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71.
In this study, first the pure polystyrenes (PS) with different molecular weights (350 × 103 and 500 × 103) have been modified by the chemical modification with succinic anhydride (SA), maleic anhydride (MA), and phthalic anhydride (PhA) and then the polystyrene based composites (CPS) prepared by addition of modified polystyrenes (MPS) into pure PS (with the molecular weight of 230 × 103) in weight % ratios of 90 : 10, 80 : 20, and 70 : 30. Ultrasonic measurements were performed on PS/MPS blends of different weight percent of MPSs by use of pulse echo method with 5-MHz frequency at room temperature. Elastic properties namely; longitudinal modulus (L), Young's modulus (E), bulk modulus (K) and shear modulus (G), Poisson's ratio (μ), and acoustic impedance (Z) were calculated from the ultrasonic velocities values measured and densities values obtained experimentally. Atomic force microscopy (AFM) has been used for determining the microstructure of composites. The variations of these parameters with increasing MPSs weight percentage content in PS/MPS from 10 to 30 have been discussed. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
72.
A configurational biomimetic imprinting technique was used to prepare recognition sites for glucose in copolymers of 2‐hydroxyethyl methacrylate (HEMA) and methacrylic acid (MAA) prepared with crosslinking agents containing poly(ethylene glycol) (PEG). We report on the structure, diffusive, and recognition characteristics of these gels, the effect of the type and ratio of crosslinking agent, as well as the template/comonomer ratios on glucose binding ability. The highest equilibrium glucose binding was found as 2.67 mg/g dry polymer when PEG monomethacrylate (PEGMMA) was used in combination with tetra ethylene glycol dimethacrylate (TEGDMA) (50%) as a crosslinking agent. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 103: 432–441, 2007 相似文献
73.
Hatice Citakoglu Murat Cobaner Tefaruk Haktanir Ozgur Kisi 《Water Resources Management》2014,28(1):99-113
Monthly mean reference evapotranspiration (ET 0 ) is estimated using adaptive network based fuzzy inference system (ANFIS) and artificial neural network (ANN) models. Various combinations of long-term average monthly climatic data of wind speed, air temperature, relative humidity, and solar radiation, recorded at stations in Turkey, are used as inputs to the ANFIS and ANN models so as to calculate ET 0 given by the FAO-56 PM (Penman-Monteith) equation. First, a comparison is made among the estimates provided by the ANFIS and ANN models and those by the empirical methods of Hargreaves and Ritchie. Next, the empirical models are calibrated using the ET 0 values given by FAO-56 PM, and the estimates by the ANFIS and ANN techniques are compared with those of the calibrated models. Mean square error, mean absolute error, and determination coefficient statistics are used as comparison criteria for evaluation of performances of all the models considered. Based on these evaluations, it is found that the ANFIS and ANN schemes can be employed successfully in modeling the monthly mean ET 0 , because both approaches yield better estimates than the classical methods, and yet ANFIS being slightly more successful than ANN. 相似文献
74.
Alexander Belushkin Filiz Yesilkoy Juan Jose Gonzlez‐Lpez Juan Carlos Ruiz‐Rodríguez Ricard Ferrer Anna Fbrega Hatice Altug 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(3)
New point‐of‐care diagnostic devices are urgently needed for rapid and accurate diagnosis, particularly in the management of life‐threatening infections and sepsis, where immediate treatment is key. Sepsis is a critical condition caused by systemic response to infection, with chances of survival drastically decreasing every hour. A novel portable biosensor based on nanoparticle‐enhanced digital plasmonic imaging is reported for rapid and sensitive detection of two sepsis‐related inflammatory biomarkers, procalcitonin (PCT) and C‐reactive protein (CRP) directly from blood serum. The device achieves outstanding limit of detection of 21.3 pg mL?1 for PCT and 36 pg mL?1 for CRP, and dynamic range of at least three orders of magnitude. The portable device is deployed at Vall d'Hebron University Hospital in Spain and tested with a wide range of patient samples with sepsis, noninfectious systemic inflammatory response syndrome (SIRS), and healthy subjects. The results are validated against ultimate clinical diagnosis and currently used immunoassays, and show that the device provides accurate and robust performance equivalent to gold‐standard laboratory tests. Importantly, the plasmonic imager can enable identification of PCT levels typical of sepsis and SIRS patients in less than 15 min. The compact and low‐cost device is a promising solution for assisting rapid and accurate on‐site sepsis diagnosis. 相似文献
75.
Assessing facial beauty through proportion analysis by image processing and supervised learning 总被引:2,自引:0,他引:2
Hatice Gunes Massimo Piccardi 《International journal of human-computer studies》2006,64(12):1184-1199
Perception of universal facial beauty has long been debated amongst psychologists and anthropologists. In this paper, we perform experiments to evaluate the extent of universal beauty by surveying a number of diverse human referees to grade a collection of female facial images. Results obtained show that there exists a strong central tendency in the human grades, thus exhibiting agreement on beauty assessment. We then trained an automated classifier using the average human grades as the ground truth and used it to classify an independent test set of facial images. The high accuracy achieved proves that this classifier can be used as a general, automated tool for objective classification of female facial beauty. Potential applications exist in the entertainment industry, cosmetic industry, virtual media, and plastic surgery. 相似文献
76.
