工业控制计算机在轮胎硫化过程控制中的设计应用

立式硫化罐在轮胎生产企业使用比较广泛,手动操作和人为控制很难保证生产工艺和产品质量,保证轮胎质量必须采用比较好的控制系统达到目的,采用工业控制计算机进行轮胎硫化过程控制可以达到硫化三要素的正确控制,从而保证产品质量,降低劳动强度,提高生产效率.     

Ternary MOF‑Based Redox Active Sites Enabled 3D‑on‑2D Nanoarchitectured Battery‑Type Electrodes for High‑Energy‑Density Supercapatteries

Designing rationally combined metal-organic frameworks(MOFs)with multifunctional nanogeometries is of significant research interest to enable the electrochemical properties in advanced energy storage devices.Herein,we explored a new class of binderfree dual-layered Ni-Co-Mn-based MOFs(NCM-based MOFs)with three-dimensional(3D)-on-2D nanoarchitectures through a polarityinduced solution-phase method for high-performance supercapatteries.The hierarchical NCM-based MOFs having grown on nickel foam exhibit a battery-type charge storage mechanism with superior areal capacity(1311.4μAh cm^−2 at 5 mA cm^−2),good rate capability(61.8%;811.67μAh cm^−2 at 50 mA cm^−2),and an excellent cycling durability.The superior charge storage properties are ascribed to the synergistic features,higher accessible active sites of dual-layered nanogeometries,and exalted redox chemistry of multi metallic guest species,respectively.The bilayered NCM-based MOFs are further employed as a battery-type electrode for the fabrication of supercapattery paradigm with biomass-derived nitrogen/oxygen doped porous carbon as a negative electrode,which demonstrates excellent capacity of 1.6 mAh cm^−2 along with high energy and power densities of 1.21 mWh cm^−2 and 32.49 mW cm^−2,respectively.Following,the MOF-based supercapattery was further assembled with a renewable solar power harvester to use as a self-charging station for various portable electronic applications.     

Magnetic particles for sugar separation from sulphuric acid solution generated during nano‐crystalline cellulose production

Nano‐crystalline cellulose (NCC) is a renewable material having different applications ranging from drug delivery to a reinforcing filling agent in polymer synthesis. Concentrated sulphuric acid is used to hydrolyze cellulosic biomass to obtain NCC. Manufacturers are keen to reuse the diluted acid solution left after the process. However, the presence of mono and oligosaccharides makes it unsuitable for repeated use. About 99 % of these compounds have been successfully separated from the acid solution by employing NaOH‐treated magnetic particles developed during this investigation. It has been observed that by NaOH treatment, zeta potential of the magnetic particles could be increased from +11 mV to +37.5 mV; correspondingly, sugar removal efficiency was increased from 23.04 % to more than 99 %. Thus a direct correlation between the change in zeta potential of the particles and sugar separation efficiency has been observed.     

Crystallization and melting behavior of HDPE in HDPE/teak wood flour composites and their correlation with mechanical properties

The nonisothermal crystallization behavior and melting characteristics of high‐density polyethylene (HDPE) in HDPE/teak wood flour (TWF) composites have been studied by differential scanning calorimetry (DSC) and wide angle X‐ray diffraction (WAXD) methods. Composite formulations of HDPE/TWF were prepared by varying the volume fraction (?_f) of TWF (filler) from 0 to 0.32. Various crystallization parameters evaluated from the DSC exotherms were used to study the nonisothermal crystallization behavior. The melting temperature (T_m) and crystallization temperature (T_p) of the composites were slightly higher than those of the neat HDPE. The enthalpy of melting and crystallization (%) decrease with increase in the filler content. Because the nonpolar polymer HDPE and polar TWF are incompatible, to enhance the phase interaction maleic anhydride grafted HDPE (HDPE‐g‐MAH) was used as a coupling agent. A shift in the crystallization and melting peak temperatures toward the higher temperature side and broadening of the crystallization peak (increased crystallite size distribution) were observed whereas crystallinity of HDPE declines with increase in ?_f in both DSC and WAXD. Linear correlations were obtained between crystallization parameters and tensile and impact strength. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Self regulation of photovoltaic module temperature in V-trough using a metal-wax composite phase change matrix

The present study was carried out to take advantage of the enhanced solar insolation in V-trough while limiting the temperature of the photovoltaic (PV) module at around the maximum (ca. 65 °C) observed for conventional usage without any concentration. Paraffin wax of 56-58 °C melting range was chosen as phase change material (PCM) and incorporated at the rear of the module to absorb the excess heat. The problem of low thermal conductivity of the wax was solved with the help of packed metal turnings wherein the wax resided. Two sets of experiments were performed indoor and outdoor. Employing a 0.06 m thick bed of the PCM matrix, the module temperature in the indoor experiment could be maintained at 65-68 °C for 3 h whereas in its absence the temperature rose beyond 90 °C within 15 min. In outdoor studies, the module temperature in V-trough could be reduced from 78 °C to 62 °C with the PCM assembly and operation could be sustained throughout the day. Using the V-trough PV-PCM system, the output power over the day could be enhanced 1.55 times with self regulation of temperature. The molten wax formed during operation re-solidified during the evening and night and could be re-used. A significant finding was the safe operation of the module even under low wind velocity conditions without sacrificing operational simplicity.     

