Low‐cost dye‐sensitized solar cells with ball‐milled tellurium‐doped graphene as counter electrodes and a natural sensitizer dye

This paper presents a facile and economic development of dye‐sensitized solar cells using a nonprecious counter electrode made from ball‐milled tellurium‐doped graphene (Te‐Gr) and a natural sensitizer extracted from Calotropis gigantea leaves. The prepared materials were characterized using various techniques, such as Raman spectroscopy, X‐ray diffraction (XRD), atomic force microscopy (AFM), impedance spectroscopy, and scanning electron microscopy with built‐in energy‐dispersive X‐ray spectroscopy (SEM with EDS). The electrochemical activity of the produced counter electrodes and the impedance of the fabricated cells were examined and discussed to devise plans for future enhancement of cell performance. A clear pattern of improvement was found when using cost‐effective Te‐Gr relative to the costly platinum counter electrodes, especially when compared with cells employing another natural sensitizer. The results show approximately 51% enhancement over chlorophyll‐based cells made from spinach, where the added advantage in our approach is the utilization of an abundant plant extract with little nutritional appeal.     

An iterative code to investigate heat pump performance improvement by exhaust gases heat recovery

The race between the development of technologies and energy demand has drawn the guidelines of energy strategies for the next two decades. Indeed, the governmental organizations as well as the private sectors are spending huge effort to come up with new adequate strategies that allow to decrease energy consumption. Having said that, heat pump becomes an essential system in our daily life not only in residential building but also in hospital, industrial and touristic building. Nonetheless, (HP)s have very high energy consumption rate. Thus, and to be in line with the new trends in energy strategies, it is convenient to find new methods to enhance the performance of heat pump in order to reduce energy consumption. In this frame, the present paper suggests an approach to enhance the performance the heat pumps using the heat recovery from generators. For this purpose, an in-house code is developed allowing to simulate two new proposed systems (condenser upstream exhaust gases heat recovery system (CU-EGHRS) and condenser downstream exhaust gases heat recovery system (CD-EGHRS). It has been shown that the increase in the performance of the heat pump depends on the capacity of the generator. Also, the CD-EGHRS is shown to be the best. For instance, in the case of a 15 kVA generator, the enhancement could reach 42% for the CD-EGHRS. This enhancement increases to 5640% in the case of a 180 kVA generator.     

Evidence of nano-galvanic couple formation on in-situ formed nano-aluminum amalgam surfaces for passivation-bypassed water splitting

Reaction of Al metal with water is a well-known technique for large scale production of hydrogen. However, this method suffers from kinetic limitations due to formation of a passivation layer on Al, preventing optimal operations. Using high resolution Scanning Kelvin Probe Force Microscopy (SKPFM), we show the origin of formation of 'nano-galvanic couple' on in situ formed nano-aluminum amalgam surfaces in a water splitting system; passivation based limitations are completely bypassed in this approach. Furthermore, they offer an opportunity to beneficiate and recover mercury in contaminated water. The nano-galvanic corrosion due to substantial lateral variation in surface contact potential is responsible for the observed high throughput of hydrogen production (720 mL/min per 0.5 g Al salt). It may be noted that this process fares better than in situ prepared nano-Al based hydrogen production, wherein 600 mL/min of hydrogen is obtained for 0.5 g Al salt. Investigations using Cyclic Voltammetry (CV) and Electrochemical Impedance Spectroscopy (EIS) provide evidence for passivation-bypassed hydrolysis and favourable kinetics for in situ derived nano-AlHg hydrolytic agents (when compared to nano-Al). This study, to the best of our knowledge, reports the first direct proof of nano-galvanic couple formation on in-situ prepared nanoaluminum amalgam surface; paving a direct way to overcome the long standing passivation problem in Al hydrolysis. It is found that the hydrogen production rate and standard deviation (SD) of the contact potential of nanoaluminum amalgam are directly related to the rate of addition of the reducing agent, offering an opportunity for kinetic control for the in situ hydrolytic process.     

Current condition and future directions for lean construction in highways projects: A small and medium-sized enterprises (SMEs) perspective

The aim of this study is to identify the parameters defining how Lean Construction (LC) is being implemented (current condition) and how LC can be further promoted (future direction) from a Small-Medium Sized Enterprises (SMEs) perspective. Although SMEs constitute the largest group in construction supply chains, LC, as an emerging phenomenon in civil construction project management, has been rarely investigated from an SMEs perspective. Also, overlooking the more macro factors like project governance and supply chain management, LC deployments have been mainly discussed from a production process perspective to date. After a review of the extant literature and 20 interviews with managers from the highways sector, a list of 31 current condition and 40 future direction statements were produced, classified under the delivery, process, training, project governance and supply chain related headings and used in a questionnaire survey with 110 responses. The current condition highlights problems like a short-term relations structure, competitive tendering mechanisms, fragmentation, problems in engaging with SMEs for LC, unstandardised LC techniques, and issues with convincing SMEs to deploy LC by demonstrating the business case on mutual benefits. Action items relating to the current project delivery structure were given the highest importance by the supply chain, alongside the LC training and project governance issues for the future of LC at highways SMEs. Additionally, a statistically significant correlation was identified among many future action items.     

