Effect of B2O3 on the structural and in vitro biological assessment of mesoporous bioactive glass nanospheres

In this paper, the boron-containing mesoporous bioactive glass (MBG) nanospheres have been successfully synthesized by modified sol-gel method assisted by surfactant, and the effect of boron substitution on structure and bioactivity was evaluated by combining experiments and ab initio molecular dynamics (AIMD) simulations. All of the samples exhibit regularly uniform mesoporous spherical microstructure with an average size of about 60 nm, and the boron-containing MBGs show higher specific surface area with the value up to 416.20 m²/g. The simulated body fluid (SBF) immersion test confirms that the deposited hydroxyapatite (HA) evidently increases with the increasing of boron content, indicating that the biological behavior has been significantly improved resulting from incorporation of boron. Additionally, our results also reveal that B₂O₃ substitution has positive impact on cell proliferation of human periodontal ligament cells (hPDLCs) at lower extracted concentration. Furthermore, AIMD simulation is employed to understand the relationship between structural changes and in vitro bioactivity in terms of structural information, especially the boron coordination number. The results illustrate that the boron-containing MBG nanospheres with excellent bioactivity are great potential for biomedical applications.     

Structure,crystallization, and performances of alkaline-earth boroaluminosilicate sealing glasses for SOFCs

We study the structure, crystallization, and performances of the sealing glasses with the composition (mol.%) of 12Al₂O₃·8B₂O₃·40SiO₂·40RO (R = Mg, Ca, Sr) for solid oxide fuel cells (SOFCs) before and after isothermal treatment at 700°C, which is within the operation temperature range (600-800°C) of SOFCs. The crystallization behavior has been investigated by differential scanning calorimetry and X-ray diffraction under both dynamic and isothermal conditions. The structural evolution is probed using the Raman and nuclear magnetic resonance spectroscopies. The performances of the sealing glasses are characterized in terms of the coefficient of thermal expansion, the crystallization-induced stress at glass–steel interface. We find that strong crystallization occurs at the operation temperature (700°C) far below the crystallization onset temperature measured by DSC. The structure origin of this anomalous crystallization is discussed in terms of structural heterogeneity of the three studied glasses. We determine the residual stress at the interface between the Ca-containing glass and the steel after isothermal treatment at 700°C for 48 h, but this stress does not lead to falling off the glass layer from the steel. This indicates that this glass is a good candidate to be applied in SOFCs.     

Single phase multi color emitting Ca2LuTaO6: Dy3+/Eu3+ double perovskite oxide phosphors

The trivalent rare-earth (RE³⁺) doped phosphors show tremendous achievement in narrow band multicolor line emission for various applications. However, the 4f–4f absorption transition of these ions is forbidden in UV and blue light excitation. Usually, a sensitizer having spin allowed transition was used as a co-dopant to excite these ions via the energy transfer phenomenon. Another approach promisingly using to excite these ions by efficient energy transfer from the intrinsic emission of the Ca₂LuTaO₆ double perovskite phosphors host lattice. Phosphors of Ca₂LuTaO₆ with double perovskite structure were synthesized by using a high-temperature solid-state reaction method. The produced Ca₂LuTaO₆ double perovskite phosphors show an intrinsic broad band emission centered at 424 nm under the excitation of 313 nm UV light. The origin of this broad band blue emission was deeply investigated by using computation and experimental approaches. The trivalent activator Dy³⁺ and Eu³⁺ were doped is a single and co-dopant in the produced Ca₂LuTaO₆ phosphors to check their excitation in UV and near-UV spectral region. X-ray diffraction and scanning electron microscopy were used to investigate the structure and phase analysis. Various characterizations such as photoluminescence excitation, emission, and CIE chromaticity coordinates were measured which illustrate the potential of Dy³⁺ and Eu³⁺ activated Ca₂LuTaO₆ double perovskite phosphors for narrow band multicolor line emission for various applications.     

Investigation of packaging adhesive properties by molecular dynamics and experiments

Adhesive polymer is a common and important material used for packaging of microelectronics and microsystem by attaching dies onto packaging shell, and its mechanical property plays a vital role in isolating dies from the thermal stress of substrate. Therefore, it is extremely significant to evaluate the polymer property in a specific packaging process. The molecular dynamics (MD) simulation is conducted in this article to investigate the material properties of the cross-linked epoxy resin formed by epoxy resin component diglycidyl ether bisphenol A (DGEBA) and curing agent 1,6-Diaminohexane. The polymer network with conversion up to 87.5% is successfully generated and simulated by constant pressure-constant temperature ensemble (NPT) and canonical ensemble (NVT) at different temperatures of curing process. Glass transition temperature (T_g) and Young's modulus are extracted and the predicted material properties are in great agreement with the experimental data. The conclusion provides a guideline to design the special curing process for different adhesive requirements.     

