A new nonparametric double exponentially weighted moving average control chart

There are many practical situations where the underlying distribution of the quality characteristic either deviates from normality or it is unknown. In such cases, practitioners often make use of the nonparametric control charts. In this paper, a new nonparametric double exponentially weighted moving average control chart on the basis of the signed-rank statistic is proposed for monitoring the process location. Monte Carlo simulations are carried out to obtain the run length characteristics of the proposed chart. The performance comparison of the proposed chart with the existing parametric and nonparametric control charts is made by using various performance metrics of the run length distribution. The comparison showed the superiority of the suggested chart over its existing parametric and nonparametric counterparts. An illustrative example for the practical implementation of the proposed chart is also provided by using the industrial data set.     

Development of high performance amine functionalized zeolitic imidazolate framework (ZIF-8)/cellulose triacetate mixed matrix membranes for CO2/CH4 separation

High cost and complex fabrication process of inorganic membranes and lower position of pristine polymeric membranes in the Robeson upper bound curve urged the researchers to develop mixed matrix membranes (MMMs). Cellulose acetate being most commercially used polymer, dominates the market of CO₂ separation mainly because of low cost and environmental friendly resource. In the present study, MMMs consists of amine functionalized zeolitic imidazolate framework (NH₂-ZIF-8) and cellulose triacetate were fabricated for the first time. NH₂-ZIF-8 was used as a filler because the pore size of ZIF-8 is between the kinetic diameter of separating gases (CO₂ and CH₄). Moreover,  NH₂ group attached on the surface of ZIF-8 has affinity with condensable gases like CO₂. Morphology, crystallinity, tensile strength and functional groups of fabricated membranes were investigated using different analytical techniques. Results revealed that the increase of feed pressure has increased CO₂ permeability and decreased permselectivity. However, improvements in gas separation performance were observed with the addition of nanofiller. Best position in Robeson's upper bound curve at 4 bar was obtained with 10 wt% loading with CO₂ permeability and CO₂/CH₄ permselectivity of 218 barrer and 13.84, respectively. The improvement in the gas separation performance with loading is attributed to the increased diffusion coefficients as well as solubility coefficients, which was increased to 33% and 3.8%, respectively.     

Egg white proteins and β-cyclodextrin: effective cryoprotectant mixture against oxidative changes in the myofibrillar proteins of Culter alburnus

The effect of egg white protein (EWP) and β-cyclodextrin (β-CD) mixture was analysed on the myofibrillar proteins (MP) of Culter alburnus during a frozen storage at −18 °C for 60 days. Different proportions of EWP:β-CD mixture (0%, 2%, 4% and 6%) were added into MP to analyse their effect against oxidative changes. During the study, sulphydryl contents and Ca-ATPase activity (0.297 to 0.136 mmol g⁻¹) decreased. Moreover, protein denaturation also prompted the surface hydrophobicity (11.47 to 32.06 μg) and carbonyls (26.36 to 49 mg.28 nmol mg⁻¹) of control MP. A significant decline was observed in emulsifying properties. Besides, EWP:β-CD showed remarkable stability against oxidative changes, by significantly reducing the carbonyls (26.26 to 37.69 nmol mg⁻¹) and surface hydrophobicity (11.51 to 20.31 μg) and also the decline of Ca-ATPase activity (0.29 to 0.19 mmol g⁻¹). It can be concluded that EWP:β-CD (6%) is an efficient approach against oxidative changes in MP from Culter alburnus.     

Micro‐morphological,environmental and phytochemical investigation of herbal medicines by using LM and SEM: A quality control tool

The use of quality control tool for authentication of Jadwar (Delphinium denudatum Wall. ex Hook.f. & Thomson), a folk herbal drug used for the treatment of different ailments, was studied. People face problems of adulteration for this drug at global, regional, national and local levels. Two different plant species are commercially marketed in the Indo‐Pak Subcontinent under the same trade name of Jadwar. One is D. denudatum Wall. ex Hook.f. & Thomson and the other is Aconitum heterophyllum Wall. ex Royle. To focus on this problem, a marketable available drug sample of Jadwar was authenticated by using basic microscopy tools (LM) and advanced chemo‐taxonomic markers. Authentication, quality and standardization of this drug was achieved using morphology, organoleptography, UV and IR analyses, scanning electron microscopy of pollen and anatomical investigations. The techniques used for authentication marked the clear difference between the studied plants. Microscopic studies, chemotaxonomic investigation and other techniques used in this project provided the basis for the authentication of this species.     

