Characterization of doped single-wall carbon nanotubes by Raman spectroscopy

Single-wall carbon nanotubes were grown by thermal chemical vapor deposition using either boron- or nitrogen-containing feedstocks or both. Carrier doping was evidenced by hardenings of the G band in Raman spectra, and the estimated carrier concentration reached ∼0.4%. In the G′ and D band spectra, a doping-induced component was observed at the high- or low-energy side of the original one. However, the appearance of the new component did not always coincide with the carrier doping. The doped SWCNTs often show radial breathing mode peaks in the off-resonance region, indicating a defect-induced modification of absorption spectrum.     

Hydrogen storage properties of lithium silicon alloy synthesized by mechanical alloying

A lithium silicon alloy was synthesized by mechanical alloying method. Hydrogen storage properties of this Li-Si-H system were studied. During hydrogenation of the lithium silicon alloy, lithium atom was extracted from the alloy and lithium hydride was generated. Equilibrium hydrogen pressures for desorption and absorption reactions were measured in a temperature range from 400 to 500 °C to investigate the thermodynamic characteristics of the system, which can reversibly store 5.4 mass% hydrogen with smaller reaction enthalpy than simple metal Li. Li absorbing alloys, which have been widely studied as a negative electrode material for Li ion rechargeable batteries, can be used as hydrogen storage materials with high hydrogen capacity.     

Spatial joint constraints for the absolute nodal coordinate formulation using the non-generalized intermediate coordinates

In this investigation, a systematic procedure that can be used for modeling joint constraints for the absolute nodal coordinate formulation is developed. To this end, the non-generalized intermediate coordinates are introduced to derive a mapping between the generalized gradient coordinates and the non-generalized rotation parameters. With this mapping, a wide variety of joint constraints can be defined for the absolute nodal coordinate formulation in terms of the non-generalized reference coordinates and, therefore, existing well-developed constraint libraries formulated for the rigid body reference coordinates can be directly employed without significant modifications in existing codes. Furthermore, in order to define a rigid surface at the joint definition point, a set of orthonormality conditions is imposed on the gradient coordinates. This leads to not only accurate modeling of interface to mechanical joint, but also a simpler definition of the joint coordinate system obtained by the orthonormal gradient vectors. For this reason, a simpler form of constraint Jacobian and quadratic velocity vectors can be obtained as compared to those of the existing approach which requires the use of highly nonlinear joint coordinate system. A systematic procedure for eliminating the non-generalized coordinates and the dependent Lagrange multipliers associated with the coordinate mapping equations from the equations of motion is presented. As a result, a standard augmented form of the equations of motion can be obtained in terms of the generalized coordinates only. Several numerical examples are presented in order to demonstrate the use of the joint constraint formulation developed in this investigation.     

Molecular mechanism of regulation of pentylenetetrazol-induced calcium entry by 3'-untranslated region of a seizure-related cDNA, PTZ-17, in Xenopus oocytes

To determine the molecular mechanism of regulation of pentylenetetrazol (PTZ)-induced calcium entry by the seizure-related gene, PTZ-17, the role of the 3'-untranslated region (3'UTR) and also interaction between 3'UTR and intracellular factors were investigated. PTZ-induced calcium inward current in Xenopus oocytes injected with PTZ-17 RNA varied in magnitude among strains of mice: RNA derived from the DBA/2 mouse, which has a high susceptibility to convulsions, showed the largest current and that from the BALB/c mouse with a low susceptibility to convulsions showed no PTZ response. The sequence of 3'UTR showed alterations among mouse strains: 3'UTR of BALB/c showed a sequence alteration from T to G and that of DBA/2 showed a GTG insertion compared with that of B6. The 3'UTR also regulated the translation of chloramphenicol acetyltransferase (CAT) RNA depending on its sequence. A particular region within the 3'UTR demonstrated interaction with 60- and 47-kDa proteins. Sequence alterations in this region corresponded to disappearance or increase in PTZ-induced calcium entry. These findings suggest that a particular region within 3'UTR of the seizure-related gene, PTZ-17, is involved in PTZ-induced calcium entry via interaction between mRNA and specific RNA-binding proteins.     

Superior suppression of gate current leakage in Al<Subscript>2</Subscript>O<Subscript>3</Subscript>/Si<Subscript>3</Subscript>N<Subscript>4</Subscript> bilayer-based AlGaN/GaN insulated gate heterostructure field-effect transistors

AlGaN/GaN-based metal-insulator-semiconductor heterostructure field-effect transistors (MIS-HFETs) with Al₂O₃/Si₃N₄ bilayer as insulator have been investigated in detail, and compared with the conventional HFET and Si₃N₄-based MIS-HFET devices. Al₂O₃/Si₃N₄ bilayer-based MIS-HFETs exhibited much lower gate current leakage than conventional HFET and Si₃N₄-based MIS devices under reverse gate bias, and leakage as low as 1×10⁻¹¹ A/mm at −15 V has been achieved in Al₂O₃/Si₃N₄-based MIS devices. By using ultrathin Al₂O₃/Si₃N₄ bilayer, very high maximum transconductance of more than 180 mS/mm with ultra-low gate leakage has been obtained in the MIS-HFET device with gate length of 1.5 μm, a reduction less than 5% in maximum transconductance compared with the conventional HFET device. This value was much smaller than the more than 30% reduction in the Si₃N₄-based MIS device, due to the employment of ultra-thin bilayer with large dielectric constant and the large conduction band offset between Al₂O₃ and nitrides. This work demonstrates that Al₂O₃/Si₃N₄ bilayer insulator is a superior candidate for nitrides-based MIS-HFET devices.     

Study of step instability on Si surfaces

Step instabilities on Si(1 1 1) vicinal surface and Si(1 1 1) vicinal surface induced by Au adsorption were observed by reflection electron microscopy. On the Si(0 0 1) vicinal surface faceting of (0 0 1) surface due to surface reconstruction takes place and surface steps are bunching. The kinetics of mass transport of Si depends on the substrate temperature and steps are impermeable for Si adatoms at lower temperature and they are permeable at higher temperature. On the Si(1 1 1) vicinal surface the permeability of steps depends on the heating current direction. The steps are permeable for step-up current heating and are impermeable for step-down current heating. Above a critical coverage of Au (≈0.3 ML) steps are bunching irrespective of heating current direction and periodic array of extremely straight step bands is formed for the step-down current heating.     

Learning of real robot's inverse dynamics by a forward‐propagation learning rule

A forward‐propagation learning rule (FPL) has been proposed for a neural network (NN) to learn an inverse model of a controlled object. A feature of FPL is that the trajectory error propagates forward in NN and appropriate values of two learning parameters are required to be set. FPL has only been simulated to several kinds of controlled objects such as a two‐link arm in a horizontal plane. In this work, we applied FPL to AIBO and showed the validity of FPL on a real controlled object. At first, we tested a learning experiment of an inverse dynamic of a two‐link arm in a sagittal plane with viscosity and Coulomb friction by computer simulation. In this simulation, a low‐pass filter (LPF) was applied to realized trajectories because coulomb friction vibrates them. From the simulation results, we found that the learning process is stable by some adequate sets of the learning parameters although it is more sensitive to the values of the parameters owing to friction and gravity terms. Finally, we tested applying FPL to motor control of AIBO's leg. The inverse dynamics model was acquired by FPL with only about 150 learning iterations. From these results, the validity of the FPL was confirmed by the real robot control experiments. © 2007 Wiley Periodicals, Inc. Electr Eng Jpn, 161(4): 38–48, 2007; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20456