was epitaxially grown on MgO substrate with four-fold magneto-crystalline symmetry. The data also show that the easy axis of magnetization is in the film plane and parallel to the ??110?? crystallographic directions of MgO substrate in all samples.     

Monitoring the Salt Stability of Layer-by-Layer Self-Assembled Films From Polyelectrolyte Blends by Quartz Crystal Microbalance-Dissipation and Their Ion Separation Performances

Our study is concerned with the development of a novel type of layer-by-layer (LbL) self-assembled membrane from a single cationic polyelectrolyte (PE) and blended anionic PEs. Their synthetic seawater stability is investigated as a function of PE type and blend ratios using quartz crystal microbalance-dissipation (QCM-D). These materials adsorbed into multilayers with significant viscoelasticity. Poly(allylamine hydrochloride) (PAH) and poly(vinylamine hydrochloride) (PVA) based LbL blend films did not show any multilayer decomposition with the addition of synthetic seawater regardless of blend ratio while chitosan based multilayers disintegrated. The flux of PVA based blend membrane to water with 1,000 ppm NaCl was found to be 6.7 L/m².h at 40 bar and the flux properties of the membranes were highly dependent on both the thickness and hydrophilicity of multilayers. Ion rejection can be controlled with the charge of the top layer consistent with a Donnan exclusion approach. Sodium ion rejection of 60.5 layered LbL blend membrane was 98.4% at 40 bar and it was determined that sodium ion rejection improved 110.7% compared to a commercial nanofiltration membrane. POLYM. ENG. SCI., 60:1006–1018, 2020. © 2020 Society of Plastics Engineers