Removal of manganese from water using combined chelation/membrane separation systems.

The addition of the chelating polymer polyacrylic acid (PAA) to assist in the removal of manganese from groundwater by membranes was investigated using membranes with different pore sizes under various operating conditions. Negligible manganese removal was achieved with the UF and NF membranes at acidic pH values, but removals exceeding 90% could be achieved at elevated pH (pH 9), presumably due to the formation of manganese hydroxides. Mn removal increased substantially when PAA was added to the feed solution, due to chelation of Mn by the PAA and rejection of the chelates by the membranes. The chelate could be broken at acidic pH, releasing free PAA that could then be separated from the Mn ions and reused. Smaller PAA molecules were lost in the first regeneration cycle, but negligible PAA was lost in subsequent cycles. In the systems with PAA, nitrate ions were rejected more efficiently than in the PAA-free systems, presumably because of electrical repulsion between nitrate ions and PAA sorbed on the membrane surface. With increasing PAA dose, the volumetric flux first decreased and then increased; the latter result was accompanied by a change in the physical-chemical form of the polymers, as indicated by an increase in turbidity.     

Design tradeoff analysis of floating-point adders in FPGAs

With gate counts of ten million, field-programmable gate arrays (FPGAs) are becoming suitable for floating-point computations. Addition is the most complex operation in a floating-point unit and can cause major delay while requiring a significant area. Over the years, the VLSI community has developed many floating-point adder algorithms aimed primarily at reducing the overall latency. An efficient design of the floating-point adder offers major area and performance improvements for FPGAs. Given recent advances in FPGA architecture and area density, latency has become the main focus in attempts to improve performance. This paper studies the implementation of standard; leading-one predictor (LOP); and far and close datapath (2-path) floating-point addition algorithms in FPGAs. Each algorithm has complex sub-operations which contribute significantly to the overall latency of the design. Each of the sub-operations is researched for different implementations and is then synthesized onto a Xilinx Virtex-II Pro FPGA device. Standard and LOP algorithms are also pipelined into five stages and compared with the Xilinx IP. According to the results, the standard algorithm is the best implementation with respect to area, but has a large overall latency of 27.059 ns while occupying 541 slices. The LOP algorithm reduces latency by 6.5% at the cost of a 38% increase in area compared to the standard algorithm. The 2-path implementation shows a 19% reduction in latency with an added expense of 88% in area compared to the standard algorithm. The five-stage standard pipeline implementation shows a 6.4% improvement in clock speed compared to the Xilinx IP with a 23% smaller area requirement. The five-stage pipelined LOP implementation shows a 22% improvement in clock speed compared to the Xilinx IP at a cost of 15% more area.     

A new generic multistep power control algorithm for the LEOsatellite channel with high dynamics

LEO satellite CDMA systems, characterized by round-trip delay and high variation in slow fading, call for different considerations on power control algorithms. Based on the criteria of fast response, small over-compensation, oscillation-avoiding and minimum power control error, the transient behavior of the fixed step, adaptive step, and multistep power control algorithms are investigated and compared. A new generic multistep power control algorithm with excellent dynamic performance is proposed for LEO satellite systems     

Effect of inter-ionic interaction on photoluminescence property of yttrium aluminate garnet phosphors

The photoluminescence of Terbium-activated yttrium aluminate with the general formula Y_3-xTb_XAl₅O₁₂was investigated as a function of Tb³⁺concentration. The main attention is focused on the ⁵D₃/⁵D₄fluorescence and its energy transfer behavior. The emission and excitation spectra were measured in terms of Tb³⁺concentration and analyzed in view of the application for plasma display panel (PDP). Also, the diffuse reflectance spectra were measured and analyzed in the range from VUV to UV. As a result, the yttrium aluminate was found to have a broad excitation band extending from VUV to UV range and to show the typical concentration quenching behaviors both for ⁵D₃and ⁵D₄fluorescence. The energy transfer was investigated by analyzing the decay curve of ⁵D₃and ⁵D₄emission based on the multipolar interaction or the exchange interaction. The decay curves of ⁵D₃emission, for which well known cross relaxation has been accepted as a main factor, were analyzed by Inokuti and Hirayama's formula based on the direct quenching scheme. The decay curves of ⁵D₄emission were analyzed by Yokota and Tanimoto's formula based on the diffusion limited quenching scheme.     