Electrical Conduction in Nano-Structured La0.9Sr0.1Al0.85Co0.05Mg0.1O3 Perovskite Oxide

Nanocrystalline La_0.9Sr_0.1Al_0.85Co_0.05Mg_0.1O₃ oxide powder was synthesized by a citrate–nitrate auto-ignition process and characterized by thermal analysis, X-ray diffraction, and impedance spectroscopy measurements. Nanocrystalline (50–100 nm) powder with perovskite structure could be produced at 900°C by this process. The powder could be sintered to a density more than 96% of the theoretical density at 1550°C. Impedance measurements on the sintered samples unequivocally established the potential of this process in developing nanostructured lanthanum aluminate-based oxides. The sintered La_0.9Sr_0.1Al_0.85Co_0.05Mg_0.1O₃ sample exhibited a conductivity of 2.40 × 10⁻² S/cm in air at 1000°C compared with 4.9 × 10⁻³ S/cm exhibited by La_0.9Sr_0.1Al_0.85Mg_0.15O₃.     

Local thermal sensation and comfort study in a field environment chamber served by displacement ventilation system in the tropics

This paper presents a study of local thermal sensation (LTS) and comfort in a field environmental chamber (FEC) served by displacement ventilation (DV) system. The FEC, 11.12 m (L)×7.53 m (W)×2.60 m (H), simulates a typical office layout. A total of 60 tropically acclimatized subjects, 30 male and 30 female, were engaged in sedentary office work for 3 h. Subjects were exposed to three vertical air temperature gradients, nominally 1, 3 and 5 K/m, between 0.1 and 1.1 m heights and three room air temperatures of 20, 23 and 26 °C at 0.6 m height. The objective of this study is to investigate the mutual effect of local and overall thermal sensation (OTS) and comfort in DV environment. The results show that in a space served by DV system, at OTS close to neutral, local thermal discomfort decreased with the increase of room air temperature. The OTS of occupants was mainly affected by LTS at the arm, calf, foot, back and hand. Local thermal discomfort was affected by both LTS and OTS. At overall cold thermal sensation, all body segments prefer slightly warm sensation. At overall slightly warm thermal sensation, all body segments prefer slightly cool sensation.     

On the origin of decay of spin current with temperature in organic spintronic devices

This article addresses the most challenging question facing the organic spintronics community today – what causes the universal loss of Giant Magnetoresistance (GMR) signal in organic spin valve devices made with different spin-polarized electrodes and organic semiconductor spacers? Careful analysis of our own and other experimental results available in literature indicate that transition of transport from polaron tunneling limit (suggested by the variable range hopping model) to thermally activated hopping limit (in the temperature range of 40–58 K) marks the most significant decrease of spin relaxation in organic semiconductors. With increasing occupancy of the available hopping sites by the thermally activated carriers, chances of spin flip inside the organic semiconductors increases significantly causing fast spin relaxation in the spin-valves.     

Optimum short-time polynomial regression for signal analysis

Sādhanā - We propose a short-time polynomial regression (STPR) for time-varying signal analysis. The advantage of using polynomials is that the notion of a spectrum is not needed and the...     

Influence of thickness on nanomechanical behavior of Black Diamond™ low dielectric thin films for interconnect and packaging applications

In the present study, we have investigated the thickness dependence of mechanical properties of the Black Diamond? (SiOC:H, BD, Low-k) films, which are of great interest in current Cu/low-k Back End of the Line (BEOL) interconnect/packaging technologies. For this investigation the BD thin films of six different thicknesses 100, 300, 500, 700, 1,000 and 1,200 nm were deposited on the 8″ Si wafer by using plasma enhanced chemical vapor deposition (PECVD) technique. Nanoindentation and nanoscratch tests of the BD films were performed by using the Nano Indenter^® XP (MTS Corp. USA). In nanoindentation testing of the BD films, significant differences in the elastic modulus of the BD films were observed. In nanoscratch testing, it is found that the critical load (Lc) and scratch width increases as the thickness of the film increases. Cross-sectional analysis of residual nanoindentation impressions was carried out using atomic force microscopy (AFM) to study the deformation behavior. The nanoindentation and nanoscratch responses of the BD thin films of six different thicknesses are different and they are expected mainly due to the molecular reorganization in thin/ultra thin films.