On the prediction of gas hold-up in two-phase flow systems using an Euler–Euler model

We quantify the ability of the two-fluid Euler–Euler model to predict the overall gas hold-up during two-phase flow in vertical columns using a combination of experiments and simulations. Gas hold-up in a bubble column and gas hold-up in the less-frequently studied co-current flow are investigated. For homogeneous flow characterized by nearly uniform bubble size, Euler–Euler model predictions are within 10% of the experimental values for both modes of operation, if the bubble diameter supplied as input to the model is the average bubble diameter in the physical system. This also holds true for heterogeneous flow in bubble columns despite the presence of a broad distribution of bubble sizes, if turbulence and bubble swarm effects on momentum exchange between phases are properly accounted for. Swarm corrections adequate for bubble columns, are less successful for co-current heterogeneous flow, for which gas hold-up predictions are least accurate (average error of 22%).     

Time-Dependent Reliability Analysis of FRP Rehabilitated Pipes

The goal of this paper is to present work that demonstrates the application of probabilistic modeling to evaluate the long-term performance of fiber-reinforced polymer (FRP) rehabilitated piping components. The time-dependent reliability index is evaluated for a fully deteriorated piping component rehabilitated with FRP considering the demands of internal fluid pressure, external soil pressure, and traffic loading. Carbon FRP (CFRP) and glass FRP (GFRP) composites are compared and the influence of material deterioration, fiber volume fraction (FVF), and variation in thickness of the composite are assessed using a first order reliability method and compared to a steel pipe under similar loading. A CFRP rehabilitation scheme having a FVF greater than 40% would be needed to exceed the as-built reliability index of a steel pipe under time-dependent composite deterioration, while no practical GFRP FVF can achieve the performance of steel pipe in the presence of time-dependent composite deterioration. Variations in the coefficient of variation (COV) can adversely affect the safety of both FRP rehabilitation schemes where an increase in COV from 10 to 30% result in decreases in the reliability index by 39.4% for CFRP (40% FVF) and 39.7% for GFRP (40% FVF).     

Immobilized lipase reactors for modification of fats and oils—A review

This review focuses on the use of immobilized lipase technology to effect hydrolysis, ester synthesis, and interesterification reactions. The various immobilization procedures, reactor configurations, and process considerations are all reviewed and discussed.     

On the role of material property gradients in noncontacting thermoelectric NDE

Inclusions and other types of imperfections in nonmagnetic metals can be nondestructively detected by noncontacting magnetic measurements that sense the thermoelectric currents produced by directional heating and cooling of the specimen. The detectability of small and/or weak imperfections is ultimately limited by the intrinsic anisotropy and inhomogeneity of the material to be inspected. This paper investigates the spurious magnetic signature produced by the simplest type of macroscopic inhomogeneity when the material properties exhibit a linear spatial variation in the cross section of a slender bar. An analytical method has been developed for calculating the normal and tangential magnetic fields produced by the resulting thermoelectric currents. Experimental results from a highly inhomogeneous artificial copper/brass sintered specimen were found to be in very good quantitative agreement with our theoretical predictions and fully verified our analytical model. Similar measurements on a weakly inhomogeneous Ti–6Al–4V titanium-alloy bar were also shown to be in very good qualitative agreement with the predictions of the analytical model although the unexpectedly high magnitude of the observed signatures could not be verified by conventional contact measurements, therefore further efforts are needed to better understand the underlying physical phenomenon and clarifying the relationship between the strength of the signature and the very complex microstructural features of this popular high-strength alloy.     

Nitrogen mineralization of sewage sludge and composted poultry manure applied to willow in a greenhouse experiment

Nitrogen requirements for production of intensively cultured willow for use as a bioenergy crop coupled with the need for safe disposal of nutrient rich organic wastes provide an opportunity to reduce costs associated with bioenergy plantations. In order to minimize N leaching from sites treated with organic wastes, knowledge of the rate of N mineralization is needed. The objective of this study was to assess N mineralization rates of four organic residuals in a controlled greenhouse environment: composted poultry manure, composted sewage sludge, and anaerobically digested sewage sludge from two different municipalities. Thirty-six weeks after application, disappearance of the mass initially applied ranged from 20% to 50%. Gross nitrogen mineralization rate (N mass released expressed as a percentage of initially applied N) ranged from 12% to 57%. Non-composted treatments released greater amounts of nitrogen than composted treatments. Within composted treatments, net N release was estimated as 325 kgNha⁻¹ for poultry manure and 86 kgNha⁻¹ for sewage sludge. Syracuse and New York City sewage sludges, with 57% and 30% gross N release rates respectively, provided approximately 360 and 240 kg plant available Nha⁻¹, respectively. These estimates of N release suggest that the application rates could be halved and that sufficient N would be provided to meet crop needs and reduce leaching losses.     

Isobaric vapour-liquid equilibrium for the binary mixtures of 1-bromobutane with isomeric butanols at 40.0 and 101.3 kpa

A dynamic recirculating still was employed to measure isobaric vapour-liquid equilibrium at 40.0 and 101.3 kPa for the binary systems 1-bromobutane and each of the isomers of butanol. All mixtures show azeotropes at both pressures. The experimental VLE data are thermodynamically consistent and were correlated using Margules, Van Laar, Wilson, NRTL and UNIQUAC equations.     

SELECTION OF MULTICOMPONENT BATCH DISTILLATION SEQUENCES

As in continuous distillation systems, the design of batch distillation begins with the selection of a sequence of separations. This paper considers the usual case where the column processes multicom-ponent mixtures with the recycle of intermediate cuts. It is proved that this cyclic operation does converge to a “steady state” balance. This permits to model batch distillation with recycle as a function of the steady state variables, i.e. without the need of successive simulations to obtain the steady state. Furthermore, we use simplified analytical models which permit a quick approximation to the optimal design of a given sequence, thus aiding the designer in the screening of alternative separation sequences, to preselect one, or a small set of good sequences.     

Foundations of a functional approach to knowledge representation

We present a new approach to knowledge representation where knowledge bases are characterized not in terms of the structures they use to represent knowledge, but functionally, in terms of what they can be asked or told about some domain. Starting with a representation system that can be asked questions and told facts in a full first-order logical language, we then define ask- and tell-operations over an extended language that can refer not only to the domain but to what the knowledge base knows about that domain. The major technical result is that the resulting knowledge, which now includes auto-epistemic aspects, can still be represented symbolically in first-order terms. We also consider extensions to the framework such as defaults and definitional facilities. The overall result is a formal foundation for knowledge representation which, in accordance with current principles of software design, cleanly separates functionality from implementation structure.