Recent Developments and Applications of Ionic Liquids in Gas Separation Membranes

Flue gas emissions and the harmful effects of these gases urge to separate and capture these unwanted gases. Ionic liquids due to negligible vapor pressure, thermal stability, and wide electrochemical stability have expanded its application in gas separations. A comprehensive overview of the recent developments and applications of ionic liquid membranes (ILMs) for gas separation is given. The three general classifications of ILMs, such as supported ionic liquid membranes (SILMs), ionic liquid polymeric membranes (ILPMs), and ionic liquid mixed‐matrix membranes (ILMMMs) along with their applications, for the separation of various mixed gases systems is discussed in detail. Furthermore, issues, challenges, computational study, and future perspectives for ILMs are also considered.     

Intelligent Transmission Control for Efficient Operations in SDN

Although the Software-Defined Network (SDN) is a well-controlled and efficient network but the complexity of open flow switches in SDN causes multiple issues. Many solutions have been proposed so far for the prevention of errors and mistakes in it but yet, there is still no smooth transmission of pockets from source to destination specifically when irregular movements follow the destination host in SDN, the errors include packet loss, data compromise etc. The accuracy of packets received at their desired destination is possible if networks for pockets and hosts are monitored instead of analysis of network snapshot statistically for the state, as these approaches with open flow switches, discover bugs after their occurrence. This article proposes a design to achieve the said objective by defining the Intelligent Transmission Control Layer (ITCL) layer. It monitors all the connections of end hosts at their specific locations and performs necessary settlements when the connection state changes for one or multiple hosts. The layer informs the controller regarding any state change at one period and controller collects information of end nodes reported via ITCL. Then, updates flow tables accordingly to accommodate a location-change scenario with a route-change policy. ICTL is organized on prototype-based implementation using the popular POX platform. In this paper, it has been discovered that ITCL produces efficient performance in the trafficking of packets and controlling different states of SDN for errors and packet loss.     

Numerical investigation on optimization of thermal analysis due to immersion of hybrid nanostructures in a fluid of shear dependent viscosity using the finite element method

This article considers the dispersion of hybrid and mono nanoparticles in a fluid with viscosity (Williamson) dependent on shear rate, over a heated surface moving with nonuniform velocity and exposed to a magnetic field in the presence of an applied current. Extensive modeling leads to complex coupled mathematical models that are solved numerically via the finite element method (FEM). Convergent simulations are run to investigate the role of parameters on the dynamics of flow fields. The magnetic field intensity plays a role in controlling the magnetohydrodynamic boundary layer thickness (BLT) and thermal radiation controls the thickness of thermal boundary layers (TBL). However, the magnetic field intensity is responsible for an increase in BLT. In contrast to this, thermal radiation plays a role in controlling the thickness of the TBL. The impact of shear rate dependent viscosity on velocity is remarkable for both fluids. The motion of both of the fluids slows down when viscosity varies as a function of shear rate. Viscosity depending on the shear rate has a significant impact on wall shear stress. It is observed from simulations that wall shear increases when the parameters appearing in the model for shear rate dependent viscosity are increased. However, this increase in wall shear stress associated with a hybrid nanofluid is greater than the increase in wall shear stress associated with a mono nanofluid.     

New insights into the crystallization process of sol-gel–derived 45S5 bioactive glass

In this work the influence of thermal treatment conditions on crystallization of a sol-gel-derived 45S5 bioactive glass was evaluated using DSC, XRD, TEM, EDX, and X-ray nanocomputed tomography (nano-CT). Temperature and time of the thermal treatment strongly influence the composition of the crystalline phases. At the onset of the glass transition temperature (600°C), combeite crystallizes as the main phase along with a calcium silicate-phosphate phase, which decomposes into rhenanite from 2 hours of thermal treatment at this temperature. At the crystallization temperature (700°C), combeite remains as the main crystalline phase. Additionally, Na₂Ca₂Si₂O₇ crystalline phase is formed. Our results provide a basic platform for tailoring the crystalline phases by controlling the nucleation and growth of crystalline phases via thermal treatments. Different morphologies (round particles, stacked layers, toothpick-like, and long features) were discerned by TEM as a function of temperature and time of treatment. It is the first time that bioactive glass is investigated by nano-CT at laboratory scale. This novel technique enables the 3D visualization of features in the nanometer range, giving clear information about the volumetric distribution of phases in the sample.