The influence of a corrosive wood-cutting environment on the mechanical properties of hardmetal tools

The influence of a corrosive wood-cutting environment on the strength of hardmetals and on their behaviour under static loading conditions has been investigated. Two commercial hardmetals were tested, which differed in hard phase composition. The results show exposure to this environment to have a highly detrimental influence on the strength of both hardmetals investigated, due to localised corrosive attack which results in the formation of stress raisers. The relative loss in strength as a function of corrosion time is the same for both hardmetals. However, the performance of the two grades differ significantly when a static load is applied in this corrosive environment: the strength of the WC-Co grade remains unaffected by the applied load, while the grade containing a mixed carbide phase exhibits stress corrosion cracking which results in a further reduction in strength.     

Conversion of carbon into CF4 for SI-traceable measurements of absolute carbon isotope amount ratios: a feasibility study

The feasibility of performing SI-traceable carbon isotope amount ratio measurements following conversion of carbon into CF4 was studied. A procedure for the direct fluorination of carbon with elemental fluorine was developed, and the conversion step was checked for losses, blank contributions, and the absence of systematic isotope effects. Gas chromatography was used to identify and quantify the gaseous fluorination products and to isolate CF4 from byproducts. After fluorination of graphite carbon, CF4 and perfluoroalkanes with up to six carbon atoms were observed as reaction products. Within an uncertainty of 10%, the graphite carbon was fully recovered in the gaseous carbon fluorides, with the main product being CF4 (80-90%) and C2F6 as the major byproduct. The fluorination and GC procedures were found to introduce an alteration not bigger than 0.03 +/- 0.04/1000 on the isotopic composition of CF4. Carbon blank contributions introduced during the fluorination procedure were below 0.5% relative to a typical sample of 4 mg of carbon. For two of the materials investigated, the carbon isotope ratios measured on a differential mass spectrometer were reproducible within a standard deviation of approximately 0.1/1000 for several individual fluorinations. For these materials, the developed fluorination procedure is a straightforward process, which can be used as a foundation to establish SI-traceable measurements of carbon isotope amount ratios. However, for the third graphite material the formation of byproducts (C2F6-C6F14) was found to induce significant isotopic fractionation.     

The flip-chip approach for millimeter wave packaging

A particularly critical issue in this regard is module packaging, i.e., the way to assemble and connect several monolithic microwave integrated circuits (MMICs) in a multichip environment in order to build the millimeter-wave front-end. The requirements on the packaging scheme are obvious: the interconnects should provide good millimeter-wave performance (primarily meaning: low reflections and low insertion loss) and, at the same time, they should allow for low-cost fabrication. Among the multichip packaging techniques available, the flip-chip approach is considered to be the most promising candidate to meet these requirements.     

Nitsche Type Mortaring for some Elliptic Problem with Corner Singularities

The paper deals with Nitsche type mortaring as a finite element method (FEM) for treating non-matching meshes of triangles at the interface of some domain decomposition. The approach is applied to the Poisson equation with Dirichlet boundary conditions (as a model problem) under the aspect that the interface passes re-entrant corners of the domain. For such problems and non-matching meshes with and without local refinement near the re-entrant corner, some properties of the finite element scheme and error estimates are proved. They show that appropriate mesh grading yields convergence rates as known for the classical FEM in presence of regular solutions. Finally, a numerical example illustrates the approach and the theoretical results. Received July 5, 2001; revised February 5, 2002 Published online April 25, 2002     

Numerical simulation of partial discharge propagation in cable joints using the finite difference time domain method

In this second of a series of three papers, the authors investigate partial discharge (PD) detection and propagation in cable joints. The complex nature of cable joints leads to errors when PD analysis is carried out using conventional equivalent circuits. The authors use the finite difference time domain method to determine the transient electromagnetic fields caused by simulated PD in model cable joints.     

Cellulose dyeing parameters of 18 isomeric phenylazo-H-acid dyes containing two different reactive groups

Eighteen isomeric dyes, each based on phenylazo-H-acid and containing two reactive groups, namely a monochlorotriazine group and a sulphuric acid ester of ß-hydroxyethylsulphone, were applied to cotton fabric by an exhaustion process at 60d?C. The following properties were studied: spectra, uptake curves of the dyes before and after adding sodium carbonate, affinity, diffusion rate, and rates of hydrolysis and of reaction with cellulose, as evidenced by fixation and colour yield. Some significant correlations were found, but some missing or poor correlations indicated that there are further parameters or relationships between parameters that remain to be elucidated.     

A framework for application systems engineering

Interactive Application Systems (IAS) attend to the information needs of application experts, i.e. problem-solving end-users within particular application environments. As such, IAS must be customized functionally and behaviourally toward both user and environment. Such customizing must be feasible in an economical fashion. The study claims that this objective is met by appropriate IAS development tools and by a basic IAS architecture that consists of the following main building blocks: a general-purpose dialogue processor that is controlled by a particular user interface specification, called information net; a library of software modules and packages for providing system functions on the basis of reusable software; and a data management system that may, just like the library elements, be procured from outside, perhaps even including an already existing information base. The paper discusses the approach in detail with particular emphasis on information nets and on the integration of reusable software into a total system. The paper argues that the approach is flexible enough to accommodate (rapid) prototyping, i.e. procuring of first versions of an IAS, that may be used during requirements analysis to refine the user wishes, or operationally during an interim period until the final system becomes available.