Discrimination between natural and HPHT-treated type IIa diamonds using photoluminescence spectroscopy

We have performed low-temperature (8 K) photoluminescence (PL) measurements on 71 natural and 12 high-pressure-and-high-temperature (HPHT)-treated type IIa diamonds. The GR1, NV⁰, NV^?, H4, and H3 defect center PL signals are compared. Some distinct differences in the PL lineshape, intensity, and appearance of side-band PL signals are observed. Furthermore, we processed 6 of the natural diamond samples with the HPHT treatment to investigate the effect of the treatment on the PL spectrum. By systematically analyzing the differences in the PL spectra, we developed a scheme to discriminate natural and HPHT-treated diamonds with 99% validity.     

Electrospun PEDOT:PSS/PVP nanofibers as the chemiresistor in chemical vapour sensing

Herein, PEDOT:PSS/PVP nanofibers were produced by electrospinning. The presence of PEDOT:PSS in the nanofibers was confirmed by FT-Raman spectroscopy. The applied voltage-dependent diameter of PEDOT:PSS/PVP nanofibers was observed. Also, sensing behaviors of electrospun PEDOT:PSS/PVP nanofibers were explored by measuring its response upon cyclic exposure to organic vapours such as ethanol, methanol, THF, and acetone at room temperature. When PEDOT:PSS/PVP nanofibers were exposed to each solvent, the protic and aprotic solvents resulted in opposite electrical responses. These findings exhibit that electrospun PEDOT:PSS/PVP nanofibers are the promising candidate for the organic vapour sensing material.     

Preparation and Thermoelectric Properties of p-Type Yb-Filled Skutterudites

p-Type Yb _z Fe_4?x Co _x Sb₁₂ skutterudites were prepared by encapsulated melting and hot pressing, and the filling and doping (charge compensation) effects on the transport and thermoelectric properties were examined. The electrical conductivity of all specimens decreased slightly with increasing temperature, indicating that they were in a degenerate state due to high carrier concentrations of 10²⁰ cm^?3 to 10²¹ cm^?3. The Hall and Seebeck coefficients exhibited positive signs, indicating that the majority carriers are holes (p-type). The Seebeck coefficient increased with increasing temperature to maximum values of 100 μV/K to 150 μV/K at 823 K. The electrical and thermal conductivities were reduced by substitution of Co for Fe, which was responsible for the decreased carrier concentration. Overall, the Yb-filled Fe-rich skutterudites showed better thermoelectric performance than the Yb-filled Co-rich skutterudites.     

Alignment of Fluid Molecules in an EHD Contact

Dichroic infrared emission spectra have been obtained from an operating elastohydrodynamic contact under conditions showing unequivocally that the molecules of the fluid are aligned under shear flow in the bulk of the fluid and that the extent of the alignment is increased by the presence of an additive in a small concentration. This work applied particularly to polyphenyl ether and to 1,1,2-trichloroethane as the additive, but similar results have been obtained with polycyclohexyls and the same additive. The observation of two separate glass transition for the polycyclohexyl solution is an indication of the occurrence of a phase separation in the Hertzian inlet zone. A model has been developed to explain the effect of these phenomena and their relation to traction.     

Crystalloids vs. colloids in fluid resuscitation: a systematic review

OBJECTIVE: To systematically review the effects of isotonic crystalloids compared with colloids in fluid resuscitation. DATA SOURCES: Computerized bibliographic search of published research and citation review of relevant articles. STUDY SELECTION: All randomized clinical trials of adult patients requiring fluid resuscitation comparing isotonic crystalloids vs. colloids were included. Pulmonary edema, mortality, and length of stay were evaluated. Independent review of 105 articles identified 17 relevant primary studies of 814 patients. Weighted c about article inclusion was high (0.76). DATA EXTRACTION: Data on population, interventions, outcomes, and methodologic quality of the studies were obtained by duplicate independent review with differences resolved by consensus. Weighted ic on the validity assessment was moderate (0.54). DATA SYNTHESIS: No difference was observed overall between crystalloid and colloid resuscitation with respect to mortality and pulmonary edema; however, the power of the aggregated data was insufficient to detect small but potentially clinically important differences. Subgroup analysis suggested a statistically significant difference in mortality in trauma in favor of crystalloid resuscitation (relative risk 0.39, 95% confidence intervals: 0.17 to 0.89). Several methodologic issues are noteworthy regarding the primary studies, including lack of blinding (except in three studies). The type, dose, and duration of fluid administration and outcomes measured were different across these trials. CONCLUSIONS: Overall, there is no apparent difference in pulmonary edema, mortality, or length of stay between isotonic crystalloid and colloid resuscitation. Crystalloid resuscitation is associated with a lower mortality in trauma patients. Methodologic limitations preclude any evidence-based clinical recommendations. Larger well-designed randomized trials are needed to achieve sufficient power to detect potentially small differences in treatment effects if they truly exist.     