Yavuz Akbulut Serkan Şendağ Gürkay Birinci Kerem Kılıçer Mehmet C Şahin Hatice F Odabaşı 《Computers & Education》2008
Internet contributes to the development of science and facilitates scientific demeanors while it also serves as a ground for academic misdemeanors. Recent studies indicate that Internet facilitates and spreads academic dishonesty. The purpose of the current study is to investigate the extent of involvement of Turkish university students in academic dishonesty practices facilitated through Internet (i.e. e-dishonesty) and to question the conditions which lead to e-dishonesty. Three hundred and forty nine education faculty students from the most populated state university in Turkey were administered two Likert-Scale questionnaires developed by the researchers. After the reliability and validity conditions were met, two exploratory factor analyses were conducted. The first one revealed the factors constituting common types of e-dishonesty among undergraduate students which were fraudulence, plagiarism, falsification, delinquency, and unauthorized help. The second factor analysis exhibited individual and contextual factors triggering e-dishonesty which were named as individual factors, institutional policies and peer pressure. Results of both analyses are discussed and suggestions for further research are provided. 相似文献
77.
Poly(N‐isopropylacrylamide)s (PNIPAAM)s were synthesized via free‐radical polymerization using a ceric ammonium nitrate, Ce(IV)–α‐ω‐dihydroxy(polydimethylsiloxane) (Tegomer H‐Si 2111, PDMS) redox pair in hexane at 30°C in a nitrogen atmosphere. The dependence of the initiation and termination steps on the [NIPAAM]/[Ce(IV)] and [NIPAAM]/[PDMS] ratios were studied using gravimetry and FTIR, 1H‐NMR, UV‐vis, and GFAA spectroscopy techniques. Gravimetric results indicated that, in the case of high concentrations of PDMS, the percentage of the solid portions of the products decreased while the amount of the oligomeric NIPAAM chains increased, that is, as the amount of PDMS in hexane was increased, the number of the short NIPAAM chains having PDMS segments at the two ends, also increased. UV‐vis results showed that the LCST of PNIPAAM initiated with Ce(IV) alone was higher than those of the ones that were synthesized using common initiator systems such as an ammonium persulfate–N,N,N′,N′‐tetramethylethylenediamine redox pair and azobis(isobutyronitrile). Further, it was observed that both siloxane blocks and ? NH? groups forming coordination bonds with free Ce(IV) ions and/or metal–ligand complexes had an important effect on the aggregation process of the chains. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 1248–1254, 2003 相似文献
78.
Polychelates were synthesized by the addition of aqueous solutions of copper(II), cadmium(II), and nickel(II) chlorides to aqueous solutions of poly(maleic anhydride‐alt‐acrylic acid) [poly(MA‐alt‐AA)] in different pH media. The thermal properties of poly(MA‐alt‐AA) and its metal complexes were investigated with thermogravimetry and differential scanning calorimetry (DSC) measurements. The polychelates showed higher thermal stability than poly(MA‐alt‐AA). The thermogravimetry of the polymer–metal complexes revealed variations of the thermal stability by complexation with metal ions. The relative thermal stabilities of the systems under investigation were as follows: poly(MA‐alt‐AA)–Cd(II) > poly(MA‐alt‐AA)–Cu(II) > poly(MA‐alt‐AA)–Ni(II) > poly(MA‐alt‐AA). The effects of pH on the complexation and gravimetric analysis of the polychelates were also studied. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3926–3930, 2006 相似文献
79.
Ercan Öztemel Hatice Kolay Cemalettin Kubat 《Journal of Intelligent Manufacturing》2004,15(4):535-542
Scheduling problems are becoming more and more complex everyday. This makes the current rules and algorithms difficult to comply with the requirements. New machines with the capabilities of processing more than one jobs is being developed. Sometimes one job is divided into parts and processed by more than one machine at the same time. These make the current algorithms insufficient. Artificial intelligence technologies, especially expert systems are proven to deal with such dynamic complex problems in several domains. In this study, an example of such a complex problem is introduced and knowledge-based scheduling for these kind of problems is elaborated with a real life industrial example. 相似文献
80.
Adsorption of proteins on solid surfaces is widely studied because of its importance in various biotechnological, medical, and technical applications, e.g., biosensors, cardiovascular implants, and chromatography. Adsorption thermodynamics has been studied on the microbeads of N,N′‐diethylaminoethyl (DEAE) Dextran anion exchanger for the human serum albumin (HSA) at 25, 30, 35, 40, and 45°C. As a result, some thermodynamic parameters like Freundlich constants, thermodynamic equilibrium constant (KD), standard free energy changes (ΔGassoc), standard entropy changes (ΔSassoc), and standard enthalpy change (ΔHassoc) have been evaluated. Using the linear Van't Hoff plot, ΔHassoc value of the system for the interaction of bovine serum albumin (BSA)‐adsorbed crosslinked DEAE dextran microbeads was determined as 20.650 kJ/mol. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3942–3947, 2006 相似文献