Unidirectional growth of pure and L-lysine added ADP crystals from aqueous solution

Pure and L-lysine added ammonium dihydrogen phosphate (ADP) crystals were grown in the 〈001〉 direction by Sankaranarayanan-Ramasamy (S-R) method. The grown crystals were characterized by X-Ray diffractometry (XRD), UV-Vis spectroscopy, Fourier Transform Infrared (FT-IR) and Vicker’s Microhardness analysis. XRD spectrum of each of the grown crystals proved its crystallinity. The crystals showed good transparency in the entire visible region. FT-IR spectra of the specimens revealed the presence of functional groups in them. The hardness of the pure and L-lysine added ADP crystals were measured and that of the added one was found higher. Meanwhile, it was found that the ADP crystals (pure and L-lysine added) grown by S-R method had higher hardness compared to ADP crystal grown by conventional method.     

Consumer perception of boar meat as affected by labelling information,malodorous compounds and sensitivity to androstenone

This study aimed to assess the influence of two label conditions on the acceptance of boar meat. A central location test was conducted with 145 consumers each assessing 4 pieces of pork loin.     

A crossover‐UNIQUAC model for critical and noncritical LLE calculations

A new model, named the crossover‐UNIQUAC model, has been proposed based on the crossover procedure for predicting constant‐pressure liquid–liquid equilibria (LLE). In this manner, critical fluctuations were incorporated into the classical UNIQUAC equation. Coexistence curves were estimated for systems having a diverse range of asymmetries. These systems included the LLE of five different mixtures, composed of nitrobenzene with one of the members of the alkane homologous family (either pentane, octane, decane, dodecane, or tetradecane), as well as an extra system having a different chemical nature, namely the mixture of n‐perfluorohexane and hexane, to further check the validity of the proposed approach. Using these nonideal mixtures, the validity of the new model was investigated within wide ranges, covering near‐critical to regions falling far away from the critical point. The graphical trends, as well as the quantitative comparison with experimental data indicated the good agreement of the proposed model results with the experimental data. A maximum AARD% value of 3.97% was obtained in calculating molar compositions by the proposed model for such challenging systems covering noncritical, as well as critical regions. In addition, to show the strength of the proposed crossover approach to describe properties other than LLE, molar heat capacities were investigated for the system of nitrobenzene + dodecane. © 2015 American Institute of Chemical Engineers AIChE J, 61: 3094–3103, 2015     

Wachstumsmessungen von Kristallen in sauberen und verunreinigten Lösungen: Einzelkristall vs. Kollektiv

Information about crystal growth rates and the influence of impurities are essential for the design of industrial crystallization processes. Here, the influence of trivalent metal ions Fe³⁺ in solution and adsorbed in the crystal on the growth and dissolution rate is investigated. The results clearly show kinetic and thermodynamic effects caused by impurities which have to be taken into account in the equipment design. Furthermore, effects of growth rate dispersion must be excluded by investigation of crystal collectives. Additionally, the crystal growth data should be obtained from real starting solutions.     

Nanomechanical and tribological behavior of hydroxyapatite reinforced ultrahigh molecular weight polyethylene nanocomposites for biomedical applications

A hydroxyapatite (HA) particulate reinforced ultrahigh molecular weight polyethylene (UHMWPE) nanocomposite is fabricated by internal mixer at 180°C and using of paraffin oil as a processing aid to overcome the high viscosity of melted UHMWPE. The reinforcing effects of nano‐HA are investigated on nanomechanical properties of HA/UHMWPE nanocomposites by nanoindentation and nanoscratching methods. Results show that the nanocomposite with 50 wt % nano‐HA exhibits a Young's modulus and hardness of 362.5% and 200% higher, and a friction coefficient of 38.86% lower than that of pure UHMWPE, respectively. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42052.     

Copper (I) ion stabilized on fe3o4‐core ethylated branched polyethyleneimine‐shell as magnetically recyclable catalyst for ATRP reaction

Branched polyethyleneimine (bPEI) was used to modify the surface of Fe₃O₄ nanoparticles coated with silica layer, and then, it was treated with ethyl iodide to prepare Fe₃O₄@SiO₂@Ethylated‐bPEI. In the next step, the yolk–shell structure was gained by selectively etching the SiO₂ middle layer. Finally, copper(I) was introduced to the yolk–shell Fe₃O₄@Ethylated‐bPEI and the activity of the catalyst was evaluated for atom transfer radical polymerization (ATRP) of styrene, led to obtain the well‐defined polymer with relatively low polydispersity. The toxicity of the residual copper in the polymer product was a limiting issue for applicability of ATRP reactions especially for biological purposes. In this report, the copper content in the polymer was reduced to the excellent value of 1.1 ppm. Moreover, the magnetic isolation, recyclability, and remove the need for an external ligand were other advantages of the synthesized catalyst which makes it suitable for employing in ATRP reactions. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42337.     

Towards the performance evaluation of 4th generation wireless communication standards: LTE versus Mobile WiMAX

Advances in wireless communication protocols and networking toward support of the next generation of mobile and radio broadband technologies have contributed to a strong competition among various telecommunication standards in particular Long Term Evolution (LTE) and Mobile Worldwide Interoperability for Microwave Access (WiMAX). In this paper, we provide an in‐depth comparison analysis of LTE and Mobile WiMAX at the physical (PHY) layer by studying the most similar PHY configuration scenarios for these two technologies. Our study includes a throughput analysis of downlink (DL) and uplink (UL) transmissions in time division duplex with the least overhead possible and different antenna schemes as well as modulation and code rates. This study also performs an overhead analysis in both protocols to provide a more in‐depth understanding of the PHY layer capacity in various PHY layer configurations. Our simulation results generally show higher performance for LTE in both DL and UL transmission with 7 Mbps in DL and 5 Mbps in UL, when using one antenna port. However, by increasing the number of antennas for multiple‐input/multiple‐output configurations, the results illustrate a reduction in the performance of LTE compared to Mobile WiMAX. This arises from the increase in reference signal overhead in LTE from 4.7% in single‐input/single‐output (SISO) to 14.28% in 4 × 4 multiple‐input/multiple‐output (MIMO). Copyright © 2013 John Wiley & Sons, Ltd.     

Time–cost optimization: using GA and fuzzy sets theory for uncertainties in cost

Uncertainties should be considered in any time–cost trade‐off problems when minimizing project cost and duration, which leads to the so‐called stochastic time–cost trade‐off problem. A new approach to investigate stochastic time–cost trade‐off problems employing fuzzy logic theory is presented. The proposed approach fully embeds the fuzzy structure of the uncertainties in total direct cost into the model. An appropriate GA is used to develop a solution to the multi‐objective fuzzy time cost model. The accepted risk level of the project manager is defined through α cut approach for which a separate Pareto front with set of non‐dominated solutions has been developed. To compare the alternative set of options for any assumed project duration, associated fuzzy costs for different values of α cut are ranked employing two appropriate approaches for fuzzy costs comparison. The proposed models are applied to solve two benchmark test problems. It is shown that the models facilitate the decision‐making process by selecting specified risk levels and employing the associated Pareto front.