A model on desulfurization characteristics of an entrained bed-bubbling bed hot gas cleanup system for IGCC

A mathematical model has been developed to predict performance of a continuous entrained-bed and bubbling fluidized-bed hot gas desulfurization system in IGCC. The model combines the particle residence time with the kinetic rate in each reactor. The model has been applied to the KIER’s laboratory scale fluidized bed process. The present model provided a reasonable fit in predicting experimental results that the outlet concentration of H₂S from the desulfurizer and SO₂ from the regenerator increased nearly proportionally to the inlet concentration of H₂S to the desulfurizer. The model also could predict well the outlet concentration of O₂ from the regenerator to decrease as the inlet concentration of H₂S to the desulfurizer increased. The present model predicted with reasonable accuracy mean diameter of bed particles and sulfur content of particles in desulfurizer and regenerator.     

Age estimation using a hierarchical classifier based on global and local facial features

The research related to age estimation using face images has become increasingly important, due to the fact it has a variety of potentially useful applications. An age estimation system is generally composed of aging feature extraction and feature classification; both of which are important in order to improve the performance. For the aging feature extraction, the hybrid features, which are a combination of global and local features, have received a great deal of attention, because this method can compensate for defects found in individual global and local features. As for feature classification, the hierarchical classifier, which is composed of an age group classification (e.g. the class of less than 20 years old, the class of 20-39 years old, etc.) and a detailed age estimation (e.g. 17, 23 years old, etc.), provide a much better performance than other methods. However, both the hybrid features and hierarchical classifier methods have only been studied independently and no research combining them has yet been conducted in the previous works. Consequently, we propose a new age estimation method using a hierarchical classifier method based on both global and local facial features. Our research is novel in the following three ways, compared to the previous works. Firstly, age estimation accuracy is greatly improved through a combination of the proposed hybrid features and the hierarchical classifier. Secondly, new local feature extraction methods are proposed in order to improve the performance of the hybrid features. The wrinkle feature is extracted using a set of region specific Gabor filters, each of which is designed based on the regional direction of the wrinkles, and the skin feature is extracted using a local binary pattern (LBP), capable of extracting the detailed textures of skin. Thirdly, the improved hierarchical classifier is based on a support vector machine (SVM) and a support vector regression (SVR). To reduce the error propagation of the hierarchical classifier, each age group classifier is designed so that the age range to be estimated is overlapped by consideration of false acceptance error (FAE) and false rejection error (FRE) of each classifier. The experimental results showed that the performance of the proposed method was superior to that of the previous methods when using the BERC, PAL and FG-Net aging databases.     

Causes of reduction in shield TBM performance - A case study in Seoul

This study investigates the fundamental reasons of reduction for excavation performance on shield TBM in the Han River riverbed tunnel by means of analysis of field measurement data. For the study: (1) measurement data were analyzed by both the thrust and penetration rate data in a given section with rock types and direction types, (2) a number of disk cutter consumption and types of abrasion were analyzed, (3) an exhaust ratio of screw conveyor and design problem of screw conveyor were analyzed by earth mud which becomes the rock powder. As a result of this study, it was found that the lack of penetration depth caused by lower thrust, disk changes according to rapidly changing rock types, and installed angle of screw conveyor, play an important role in the excavation performance.     

Analysis of the HVAC system’s sound quality using the design of experiments

Human hearing is very sensitive to sound, so a subjective index of sound quality is required. Each situation of sound evaluation is composed of Sound Quality (SQ) metrics. When substituting the level of one frequency band, we could not see the tendency of substitution at the whole frequency band during SQ evaluation. In this study, the Design of Experiments (DOE) is used to analyze noise from an automotive Heating, Ventilating, and Air Conditioning (HVAC) system. The frequency domain is divided into 12 equal parts, and each level of the domain is given an increase or decrease due to the change in frequency band based on the “loud” and “sharp” sound of the SQ analyzed. By using DOE, the number of tests is effectively reduced by the number of experiments, and the main result is a solution at each band. SQ in terms of the “loud” and “sharp” sound at each band, the change in band (increase or decrease in sound pressure) or no change in band will have the most effect on the identifiable characteristics of SQ. This will enable us to select the objective frequency band. Through the results obtained, the physical level changes in arbitrary frequency domain sensitivity can be determined.     

Exposure assessment of engineered nanomaterials in the workplace

Nanotechnology is a rapidly growing field and numerous products containing engineered nanomaterials are already in the market. With the increasing use of engineered nanomaterials, it is expected to increase the exposures to nanomaterials in the workplace. However, the researches on the exposure assessment of nanomaterials to humans and the environment are just a beginning step, as the nanotechnology industries are expanding. Questionnaire surveys conducted by various organizations reveal that many nanotechnology companies are searching for information on exposure measurement for the protection of workers who handle nanomaterials. We analyze the trends of researches on the occupational exposure measurement of engineered nanomaterials and investigate the methodologies of exposure assessment recommended by the related working groups. This work is expected to fill the gaps in knowledge on the exposure assessment of nanomaterials.