Optimize adaptive media playout using dynamic fuzzy logic control for video streaming

Multimedia Tools and Applications - Adaptive Media Playout (AMP) controls adapt playout rate to prevent buffer outage and to reduce delay in playout. Most AMP techniques use buffer fullness or its...     

Exercise classification and event segmentation in Hammersmith Infant Neurological Examination videos

Image and video processing techniques are being frequently used in medical science applications. Computer vision-based systems have successfully replaced various manual medical processes such as analyzing physical and biomechanical parameters, physical examination of patients. These systems are gaining popularity because of their robustness and the objectivity they bring to various medical procedures. Hammersmith Infant Neurological Examinations (HINE) is a set of physical tests that are carried out on infants in the age group of 3–24 months with neurological disorders. However, these tests are graded through visual observations, which can be highly subjective. Therefore, computer vision-aided approach can be used to assist the experts in the grading process. In this paper, we present a method of automatic exercise classification through visual analysis of the HINE videos recorded at hospitals. We have used scale-invariant-feature-transform features to generate a bag-of-words from the image frames of the video sequences. Frequency of these visual words is then used to classify the video sequences using HMM. We also present a method of event segmentation in long videos containing more than two exercises. Event segmentation coupled with a classifier can help in automatic indexing of long and continuous video sequences of the HINE set. Our proposed framework is a step forward in the process of automation of HINE tests through computer vision-based methods. We conducted tests on a dataset comprising of 70 HINE video sequences. It has been found that the proposed method can successfully classify exercises with accuracy as high as 84%. The proposed work has direct applications in automatic or semiautomatic analysis of “vertical suspension” and “ventral suspension” tests of HINE. Though some of the critical tests such as “pulled-to-sit,” “lateral tilting,” or “adductor’s angle measurement” have already been addressed using image- and video-guided techniques, scopes are there for further improvement.     

Ag–Sr doped mesoporous bioactive glass nanoparticles loaded chitosan/gelatin coating for orthopedic implants

In this study, we investigated surface and biological properties of Ag–Sr-doped mesoporous bioactive glass nanoparticle (Ag–Sr MBGN) loaded chitosan/gelatin coatings deposited by electrophoretic deposition (EPD) on 316L stainless steel. The EPD parameters, that is, deposition time, applied voltage, and distance between the electrodes was optimized by the Taguchi design of experiment (DoE) approach. Scanning electron microscopy (SEM) images illustrated the spherical morphology of the synthesized Ag–Sr MBGNs with the mean particle size of 160 ± 20 nm. Energy-dispersive X-ray (EDX) spectroscopy results confirmed the presence of Ag and Sr in the synthesized MBGNs. Optimum EPD parameters determined by DoE approach were 5 g/L of Ag–Sr MBGNs, deposition time of 5 min, and applied voltage of 30 V. SEM images confirmed that the coatings were fairly homogenous. Fourier-transform infrared spectroscopy and EDX results confirmed the presence of chitosan, gelatin, and Ag–Sr MBGNs in the coatings. Chitosan/gelatin/Ag–Sr MBGN composite coatings exhibited suitable wettability for the protein attachment and proliferation of osteoblast cells. The composite coatings exhibited suitable adhesion strength with the substrate. The coatings developed HA crystals upon immersion in simulated body fluid. The results of the turbidity test confirmed that the coatings are antibacterial to the Escherichia coli cells.     

Improvement of the production of poly(3‐hydroxybutyrate‐co‐3‐hydroxyvalerate‐co‐4‐hydroxybutyrate) terpolyester by manipulating the culture condition

BACKGROUND: The aim of this work is to enhance the production of terpolyester poly(3‐hydroxybutyrate‐co‐3‐hydroxyvalerate‐co‐4‐hydroxybutyrate) (P(3HB‐co‐3HV‐co‐4HB)) produced by a locally isolated bacterium, Cupriavidus sp. USMAA2‐4. The monomer composition was varied by supplementing different carbon precursors and by manipulating the culture condition through one‐stage cultivation. The effect of C/N ratio and different concentrations of carbon source and precursors were investigated in order to produce higher content of this terpolyester. Although research on this biodegradable polyester is abundant, studies on terpolyester P(3HB‐co‐3HV‐co‐4HB) are still limited. RESULTS: Supplementation of oleic acid in accumulation medium increased the bacterial growth and polyhydroxyalkanoate (PHA) accumulation. It was also shown that medium consisting of assorted carbon precursors at C/N 20 gave relatively high dry cell weight and P(3HB‐co‐3HV‐co‐4HB) content. Various compositions of terpolyester were obtained when the concentration of oleic acid and 4HB precursors were manipulated. The combination of oleic acid with γ‐butyrolactone and 1‐pentanol was found to be the best combination to produce high PHA content (81 wt%). The composition of monomer in P(3HB‐co‐3HV‐co‐4HB) was produced in the range 8–13 mol% for 3HV and 9–24 mol% for 4HB, respectively. CONCLUSIONS: The production of P(3HB‐co‐3HV‐co‐4HB) in shake‐flasks successfully produced 81 wt% of PHA content. This manipulated culture condition can be used at larger scale to provide modeling for the production of terpolyester in a bioreactor. Copyright © 2012 Society of Chemical Industry     

SQC and the fluency hypothesis

Students’ Quality Circles (SQCs) are considered in the context of English Language Teaching in Pakistan, with a focus on oral expression. SQCs offer many educational benefits.