石灰湿法烟气脱硫给液系统设计和工程实践

阐述了石灰湿法烟气脱硫给液系统工艺设计特点。采用间歇消化、两次定量稀释和三级连续沉砂工艺制备消石灰稀液 ,供给三台 6 5t/h锅炉烟气脱硫。工程实践表明 :消石灰稀液质量浓度稳定 ,易操作 ,易控制和易监督 ,证明了给液系统是湿法烟气脱硫的重要部分     

喷射成形CuCr25合金触头材料的制备及致密化处理

利用喷射成形技术制备了CuCr2 5合金触头材料 ,研究了雾化压力对显微组织、致密度和收得率的影响 ,对制得的沉积坯件进行了热锻压和热等静压致密化处理 ,并测试了触头材料的密度、硬度和电导率。研究结果表明 :最合适的雾化压力为 0 .6MPa ,沉积坯件经过 95 0℃锻压后再在 10 70℃ ,2 0 0MPa下热等静压 8h ,可以得到全致密的触头材料 ,铬颗粒平均直径小于 10 μm ,硬度达 10 0HB ,电导率 2 5～2 9Ms·m- 1 ,说明致密化处理后的喷射成形CuCr2 5合金是一种优良的触头材料。     

Synthesis and red electrophosphorescence of a novel cyclometalated iridium complex in polymer light-emitting diodes

The preparation and characterization of a new cyclometalated iridium complex with 2-(1-naphthalene) pyridine ligand were reported. An electrophosphorescent device was fabricated by using this new iridium complex as guest and poly-(cyano-paraphenylene) as host. Red electrophosphorescence was observed with an emission peak at approximately 600 nm. An external quantum efficiency of 1.3% was achieved in this electrophosphorescent polymer light-emitting devices.     

在World Wide Web上检索图像和视频信息

提出了一种综合利用图像和视频的文本信息和基于内容的视觉特征进行World Wide Web上图像视频信息检索的原型系统。在这个原型系统中，一个完整的Web上图像和视频信息的处理过程包括：(1)通过探索器从Web上自动收集信息；(2)在文本和视频特征两个域内同时进行分析；(3)图像和视频信息分类；(4)标定索引，进行快速检索。实验结果表明，利用这个系统，可以获得较高的视觉分类率。     

On glass formation for a Na2O·4TeO2 melt: Effect of melting temperature, time, and raw material

The effect of melting temperature, time, and the type of raw material, NaNO₃ or Na₂CO₃, as a source for Na₂O on the glass formation for a Na₂O·4TeO₂(NT₄) melt was investigated. Melting with NaNO₃ at 750°C for a short time (15 min) produced a glass that is slightly more chemically durable and more resistant to crystallization than glasses melted at a higher temperature (800°C), or for a longer time (60 min), or using Na₂CO₃. A thin surface layer (<1.5 nm) that contains some nitrogen and a higher concentration of bridging oxygen is suspected to be the reason for the higher chemical durability and higher resistance to crystallization for this glass. However, melting at 800°C for 60 min produced a glass, whose properties were independent of the type of raw material, NaNO₃ or Na₂CO₃, used.     

Tailored microstructure of zirconia and hafnia-based thermal barrier coatings with low thermal conductivity and high hemispherical reflectance by EB-PVD

Zirconia and hafnia based thermal barrier coating materials were produced by industrial prototype electron beam-physical vapor deposition (EB-PVD). Columnar microstructure of the thermal barrier coatings were modified with controlled microporosity and diffuse sub-interfaces resulting in lower thermal conductivity (20–30% depending up on microporosity volume fraction), higher thermal reflectance (15–20%) and more strain tolerance as compared with standard thermal barrier coatings (TBC). The novel processed coating systems were examined by various techniques including scanning electron microscopy (SEM), X-ray diffraction, thermal conductivity by laser technique, and hemispherical reflectance.     

The effects of gravity on the features of the interfacial waves in annular two-phase flow

A physical model of interfacial waves in annular two-phase flow was studied in both microgravity and normal gravity. The wave structure was obtained for local film thickness and velocity measurements using a conductance probe technique. It was found that the wave height, and not its width, is strongly affected by changing the gravity level. In fact, the wave height in normal gravity is more than twice that in microgravity. Using an analogous approach to a turbulent, single-phase flow in a rough tube, a preliminary mathematical model was proposed to calculate the wave amplitude. The model fits well with the experimental data and shows that the wave height in normal gravity is approximately 1.7 times the combined thickness of the viscous sublayer and transition zones in the turbulent gas stream. The wave height in microgravity was estimated to be approximately 80% of the total thickness.     

板坯连铸中间包钢液洁净度的水力学模拟和应用

为改善太钢 10 4 0mm× 16 0mm连铸不锈钢板坯质量 ,通过水力学模拟研究了中间包内钢液的流动 ,并用直径 0 .5～ 1.0mm ,密度 0 .99mg/mm3 的聚苯乙烯塑料粒子模拟钢中直径 5 0～ 10 0 μm夹杂物的排除情况 ,确定了在中间包内设置挡渣墙和坝流控制方案 ,并进行 4 0 9不锈钢 10 4 0mm× 16 0mm连铸板的工业试验 ,结果表明 :中间包设置挡渣墙和坝后 ,铸坯夹杂物总量比中间包无控流装置生产的铸坯降低 6 6 %。     

Preparation and High-Temperature Water-Gas Shift Catalytic Features of La1-xCexFeO3 Perovskite

Based on water-gas shift reaction mechanism and perovskite compounds characteristics, La1-xCexFeO3(.K) perovskite were designed and prepared as shift catalysts. DTA and XRD results reveal that La1-xCexFeO3 can be formed at 730-760℃ by mechanic-mix thermal decomposition method. Activity and heat-resisting tests show that La1-xCexFeO3 (.K) possess high thermal stability if x is less than or equals to 0.5. But when x is greater than 0.5, La1-xCexFeO3 (.K) will be converted into ceria and magnetite partially or completely under shift reaction conditions. In the case of x=0.5, the conversion of CO is about 68% at 530℃. Potassium can greatly improve the low temperature activity, but slightly reduces the high temperature activity, and has little impact on the thermal stability. La0.5Ce0.5FeO3(.K) is a promising chromium-free high temperature shift catalyst.