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排序方式: 共有1301条查询结果,搜索用时 15 毫秒
41.
Stacy A. Sommer Joseph R. Byrom Hanna D. Fischer Rajan B. Bodkhe Shane J. Stafslien Justin Daniels Carolyn Yehle Dean C. Webster 《Journal of Coatings Technology and Research》2011,8(6):661-670
Siloxane–polyurethane paints were formulated and characterized for coating properties and performance as fouling-release (FR) marine coatings. Paints were formulated at 20 and 30 pigment volume concentrations with titanium dioxide, and aminopropyl-terminated poly(dimethylsiloxane) (APT-PDMS) loadings were varied from 0 to 30% based on binder mass. The coatings were characterized for water contact angle, surface energy (SE), gloss, and pseudobarnacle (PB) adhesion. The assessment of the FR performance compared with polyurethane (PU) and silicone standards through the use of laboratory biological assays was also performed. Biofilm retention and adhesion were conducted with the marine bacterium Cellulophaga lytica, and the microalgae diatom Navicula incerta. Live adult barnacle reattachment using Amphibalanus amphitrite was also performed. The pigmented coatings were found to have properties and FR performance similar to those prepared without pigment. However, a higher loading of PDMS was required, in some cases, to obtain the same properties as coatings prepared without pigment. These coatings rely on a self-stratification mechanism to bring the PDMS to the coating surface. The slight reduction in water contact angle (WCA) and increase in pseudobarnacle release force with pigmentation suggests that pigmentation slowed or interfered with the self-stratification mechanism. However, increasing the PDMS loading is an apparent method for overcoming this issue, allowing for coatings having similar properties as those of clear coatings and FR performance similar to those of silicone standard coatings. 相似文献
42.
Jeannette Aumo Johanna Lilja Päivi Mäki-Arvela Tapio Salmi Mats Sundell Hanna Vainio Dmitry Yu. Murzin 《Catalysis Letters》2002,84(3-4):219-224
A polymer-supported Pd catalyst was investigated in hydrogenation of citral (3,7-dimethyl-2,6-octadienal), which is a stereoisomer with an isolated and a conjugated double bond as well as a carbonyl group. The catalyst was a fibrous polymer-supported catalyst modified with functional groups and immobilized metals. A comparison of the polymer-supported catalyst with conventional catalysts was made. 相似文献
43.
The influence of silver loading on the lean NOx reduction activity using methanol as reductant has been studied for alumina supported silver catalysts. In general, increasing the silver loading (0–3 wt%), in Ag–Al2O3, shifts or extends the activity window, for lean NOx reduction towards lower temperatures. In particular Ag–Al2O3 with 3 wt% silver is active for NOx reduction under methanol-SCR conditions in a broad temperature interval (200–500 °C), with high activity in the low temperature range (maximum around 300 °C) typical for exhaust gases from diesel and other lean burn engines. Furthermore, increasing the C/N molar ratio enhances the reduction of NOx. However, too high C/N ratios results in poor selectivity to N2. 相似文献
44.
Fredrik Gunnarsson Jenny-Yue Zheng Hannes Kannisto Clément Cid Anna Lindholm Miroslawa Milh Magnus Skoglundh Hanna Härelind 《Topics in Catalysis》2013,56(1-8):416-420
The influence of ageing temperature, silver loading and type of reducing agent on the lean NO x reduction over silver–alumina catalysts was investigated with n-octane and bio-diesel (NExBTL) as reducing agent. The catalysts (2 and 6 wt% Ag–Al2O3) were prepared with a sol–gel method including freeze drying and the evaluation of NO x reduction and aging were performed using a synthetic gas-flow reactor. The results indicate a relatively high NO x reduction for both reducing agents. The hydrothermally treated 6 wt% Ag–Al2O3 sample displays a maximum NO x reduction of 78 % at 350 °C for n-octane as reductant and the corresponding value for NExBTL is 60 %. Furthermore, the catalysts show high durability and an increase in activity for NO x reduction after ageing at temperatures up to 650 °C, with n-octane as reducing agent. 相似文献
45.
Roman Klimkiewicz Helena Teterycz Hanna Grabowska Ireneusz Morawski Ludwik Syper Benedykt W. Licznerski 《Journal of the American Oil Chemists' Society》2001,78(5):533-535
A mixture of methyl esters of fatty acids obtained by transterification of nonerucic rape oil was ketonized. The starting
material, diluted with methanol, was converted at atmospheric pressure over a catalyst that contained Sn, Ce, and Rh oxides
in a molar ratio of 90:9:1. At a temperature of 385°C ketones were obtained with a total yield of 63% at the 96% conversion
of starting material. The reported experiments prove that catalysts other than iron that are active in ketonization of primary
alcohols can be successfully used in ketonization of esters of fatty acids. The kind of diluent used plays a crucial role
in the conversion. 相似文献
46.
Sajith Thottathil Abdulrahman Zakiah Ahmad Sabu Thomas Hanna J. Maria Azerai Ali Rahman 《应用聚合物科学杂志》2020,137(44):49372
The influence of boric acid (BA) and borax (BO) neutron-absorbing fillers on thermal stability and viscoelastic behavior of natural rubber (NR) low-density polyethylene composites has been studied. The thermal degradation and dynamic mechanical properties of the composites have been analyzed as a function of temperature. The results revealed the enhancement of thermal stability of the composites by the addition of BA and BO fillers. The flame resistance of the material was improved by the addition of both the fillers. The storage modulus was found to be dependent upon the temperature and nature of the filler. The amount of NR chains immobilized by filler particles has been quantified from dynamic mechanical analysis and secondary filler/filler interactions have been verified by the Payne effect analysis. Finally, the experimental results have been compared with theoretical predictions. 相似文献
47.
