Synthesis and characterization of phosphonate and aromatic-based polynorbornene polymers derived from the ring opening metathesis polymerization method and investigation of their thermal properties

In the present study, phosphonate ester, phosphonic acid, and aromatic (phenyl, naphthalene, anthracene) groups containing polymers were synthesized by the ROMP method to analyze thermal properties of these polymers. Thermal stability of the synthesized polymers is tested by thermal gravimetric analysis under nitrogen, air, and microscale combustion calorimetry analysis. Analysis shows that thermal behavior is directly related to the phosphorus level in the copolymer series. All the polymers are thermally stable under nitrogen and air up to 900 °C. Synergistic charring effect under air was observed between aromatic groups and phosphonic acid functionality in the copolymer series. Anthracene units have a greater potential to form carbonaceous char than the naphthalene and phenyl units. Phosphonate ester and naphthalene units bearing copolymers (P3A) gave 8.13% char yield at 900 °C under air. Phosphonic acid derivatives of this polymer, P3D, gave a highest char residue of 17.15% under the same condition. The introduction of phosphonate and phosphonic acid in each copolymer series is also beneficial in reducing the peak heat release rate (PHRR). Cleavage of the phosphonate ester bearing homopolymer (P4) to phosphonic acid (P4A) causes a sharp decrease in the PHRR ratio from 274 to 28.2 W/g. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47085.     

Synthesis of phosphorus‐ and phenyl‐based ROMP polymers and investigation of their effects on the thermomechanical and flammability properties of a polypropylene–IFR system

In this study, we present an approach for the synthesis of novel phosphorous‐ or phenyl‐ containing polymers, 2_phenyl, 3_phospho, and 2_phenyl‐co‐3_phospho, derived from ring‐opening metathesis polymerization (ROMP), to reduce the flammability of polypropylene (PP). The composites were processed by melt‐blending ROMP polymers and octaphenyl–polyhedral oligomeric silsesquioxane with PP/intumescent flame retardant (IFR) compounds at different compositions. The composites were characterized by limiting oxygen index (LOI), UL‐94, and mechanical tests as well as thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The molecular structures of phosphorous‐ and phenyl‐containing polymers were proved by ¹H‐NMR, ¹³C‐NMR, and Fourier transform infrared spectroscopy. The online rheological measurements indicated that the addition of additives to the PP/IFR system increased the melt viscosity of the compounds regardless of the type. The DSC analysis showed that the addition of ROMP polymers to the PP/IFR system influenced the crystal perfection and degree of crystallization. TGA analysis of the composites revealed that the addition of ROMP polymers to PP/IFR compounds deteriorated the thermal stability as the amount of phosphorus increased in the matrix. Dynamic mechanical properties such as storage modulus (E′) and loss modulus (E″) of the composites were lowered by the addition of ROMP polymers. The LOI and UL‐94 rating of PP/IFR were enhanced by the addition of ROMP polymers. It was successfully demonstrated that the novel phosphorous‐ or phenyl‐containing polymers were highly potent additives in optimizing the flammability of PP composites. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 45998.     

Thermal and neutron shielding properties of <Superscript>10</Superscript>B<Subscript>2</Subscript>O<Subscript>3</Subscript>/polyimide hybrid materials

In this study, ¹⁰B₂O₃/polyimide (PI) hybrid materials were synthesized with the aim to improve their thermal stability and neutron shielding properties. 3,3′-Diaminodiphenyl sulfone (DADPS) reacted with 3,3′,4,4′-benzophenonetetracarboxylic dianhydride (BTDA) in N-methyl-2-pyrrolidone (NMP) and mixed with amine functionalized ¹⁰B₂O₃ to prepare a series of poly (amic acid), meanwhile, corresponding PIs were obtained via the thermal imidization procedures. The morphologies and structures of the prepared hybrid materials were characterized by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR). The thermooxidative and flame retardancy properties of the PI films were examined by thermogravimetric analysis (TGA) and limiting oxygen ındex (LOI). The experimental results showed that as the amount of functionalized ¹⁰B₂O₃ was increased, flame retardant properties of the hybrid films were increased. Hybrid materials were also irradiated with thermal neutrons. The neutron shielding properties increasing depends on the amount and the distribution of the ¹⁰B isotope.     

Determination of physical properties of carbonate rocks from P-wave velocity

Velocity, density, porosity, void ratio, water absorption by weight and P-wave velocity tests were conducted on 14 different carbonate rocks. Strong correlations between P-wave velocity and all the physical properties of the rock were found. The relations follow a linear function. The equations developed were compared with others in the literature. Although it appears that the physical properties of the tested carbonate rocks can be estimated from P-wave velocity, the validity of the derived equations must be checked for other carbonate rocks as the equations given are likely to be specific to the test method and vary with rock type, degree of saturation and presence of bedding planes.      

Technology independent circuit sizing for standard cell based design using neural networks

This paper presents a neural network (NN) approach for modeling the time characteristics of fundamental gates of digital integrated circuits that include inverter, NAND, NOR, and XOR gates. The modeling approach presented here is technology independent, fast, and accurate, which makes it suitable for circuit simulators. Firstly transient simulations were done in order to obtain delay times for different transistor sizes and different load capacitances using AMIS 1.5 μm, TSMC 0.25 μm and TSMC 0.18 μm technology parameters with HSPICE. These delay time results constitute the inputs of NN while the outputs are transistor sizes. Then, two neural network structures, multilayer perceptron (MLP) and general regression neural network (GRNN), were compared to estimate the transistor sizes. MLP achieved 91 acceptable results through 120 test data where GRNN had 77. The important thing is that the NN is able to generalize the input–output mapping and estimates the outputs for new data which were not applied to the NN for training before. As a conclusion, fundamental gates used for standard cell based VLSI design can be sized for desired delay times using neural networks without knowing SPICE technology parameters.     

Experimental and Numerical Investigation on Hydraulic Performance of Slit-check Dams in Subcritical Flow Condition

Water Resources Management - Slit-check dams have a flow regulation function under normal flow conditions as well as holding large solid (debris flow control). However, the effects of such...     

Experimental study of gasoline-ethanol-hydrogen blends combustion in an SI engine

This study presents experimental results of engine performance, combustion and emissions in an SI engine fueled by gasoline-ethanol-hydrogen blends. In the experimental studies, engine performance and emission values were analyzed fueled by gasoline, gasoline-ethanol and gasoline-ethanol-hydrogen blends, respectively. When ethanol has been added volumetrically to gasoline 20% of ethanol (G80E20), engine performance and emissions have been worsened. However, the engine performance and emission values have been improved with the adding of hydrogen to blend. The results showed that the addition of hydrogen to the gasoline-ethanol blend improved the combustion process and improved the combustion efficiency, expanded the combustibility range of the gasoline-ethanol blend, reduced emissions. But, nitrogen oxide emission values increased with the adding of hydrogen.     

Wind energy potential in Antakya and skenderun regions, Turkey

The aim of this study is to establish the potential and the feasibility basis for the wind energy resources in some locations of East Mediterranean region of Turkey and provide suitable data for evaluating the potential wind power. For this purpose, hourly wind data, which were observed between the years 1997 and 2001 at the meteorological stations of Antakya and skenderun regions, were used. The dominant wind directions, the mean values, wind speeds, wind potential and the frequency distributions were determined. The results were classified according to the height above the ground level. Finally, the wind atlas of these regions in the form of contours of constant wind speed and wind potential was produced.