Syntheses and Structural Characterization of Triorganotin Derivatives of Bis(carboxymethyl)trithiocarbonate: X-ray Crystal Structures of 2D Network Polymers

Six triorganotin(IV) complexes of the type {(R₃Sn)₂[C₃S₃(COO)₂]}_n (R = C₆H₅ 1; n-Bu 2; PhCH₂ 4; p-F-PhCH₂ 5; o-F-PhCH₂ 6) and {(R₃Sn)₂[C₃S₃(COO)₂]}_n·[EtOH] (R = Me 3) have been synthesized by the reaction of bis(carboxymethyl)trithiocarbonate with triorganotin(IV) chloride in the presence of sodium ethoxide. All complexes were characterized by elemental analysis IR, ¹H, ¹³C and ¹¹⁹Sn NMR spectroscopy. Except for 4–6, all complexes were also characterized by X-ray crystallography. The X-ray date revealed that complexes 1–3 show two-dimensional network polymeric structure in which the geometries of tin atoms are trigonal bipyramid with the axial positions occupied by carboxylic oxygen atoms.     

有关地下公共娱乐场所防排烟设计的探讨

根据地下公共娱乐场所的结构特点和火灾特点,结合某地下娱乐场所的防排烟设计,探讨如何进行防排烟设计。     

过程控制级模拟轧钢系统的研制及在热轧试车中的应用

宝钢集团上海第一钢铁有限公司(后面简称一钢)新建的不锈钢工程1780热轧项目中,为了能在较短周期内完成所有的应用软件开发与测试任务,特别研制了模拟轧钢功能。本论文主要阐述利用计算机的集成思想,结合热轧工艺,来开发模拟轧钢功能,以及利用模拟轧钢进行现场各种情况的模拟测试。     

凯萨·布隆斯泰德和沃迪·凯威设计事务所

本文通过对主要设计成员凯萨·布隆斯泰德和沃迪·凯威的背景,以及对私人住宅、餐馆、办公楼、图书馆、精品屋等案例的阐释,向读者介绍了这家十分活跃的芬兰设计事务所,同时展现了北欧的室内设计风格。     

以加入WTO为契机 提高国土资源管理水平

以加入世贸组织为契机 ,加强资源战略研究 ,抓好管理重点 ,为“工业强省”提供国土资源支持。规范市场 ,处理好 5种关系 ,全面清理法规、规章、政策 ,转变政府职能     

企业信息化中的网络存储整合应用

首先介绍了网络存储技术中NAS技术和SAN技术的基本原理,并对两者的特性进行了比较;然后详细介绍了企业信息化过程中网络存储整合的一个典型案例,分析了其整合前存在的不足,制定有效的整合实施方案,并对实施过程中许多关键技术部分进行了阐述,最终很好的达到了预定目标;最后总结了网络存储整合需要规划多种技术相融合的必要性.     

一种VSAT数据通信网络报文传输协议的分析

本文描述并分析了一种适用于多信道ＶＳＡＴ卫星数据通信网的报文传输协议，特别是考虑了无线信道误码率对传输协议的影响，分析表明利用Ｓ－ＲＥ－ＡＬＯＨＡ作为预订信道的多址方式及按报文占用数据信道方法可以减小报文传输延时并增加系统吞吐量。     

Rapid synthesis of La0.7Sr0.3MnO3+λ catalysts by microwave irradiation process

Microwave irradiation processing (MIP) was considered as a potential method to synthesize perovskite-type oxides rapidly, cleanly and energy-efficiently. In this paper, La_0.7Sr_0.3MnO_3+λ, a kind of promising catalyst for automobile exhaust purification, was successfully prepared by MIP in not more than 5 min. The sol–gel method was also used for comparison. All the samples were evaluated by catalytic activity tests in the simulated exhaust and characterized by XRD, BET, TEM and XRF analyses. The results showed that the integrated perovskite-type phase and uniform particle size were obtained in the microwave-treated samples. And those ones exhibited a better oxidation activity under slightly oxygen-rich condition than that by sol–gel method, which may be related to more A-site cation vacancies and larger bulk oxygen content generated in MIP. Possible formation mechanism of perovskites in MIP was also discussed.     

Unified analytical expressions for calculating resonantfrequencies, transimpedances, and equivalent input noise currentdensities of tuned receiver front ends

Unified analytical expressions have been derived for calculating the resonant frequencies, transimpedance and equivalent input noise current densities of the four most widely used tuned optical receiver front ends built with FETs and p-i-n diodes. A more accurate FET model has been used to improve the accuracy of the analysis. The Miller capacitance has been taken into account, and its impact on the performances of the tuned front ends has been demonstrated. The accuracy of the expressions has been verified by Touchstone simulations. The agreement between the calculated and simulated performances of the front ends is very good. The expressions can be used to investigate the performances of different tuned front ends in a very simple way and provide a good starting point for further computer optimizations of the front ends