Jiji Abraham Krishnan Sidhardhan Sisanth Ajesh Kulamamvila Zachariah Hanna Joseph Mariya Soney C. George Nandakumar Kalarikkal Sabu Thomas 《应用聚合物科学杂志》2020,137(46):49429
Obtaining strong interfacial interaction between filler and polymer matrix is very crucial for the fabrication of polymer nanocomposites with superior performance. Present study is aimed to fabricate high performance styrene butadiene rubber (SBR) nanocomposites with imidazolium type ionic liquid modified multiwalled carbon nanotube (MWCNT). Ionic liquid facilitates the dispersion of MWCNT in rubber matrix and it is obvious from transmission electron microscopy images. Diffusion of toluene through SBR nanocomposite membranes has been investigated as a function of surface modified MWCNT (f-MWCNT) content to analyze the chain dynamics and filler-polymer interactions. O2 gas barrier effect of nanocomposites with special reference to the filler loading is explored. The substantial improvement in the barrier effect in presence of filler interpreted on the grounds of a theoretical model describing permeability of heterogeneous systems. Finally solvent sensing characteristics of prepared nanocomposites are also analyzed and it is observed that prepared nanocomposites can be used as a flexible solvent sensor. 相似文献
48.
Preparation of dual‐layer acetylated methyl cellulose hollow fiber membranes via co‐extrusion using thermally induced phase separation and non‐solvent induced phase separation methods 下载免费PDF全文
Hanna Jang Du‐Hyun Song Hye‐Jin Lee Seong‐Han Lim In‐Chul Kim Young‐Nam Kwon 《应用聚合物科学杂志》2015,132(43)
Dual‐layer acetylated methyl cellulose (AMC) hollow fiber membranes were prepared by coupling the thermally induced phase separation (TIPS) and non‐solvent induced phase separation (NIPS) methods through a co‐extrusion process. The TIPS layer was optimized by investigating the effects of coagulant composition on morphology and tensile strength. The solvent in the aqueous coagulation bath caused both delayed liquid–liquid demixing and decreased polymer concentration at the membrane surface, leading to porous structure. The addition of an additive (triethylene glycol, (TEG)) to the NIPS solution resolved the adhesion instability problem of the TIPS and NIPS layers, which occurred due to the different phase separation rates. The dual‐layer AMC membrane showed good mechanical strength and performance. Comparison of the fouling resistance of the AMC membranes with dual‐layer polyvinylidene fluoride (PVDF) hollow fiber membranes fabricated with the same method revealed less fouling of the AMC than the PVDF hollow fiber membrane. This study demonstrated that a dual‐layer AMC membrane with good mechanical strength, performance, and fouling resistance can be successfully fabricated by a one‐step process of TIPS and NIPS. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42715. 相似文献
49.
DNA Primer Extension with Cyclopropenylated 7‐Deaza‐2′‐deoxyadenosine and Efficient Bioorthogonal Labeling in Vitro and in Living Cells 下载免费PDF全文
Dr. Damian Ploschik Dr. Franziska Rönicke Hanna Beike Dr. Ralf Strasser Prof. Dr. Hans‐Achim Wagenknecht 《Chembiochem : a European journal of chemical biology》2018,19(18):1949-1953
A deoxyadenosine triphosphate (dATP) analogue for DNA labeling was synthesized with the 1‐methylcyclopropene (1MCP) group at the 7‐position of 7‐deaza‐2′‐deoxyadenosine and applied for primer extension experiments. The real‐time kinetic data reveals that this 1MCP‐modified dATP analogue is incorporated into DNA much faster than that of the similarly 1MCP‐modified deoxyuridine triphosphate (dUTP) analogue. The postsynthetic fluorescent labeling of these oligonucleotides works efficiently according to PAGE analysis, and can be applied for immobilization of a functional antibody on a surface. Site‐specific labeling at two different positions in DNA was achieved and the bioorthogonality of the postsynthetic fluorescent labeling was demonstrated in living HeLa cells. 相似文献
50.
Völler GH Krawczyk JM Pesic A Krawczyk B Nachtigall J Süssmuth RD 《Chembiochem : a European journal of chemical biology》2012,13(8):1174-1183
Lantibiotics are a large group of ribosomally synthesized peptides post-translationally modified to incorporate the amino acid lanthionine. They are classified, according to their biosynthetic pathway and bioactivity, into three major subtypes. Of Actinomycetes type III lantibiotics, only four peptides (SapB, SapT, LabA1, and LabA2) have been described and structurally characterized, although homologous gene clusters are abundant in other Actinomycetes. All these gene clusters share a similar architecture with a characteristic Ser/Ser/Cys motif in precursor peptides, which has previously been suggested to act as a precursor for lanthionine (SapB) and labionin (LabA2) rings. Mass spectrometry screening led to the discovery and characterization of three new representatives of type III lantibiotics: Avermipeptin (Avi), Erythreapeptin (Ery), and Griseopeptin (Gri) from Streptomyces avermitilis DSM 46492, Saccharopolyspora erythraea NRRL 2338, and Streptomyces griseus DSM 40236, respectively. Apart from the assignment of these peptides to their corresponding gene clusters, additional investigations on Avi, Ery and Gri peptides indicate stepwise leader processing by putative aminopeptidase-like protease(s), thus yielding mixtures of differently N-terminal-processed lantibiotic peptides. Similar peptide processing was observed for a heterologously expressed eryth biosynthetic gene cluster expressed in a Streptomyces host system. Remarkably, all isolates of the new type III lantibiotics contain both the amino acids lanthionine and labionin, thus implying dual-mode cyclase activity of the processing lyase-kinase-cyclase enzymes. These findings have implications for the structures and maturation of other type III lantibiotics from Actinomycetes. 相似文献