Simple approach to fabricate MXene/cellulose paper for electromagnetic interference shielding applications

A simple approach was developed to fabricate high-performance MXene/cellulose (MC)-based electromagnetic interference (EMI) shielding papers. The oriented MXene sheets located on one side of cellulose filter paper construct a continuous conductive layer, endowing the MC paper with high electrical conductivity (240.1 S/m) and excellent EMI shielding effectiveness (29.3 dB for 0.192-mm thickness) at an MXene content of 0.72 vol%. Moreover, the EMI shielding effectiveness of four stacked MC papers reached 40.5 dB. This result means that 99.9911% of the microwave radiation is attenuated, and 0.0089% is transmitted, through the four-piece MXene/cellulose filter papers. Therefore, MC paper has promising properties for excellent EMI shielding materials in current electronic devices.     

基于不同接地方式与列车工况的负阻变换器牵引供电系统轨道电位与杂散电流

为解决城市轨道交通中轨道电位与杂散电流导致的安全问题,该文提出一种负阻变换器牵引供电系统(NRC-TPS).在传统牵引供电系统(CON-TPS)的基础上,NRC-TPS通过直接安装电力电子设备,为列车电流提供零阻回路,缩短其回流至牵引变电所的路径长度.由于杂散电流的产生源头减少,NRC-TPS能够降低城市轨道交通系统的轨道电位与杂散电流.此外,考虑牵引变电所的接地方式与列车工况,该文详细研究NRC-TPS的工作原理、轨道电位与杂散电流的分布规律.建模与实验结果表明,NRC-TPS无需改造列车与轨道等基础部件,即可有效降低轨道电位与杂散电流,在既有线路和新建线路中均具有良好的应用前景.     

测试性能估算的测试集重排序方法

目前在集成电路测试中,测试时间长、测试效率低是影响测试成本的关键问题之一,针对此问题提出了一种基于测试性能估算的测试集重排序方法。首先针对不同的故障类型进行分类建模,然后对每种故障类型进行仿真,通过在每个逻辑门注入故障,统计测试向量命中故障门的面积之和来估算测试向量的测试性能,最后根据测试性能的优劣对测试集进行重新排序。实验表明,对于单固定故障使用排序后的测试集测试可以减少5329%的故障检测时间。该方法是通过对电路的逻辑结构进行分析和统计然后对测试集进行优化,对ISCAS 89标准电路进行试验,与其他测试集重排序对比,有着明显的优化。算法运行完全是基于软件的,不需要增加任何硬件开销,可以直接相容于传统的集成电路测试流程。     

EL-CID电磁铁心故障检测试验的应用研究

为了检验发电机定子铁心质量,在制造过程中和安装现场,对发电机定子铁心进行试验是必不可少的.目前国内针对定子铁心更多地是采用常规试验方法,但是常规铁损试验所需的设备容量大、试验线路复杂,而且经济性较差、效率低下.而采用电磁定子铁芯故障探测仪(EL-CID)铁心试验只需提供约4％的额定磁通量,即可完成对铁心故障的诊断,其所需的励磁电源容量较小且容易配备和携带.为了更好地利用EL-CID检测方式进行铁心质量的判定,本文通过模拟多种故障状况下的试验,论证了EL-CID的使用条件和影响因素,为实际工作中EL-CID的应用提供更好的参考依据.     

轰运飞机气动元件综合测试台的设计

本文较系统地介绍了测试台气动系统和CAT系统的设计。该测试台一方面功能齐全、可靠性高、操作方便，另一方面软件部分较为完善优越，运行速度较快，使得数据的采集、处理实现了计算机自动化，是航空气动元件比较理想的测试设备。     

依靠市场促进我国钛工业持续发展

钛工业是高新技术产业，钛及钛合金是对国防事业、尖端科学技术和民用工业发展具有战略意义、不可缺少的稀有金属材料。钛应用量的多少，是一个国家的军事实力和国民经济综合实力强弱的重要标志。简要回顾我国钛工业发展历程，探讨以市场为导向，推动钛应用和开发新应用对钛工业持续发展的重要性。