Vinyl acetate monomer—a pilot plant study

The kinetics of the reaction of acetic acid and acetylene over zinc acetate-activated carbon catalyst was investigated over a wide range of process variables in a pilot reactor. Although various catalytic reaction mechanisms were postulated, the rate of reaction was most satisfactorily correlated by a mechanism of surface reaction between charged adsorbed acetic acid and acetylene, which assumes that the rate controlling step was the irreversible charged adsorption of acetylene and acetic acid.     

Ionoluminescence decay measured with single ions

A new ion beam analysis-based, single ion technique called the time to first photon has been developed to measure the decay of the luminescence signal of phosphors. Such measurements are currently needed to study luminescence decay mechanisms following high-density excitations and to identify strongly luminescent phosphor coatings with short lifetimes for ion photon emission microscopy (IPEM). The samples for this technique consist of thin phosphor layers placed or coated on the surface of PIN diodes. Single ions from an accelerator strike this sample and simultaneously create ion beam induced luminescence (IBIL) from the phosphor that is measured by a single-photon-detector, and an ion beam induced charge collection (IBICC) signal in the PIN diode. In this case, the IBICC signal provides the start pulse and the IBIL signal the stop pulse to a time to amplitude converter. It is straightforward to show that this approach also measures a signal proportional to activity versus time with an accuracy of 5% as long as the number of detected photons per ion is less than 0.1, which usually requires the use of absorbers for the IBIL detector or electronic discrimination for the IBIL signals. Details of the new analysis are given together with examples of luminescence decay measurements of several ceramic phosphors being considered to coat IPEM samples. IPEM is currently being developed at Sandia National Laboratory (SNL), the University of North Texas in Denton, and the Universities and INFN of Padova and Torino.     

Properties of ligno‐cellulose fiber Hildegardia

Studies on some properties such as the density, the degradation temperatures, the morphology and the spectral features of the ligno‐cellulose fiber Hildegardia were carried out in both untreated and alkali treated form. The fibers are found to have good morphology and moderate initial and final degradation temperatures. On alkali treatment, the lignin was found to be eliminated. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 2216–2221, 2002     

Synthesis and characterization of tungsten disulphide films grown by pulsed-laser deposition

The synthesis and characterization of tungsten disulphide (WS₂) films grown on 440C stainless steel substrates using the 248 nm line from a KrF excimer laser are reported. Film properties could be adjusted by controlling substrate temperature and by laser or thermal anneals. X-ray photoelectron spectroscopy, glancing angle XRD, Raman spectroscopy and high-resolution scanning electron microscopy were used to evaluate film chemistry, crystallinity and morphology. Films grown at room temperature were amorphous, near stoichiometric, and had a multiplicity of chemical states. Local order and bonding were improved most dramatically through post-deposition laser anneals. Crystallite size could be increased by raising the substrate temperature during deposition and, to a lesser degree, by post-deposition thermal anneals. Local disorder was observed within the larger crystallites compared to those that were laser annealed. Crystallinity was induced in amorphous films by mechanical rubbing at room temperature under conditions where frictional heating was negligible. The degree of control over film properties provided by PLD demonstrates its value for growing/designing tribological coatings.     

A mathematical framework for algorithm-based fault-tolerant computing over a ring of integers

In this work, we establish a complete mathematical framework for algorithm-based fault-tolerant computing for data vectors defined over a ring of integers. The ring of integers consists of integers {0,1,…,M−1} and all the arithmetic operations are performed modulo the integerM, which is assumed to be composite. The importance of the work lies in the suitability of modulo arithmetic in certain computational environments. Lack of an underlying Galois field,GF(q), presents a unique challenge to this framework. We develop the theory and algorithms for single as well as multiple fault correction and detection. We also analyze the parallel and serial nature of the encoder and decoder configurations. Certain known but rather old results in the theory of numbers dealing with linear congruences and matrix algebra are also described and extended further using mathematical terminology that modern-day researchers are expected to be familiar with.     

Instability due to Viscosity Stratification Downstream of a Centerline Injector

A common injector geometry upstream of a static mixer is the centerline injector. A flow instability can arise due to viscosity differences between the injected core‐flow and the outer co‐flow. This instability can adversely affect the effectiveness of the mixing operation. An experimental investigation of miscible viscosity‐stratified flow in a circular geometry was performed using Laser Induced Fluorescence (LIF) and Particle Image Velocimetry (PIV). The experimental results for the stable region agree with the analytical results. The unstable region exhibits different modes depending on the viscosity ratio, volume flux ratio, and Reynolds number. The modes include wavy core‐flow with fissures and wavy core‐flow with core breakup. The time‐averaged experiment velocity profiles for the unstable core indicate a broadening of the jet at the centerline, which is consistent with the LIF visualization.     

Spectrum efficiency analysis for microcellular mobile radio systems

Spectrum efficiency is analysed in a microcellular mobile radio environment considering an appropriate model for UHF ground-wave path loss. The influence of cluster size and reuse distance on the spectrum efficiency is investigated by obtaining the probability of cochannel interference for uncorrelated Rayleigh fading interferers and Rician fading desired signal. The effect of traffic intensity is also considered in evaluating the spectrum efficiency.<>     

Scanned electron beam irradiation of Ti Schottky contacts to n-GaAs

Ti Schottky contacts were formed on n-GaAs surfaces and irradiated using a low energy scanned electron beam at various fluence levels from 10¹⁵ to 10¹⁸ cm^–2. For fluence levels up to 10¹⁷ cm^–2, the Schottky contacts were found to exhibit a reduction in their leakage currents and increased barrier voltages. For fluence levels in excess of 10¹⁷ cm^–2, the Schottky diodes were found to exhibit significantly increased leakage currents and barrier voltages. The changes in leakage currents were consistent with the changes in their respective interface state density (D _it) values. However, the electron beam irradiation had little or no effect on the diode ideality factorn.     

Function dependent fully testable programmable logic array

Two techniques for designing function-dependent easily testable programmable logic arrays are presented. The techniques can detect all the multiple stuck-at, crosspoint and bridging faults, as compared with most of the existing techniques where some of the faults, especially bridging faults, remain undetected.<>     

One-, two-, and three-photon pumped lasing in a novel liquid dye salt system

We report the observation of one-, two-, and three-photon pumped lasing in the same medium, a novel liquid dye salt system when excited by pulsed 0.532-, 1.06-, and /spl sim/1.49-/spl mu/m coherent radiation pulses, respectively. Since the gain medium is a liquid and not a solution, it contains a significantly higher effective dye concentration and, therefore, is highly suitable for multiphoton pumped lasing and optical power limiting applications. The lasing spectra, temporal waveforms, near- and far-field intensity distributions, and output/input efficiency were measured under the conditions of one-, two-, and three-photon pump configurations.