Impact of the location area structure on the performance ofsignaling channels in wireless cellular networks

The authors consider connection-oriented wireless cellular networks such as IS-54, IS-95, GSM, and wireless ATM networks. These are connection-oriented digital networks which employ separate radio channels for the transmission of signaling information. A forward signaling channel is a common signaling channel assigned to carry the multiplexed stream of paging and channel-allocation packets from a base station to mobile stations. For wireless ATM networks, paging and virtual-circuit (VC) allocation packets are multiplexed across the forward signaling channels as part of the VC setup phase. A reverse signaling channel, which employs a contention-oriented medium access algorithm, is used by mobile stations to send channel-request and location-update packets. A location area is a region which includes a specified set of adjacent cells; it is used to track the location of mobile stations. Mobile units must reregister as they cross the boundary of a location area. The channel setup and paging response times are critical performance factors in the design of the signaling subsystem. A location area structure must be suitably selected to ensure that acceptable levels of such performance functions are achieved. A network which employs small location-areas will experience a high rate of location updates, while larger location areas lead to higher traffic intensities of paging messages. The authors overview a method for calculating the performance behavior of signaling messages. Subsequently the impact of the location area structure on the performance of the signaling system is investigated     

High-resolution crystal structures of delta5-3-ketosteroid isomerase with and without a reaction intermediate analogue

Bacterial Delta5-3-ketosteroid isomerase (KSI) catalyzes a stereospecific isomerization of steroid substrates at an extremely fast rate, overcoming a large disparity of pKa values between a catalytic residue and its target. The crystal structures of KSI from Pseudomonas putida and of the enzyme in complex with equilenin, an analogue of the reaction intermediate, have been determined at 1.9 and 2.5 A resolution, respectively. The structures reveal that the side chains of Tyr14 and Asp99 (a newly identified catalytic residue) form hydrogen bonds directly with the oxyanion of the bound inhibitor in a completely apolar milieu of the active site. No water molecule is found at the active site, and the access of bulk solvent is blocked by a layer of apolar residues. Asp99 is surrounded by six apolar residues, and consequently, its pKa appears to be elevated as high as 9.5 to be consistent with early studies. No interaction was found between the bound inhibitor and the residue 101 (phenylalanine in Pseudomonas testosteroni and methionine in P. putida KSI) which was suggested to contribute significantly to the rate enhancement based on mutational analysis. This observation excludes the residue 101 as a potential catalytic residue and requires that the rate enhancement should be explained solely by Tyr14 and Asp99. Kinetic analyses of Y14F and D99L mutant enzymes demonstrate that Tyr14 contributes much more significantly to the rate enhancement than Asp99. Previous studies and the structural analysis strongly suggest that the low-barrier hydrogen bond of Tyr14 (>7.1 kcal/mol), along with a moderate strength hydrogen bond of Asp99 ( approximately 4 kcal/mol), accounts for the required energy of 11 kcal/mol for the transition-state stabilization.     

Fabrication of amorphous silicon p-i-n solar cells using ion shower doping technique

We have studied the fabrication of amorphous silicon (a-Si : H) p-i-n solar cells using an ion shower doped n⁺-layer. The p-i-n cells with ion-doped n⁺-layer exhibited open-circuit voltage of > 0.8 V, fill factor of > 0.62 and conversion efficiency of > 8.4% when the ion acceleration voltage was between 3 and 7 kV. The a-Si : H p-i-n solar cell fabricated under an optimized ion-doping condition exhibited an open-circuit voltage of 0.84 V, a fill factor of 0.66 and a conversion efficiency of 9.9% which was very similar to those of conventional a-Si : H p-i-n cells fabricated in the same deposition chamber. Therefore, ion shower doping technique can be applied to fabricate large area, high performance a-Si : H p-i-n solar cells.     

Effect of Ni loading and calcination temperature on catalyst performance and catalyst deactivation of Ni/SiO2 in the hydrodechlorination of 1,2‐dichloropropane into propylene

The hydrodechlorination of 1,2‐dichloropropane (DCPA), a chlorinated organic waste which is produced in the epichlorohydrin process, to propylene was carried out over Ni/SiO₂ catalysts. The effects of Ni loading and calcination temperature on catalyst performance and catalyst deactivation of Ni/SiO₂ were systematically investigated. The Ni/SiO₂ catalysts efficiently converted DCPA into propylene in 95% selectivity or higher. The particle size of Ni on SiO₂ was strongly related to the catalyst stability. In terms of the effect of Ni loading, the largest Ni particles on SiO₂ showed the best durability against deactivation. A series of TPR and UV‐DRS measurements revealed that nickel hydrosilicate was formed as the result of the interaction between Ni and SiO₂. Nickel hydrosilicate was found to be responsible for the catalyst stability leading to low catalyst deactivation. HCl adsorption on Ni/SiO₂ was the main reason for catalyst deactivation. HCl modified the crystal structure of metallic Ni to NiCl₂ and led to irreversible deactivation and metal sintering. This revised version was published online in July 2006 with corrections to the Cover Date.