Mechanism of superconductivity in the polyhedral-network compound Ba8Si46

The silicon clathrates--materials composed of metal-doped Si(20) dodecahedra--were identified as the first superconductors based on pure silicon networks. The mechanism of superconductivity in these materials can be obtained by studying their phonon modes, as modified by isotope substitution, and specific-heat measurements. Here, we present experimental studies that provide strong evidence that superconductivity in Ba(8)Si(46) is explained in the framework of phonon-mediated Bardeen-Cooper-Schriefer theory. Analyses using the McMillan approximation of the Eliashberg equation indicate that the superconducting mechanism is in the medium coupling regime, but at the high-end limit. The large density of states at the Fermi level, which arises from hybridization of the Si(20) cluster and Ba orbitals, is responsible for the unexpectedly high superconducting temperature. The temperature evolution of the specific heat unambiguously shows that this is an s-wave symmetry superconductor.     

Observations of vibration shape of AT-cut quartz resonator including electric twins

Quartz crystal resonators, including electric twins, are investigated. Electric twins are artificially formed in the usual AT-cut quartz crystal resonantor before the deposition of electrodes. We have directly observed that vibrations generated at electrodes propagate into the outside region isotropically, but cannot propagate into the region of electric twin.     

Fine silicon carbide fibers synthesized from polycarbosilane-polyvinylsilane polymer blend using electron beam curing

A fine SiC fiber is synthesized from a polymer blend of polycarbosilane (PCS) and polyvinylsilane (PVS) with electron beam curing under vacuum. The obtained SiC fiber from the PCS-PVS blend polymer has smaller average diameter of 8.5 m than that of 11.8 m from PCS, and shows higher average tensile strength of 3.2 GPa than that of 2.8 GPa from PCS after heat treatment at 1673 K in Ar gas atmosphere. However, the SiC fiber from the polymer blend decreases in tensile strength after heat treatment above 1773 K due to -SiC crystal growth near the fiber surface, because of a small amount of oxygen incorporated in the fiber.     

Disintegration process of yttria-stabilized zirconia ceramics using hydrothermal conditions

Capability of the recycling of high strength and high fracture toughness yttria-stabilized tetragonal zirconia polycrystalline (Y-TZP) sintered body utilizing “low-temperature annealing degradation” phenomenon was investigated. Hydrothermal treatment was employed to induce the phase transformation from tetragonal to monoclinic zirconia and to disintegrate the Y-TZP sintered body. 3 mol% Y₂O₃–ZrO₂ specimens sintered at 1,550 °C and more were disintegrated without leaving the original appearances when the treatment temperature was between 200 °C and 400 °C. The size of the disintegrated fragments of Y-TZP sintered body was much affected by hydrothermal treatment conditions. Only with hydrothermal treatment and simple ball milling, the sintered body was pulverized into the primary particle level. This technique is expected to apply to a sustainable recycling system for the zirconia ceramics, which restrains an energy consumption compared to crushing zirconia using mechanical procedures.     

An Improvement Method of Matrix Converter Drives Under Input Voltage Disturbances

While the matrix converter has many advantages that include bidirectional power flow, a size reduction, a long lifetime, and sinusoidal input currents, it is vulnerable to the input voltage disturbances, because it directly exchanges the input voltage to the output voltage. The instantaneous effective power control (IEPC) method has been proposed to compensate the input voltage disturbances, in which the instantaneous effective power is kept constant by controlling input current. However, to date, no method has been proposed to maintain the stability of the system with the IEPC. The purpose of this paper is to propose a method to control the stability of the system with IEPC. First, this paper explains the IEPC theoretically. Next, a model of the system with the IEPC is developed, and stability analyses are conducted. Then, based on the results of the analyses, a stability control method for the system with the IEPC is proposed. Furthermore, the validities of the proposed method are demonstrated by simulation and experiments. Finally, a restart performance of the system after momentary power interruption is discussed. Because the IEPC does not need phase-locked-loop to detect the phase angle of the input voltage, fast restart is expected     

Low-Force Electric Contact Processes on Cu Electrodes

A contact process between large-scale integration (LSI) pads and test probes at low contact force is a key to developing a probe card with smaller pitch and higher pin count. In this paper, we report on the characteristics of low-force contact methods on Cu electrodes. One is the fritting process, in which an electric breakdown is utilized to break the surface oxide, and the other is the heating treatment in hydrogen gas aimed at deoxidizing the surface Cu oxide. Conventional tungsten needle probes were used as testing probes, and contact resistances at low contact force of 1-5 mN were measured. Contact resistances smaller than 1 Omega were obtained by the fritting processes, in which the voltage and the current were 10 V and 280-320 mA, respectively. A deoxidization process at over 260degC was found to be effective for decreasing the contact resistance. The X-ray photoelectron spectroscopy (XPS) was utilized to investigate the surface state of hydrogen-treated Cu, and the deoxidization of Cu₂O to Cu was observed in samples treated at 260degC, while no change was found in that at 150degC.     

Numerical analysis method for the RC and geological structures subjected to extreme loading by energetic materials

This paper proposes and demonstrates a numerical simulation method suitable to analyze the local damage and dynamic response of the structures composed of the reinforced concrete (RC) and/or the geological materials subjected to extremely severe loading by the energetic material like high explosives (HE).     

Design principle of micromechanical probe with an electrostatic actuator for friction force microscopy

It is important to understand friction force in micro/nano mechanical devices both at high sliding speed and with high lateral resolution. Dual-axis friction force microscopes that can provide high lateral resolution and accuracy have been proposed; however, the sliding speed is limited by the probe scan speed. While a micro mechanical probe (MMP) with an electrostatic actuator can overcome this problem, details of probe design have not been established yet. This paper presents the principle of the mechanical design for an MMP with high force sensitivity and sufficient drive force. The dimensions of the double cantilever beam control the spring constants, resonant frequencies, and drive force. The use of an actuated MMP enables accurate friction force microscopy at high sliding speeds, which is required for the design of micro/nano mechanical devices.     

Investigation of Ozone Loss Rate Influenced by the Surface Material of a Discharge Chamber

Decay characteristics of ozone concentration in oxygen in a chamber with three types of wall material (stainless steel, copper, and aluminum) are measured using the 254 nm photoabsorption method. Effective lifetimes of ozone are estimated from decay curves of ozone concentration. These values depend on the wall material: They are largest for stainless steel and smallest for aluminum. The relationship between effective lifetime and gas pressure is investigated precisely to determine three values. The equivalent diffusion coefficient of ozone in oxygen and the reflection coefficient of ozone at the wall correspond to the loss rate of ozone at the wall. The collisional loss (quenching) rate coefficient of ozone in oxygen is also determined.