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51.
Catalysis Letters - Hydroxyl groups are considered as anchoring sites for active components on catalysts. Guided by this viewpoint, 4 wt. % Ag/Al2O3 catalyst derived from Boehmite (AlOOH) was... 相似文献
52.
Molybdate and tungstate as corrosion inhibitors for cold rolling steel in hydrochloric acid solution 总被引:2,自引:0,他引:2
The inhibition effects of molybdate and tungstate on the corrosion of cold rolling steel (CRS) in hydrochloric acid solution (0.1-0.5 M) were investigated by weight loss and electrochemistry methods. The results reveal that both molybdate and tungstate are very good inhibitors with little concentration. The adsorption of inhibitors on the CRS surface basically obeys the Langmuir adsorption isotherm equation. The effect of temperature on the corrosion behavior of CRS was also studied at 25 °C and 35 °C, the thermodynamic parameters such as adsorption heat (ΔH0) and adsorption free energy (ΔG0) were calculated. In the same conditions, a comparative study of corrosion inhibition of molybdate and tungstate indicated that molybdate was the better inhibitor in 0.1 M HCl. However, the value of percentage inhibition efficiency (IE) was dependent on the concentration of inhibitors in 0.2-0.5 M HCl. It seemed that molybdate did not have the strong inhibitive effect compared to tungstate with relatively small concentration of inhibitors, but molybdate was a better inhibitor over a wide concentration range of inhibitors. A kinetic study of cold rolling steel in uninhibited and inhibited acid was also discussed. Various parameters such as rate constant k and the kinetic parameter B were calculated for the reactions of corrosion. Polarization curves showed that both molybdate and tungstate are mixed-type inhibitors in acidic media. 相似文献
53.
本文论述了现有液压胀形法生产护环所存在的不足,介绍了新一代液压胀形工艺即外补液胀形的原理、优点,以及在我国首次生产应用中所显示出的明显的技术经济效益。 相似文献
54.
长轴表面激光淬火变形与控制 总被引:1,自引:0,他引:1
应用激光淬火强化技术控制长轴的淬火变形,分析了激光淬火变形的原因和影响因素。研究结果表明,激光淬火不仅可使长轴振摆变形量控制在很小的范围内,而且可将已变形的长轴校直到很高的精度。 相似文献
55.
Hongbing Song Lei Liu Bingxiao Feng Haozhong Wang Meng Xiao Hengjun Gai Yubao Tang Xiaofei Qu Tingting Huang 《中国化学工程学报》2021,40(12):293-303
In this work, modified g-C3N4 was fabricated successfully by calcination of ionic liquid (IL) and urea. The addition of IL changed the polymerization mode of urea, induced the self-assembly of urea molecules, modified the morphological structure of the tightly packed g-C3N4, and extended the electron conjugation system. When using 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) as a modifier, the heteroatom Cl could be inserted into the g-C3N4 to optimize the electronic structure. The results of characterizations indicate that the unique structure of modified g-C3N4 has an expanded electron delocalization range, introduces an interlayer charge transmission channel, promotes the charge transmission, reduces the band gap, enhances the absorption of visible light, and inhibits electron-hole recombination. Modified g-C3N4 showed excellent photocatalytic performance for the degradation of rhodamine B and tetracycline. Furthermore, the effect of different anions in 1-butyl-3-methylimidazolium salts ([Bmim]Cl, [Bmim]Br, [Bmim][BF4], and [Bmim][PF6]) on the structure and function of g-C3N4 are discussed. 相似文献
56.
Yichuan Liu Hui-Qi Qu Xiao Chang Lifeng Tian Jingchun Qu Joseph Glessner Patrick M. A. Sleiman Hakon Hakonarson 《International journal of molecular sciences》2021,22(7)
RNA-seq has been a powerful method to detect the differentially expressed genes/long non-coding RNAs (lncRNAs) in schizophrenia (SCZ) patients; however, due to overfitting problems differentially expressed targets (DETs) cannot be used properly as biomarkers. This study used machine learning to reduce gene/non-coding RNA features. Dorsolateral prefrontal cortex (dlpfc) RNA-seq data from 254 individuals was obtained from the CommonMind consortium. The average predictive accuracy for SCZ patients was 67% based on coding genes, and 96% based on long non-coding RNAs (lncRNAs). Machine learning is a powerful algorithm to reduce functional biomarkers in SCZ patients. The lncRNAs capture the characteristics of SCZ tissue more accurately than mRNA as the former regulate every level of gene expression, not limited to mRNA levels. 相似文献
57.
Xin Fusheng Ding Wangwang Tao Qiying Tian Hanqing Chen Gang Qin Mingli Qu Xuanhui 《Metallurgical and Materials Transactions A》2022,53(4):1164-1175
Metallurgical and Materials Transactions A - In this work, we used hydride-dehydride Ti (HDH-Ti) powders (with the oxygen levels of 0.17 and 0.51 wt pct, respectively) combined with microstructural... 相似文献
58.
Islam S. Humail F. Akhtar S.J. Askari M. Tufail Xuanhui Qu 《International Journal of Refractory Metals and Hard Materials》2007,25(5-6):380-385
Tungsten heavy alloys (WHAs) are metal–metal composites consisting of nearly pure spherical tungsten particles embedded in a Ni–Fe–W or Ni–Co–W or Ni–Cu–W ductile matrix. In this dual phase alloy, there are several complicated relations between the ductile matrix and hard tungsten particles. The aim of this research was to examine the effect of varying tungsten content on the microstructure and mechanical properties of tungsten heavy alloys. The microstructural parameters (grain size, connectivity, contiguity and solid volume fraction) were measured and were found to have a significant effect on the mechanical properties of tungsten-based heavy alloys. The result shows that the binding strength between the W and the matrix phase has a major influence on the ductility of tungsten-based alloys. The larger this binding force is, the better the ductility is. 相似文献
59.
60.