Wireless Networks - Friendly spectrum jamming is a flexible scheme to establish secure communications among heterogeneous wireless devices without the need of encryption. Previous works have... 相似文献
A facile one-step approach to synthesize various phase-separated porous, raspberry-like, flower-like, core–shell and anomalous nanoparticles and nanocapsules via 1,1-diphenylethene (DPE) controlled soap-free emulsion copolymerization of styrene (S) with glycidyl methacrylate (GMA), or acrylic acid (AA) is reported. By regulating the mass ratio of S/GMA, transparent polymer solution, porous and anomalous P(S-GMA) particles could be produced. The P(S-GMA) particles turn from flower-like to raspberry-like and then to anomalous structures with smooth surface as the increase of divinylbenzene (DVB) crosslinker. Transparent polymer solution, nanocapsules and core–shell P(S-AA) particles could be obtained by altering the mole ratio of S/AA; anomalous and raspberry-like P(S-AA) particles are produced by adding DVB. The unpolymerized S resulted from the low monomer conversion in the presence of DPE aggregates to form nano-sized droplets, and migrates towards the external surfaces of the GMA-enriched P(S-GMA) particles and the internal bulk of the AA-enriched P(S-AA) particles. The nano-sized droplets function as in situ porogen, porous P(S-GMA) particles and P(S-AA) nanocapsules are produced when the porogen is removed. This novel, facile, one-step method with excellent controllability and reproducibility will inspire new strategies for creating hierarchical phase-separated polymeric particles with various structures by simply altering the species and ratio of comonomers. The drug loading and release experiments on the porous particles and nanocapsules demonstrate that the release of doxorubicin hydrochloride is very slow in weakly basic environment and quick in weakly acidic environment, which enables the porous particles and nanocapsules with promising potential in drug delivery applications.
Tensile properties and failure mechanism of a newly developed three-dimensional (3D) woven composite material named 3D nonorthogonal woven composite are investigated in this paper. The microstructure of the composite is studied and the tensile properties are obtained by quasi-static tensile tests. The failure mechanism of specimen is discussed based on observation of the fracture surfaces via electron microscope. It is found that the specimens always split along the oblique yarns and produce typical v-shaped fracture surfaces. The representative volume cell (RVC) is established based on the microstructure. A finite element analysis is conducted with periodical boundary conditions. The finite element simulation results agree well with the experimental data. By analyzing deformation and stress distribution under different loading conditions, it is demonstrated that finite element model based on RVC is valid in predicting tensile properties of 3D nonorthogonal woven composites. Stress distribution shows that the oblique yarns and warp yarns oriented along the x direction carry primary load under x tension and that warp yarns bear primary load under y tension. 相似文献
High quality single crystals of YBa2Cu3O7- (YBCO) have been grown in yttria-stabilized zirconia crucibles by using a flux method. This method yields crystals with area 3 to 4 times larger than a previous method, and 3 to 5 times more crystals. Several crystals as large as 3×4mm2 in thea-b plane are routinely obtained from each crucible. The samples typically range from 10 to 60 m thick. The superconductivity transition temperatureTc of the crystals, measured by magnetic susceptibility, falls in the range 92.5 to 93 K and the smallest transition width (10 to 90%) is less than 0.25 K. Compared with the previous method, the surface is generally smoother, with less flux, and larger untwinned regions of 1 x 1 mm2 are usually found. 相似文献
Multimedia Tools and Applications - Recently, with the widespread popularity of SNS (Social Network Service), such as Twitter, Facebook, people are increasingly accustomed to sharing feeling,... 相似文献