A High-Speed, High-Sensitivity Digital CMOS Image Sensor With a Global Shutter and 12-bit Column-Parallel Cyclic A/D Converters

This paper presents a high-speed, high-sensitivity 512times512 CMOS image sensor with column parallel cyclic 12-bit ADCs and a global electronic shutter. Each pixel has a charge amplifier for high charge-to-voltage conversion gain despite of using a large-size photodiode, and two sample-and-hold stages for the global shutter and fixed pattern noise (FPN) canceling. High-speed column-parallel cyclic ADC arrays with 12-bit resolution having a small layout size of 0.09 mm ² are integrated at both sides of image array. A technique for accelerating the conversion speed using variable clocking and sampling capacitance is developed. A digital gain control function using 14-bit temporal digital code is also set in the column parallel ADC. The fabricated chip in 0.25-mum CMOS image sensor technology achieves the full frame rate in excess of 3500 frames/s. The in-pixel charge amplifier achieves the optical sensitivity of 19.9 V/lxmiddots. The signal full scale at the pixel output is 1.8 V at 3.3-V supply and the noise level is measured to be 1.8mV_rms, and the resulting signal dynamic range is 60 dB     

Surface acoustic wave based sensors employing ionic liquid for hydrogen sulfide gas detection

This paper describes a new type hydrogen sulfide (H₂S) gas sensor using ionic liquid (IL). In this sensor, a reservoir for the IL was integrated on a surface acoustic wave (SAW) resonator. The IL serves as an absorber for H₂S gas. Mass change due to this absorption is detected as shift in the resonant frequency. In this study, we fabricated and demonstrated the sensor using the lithium niobate (LiNbO₃) SAW resonator with the resonant frequency of 38 MHz. The integrated reservoir was filled by the IL 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim]-[PF₆]). As an experimental result, we observed the linear correlation between the frequency-shift and the exposure time of the sensor to the H₂S gas.     

Coseismic lateral offsets of surface rupture zone produced by the 2001 Mw 7.8 Kunlun earthquake,Tibet from the IKONOS and QuickBird imagery

Analyses and interpretations of 1m‐resolution IKONOS, and 61cm‐resolution QuickBird images reveal that the distribution of strike‐slip offsets and ground deformation characteristics of the coseismic surface rupture produced by the 2001 M _w 7.8 Kunlun earthquake occurred in the western segment of the strike‐slip Kunlun fault, northern Tibet. The 2001 coseismic strike‐slip offsets measured from IKONOS images range from 2 m up to 16.7 m, generally 3–8 m, which are generally consistent with those measured immediately in the field after the earthquake. The coseismic surface ruptures along which offsets were observed are mainly composed of a numerous of en echelon shear faults and cracks which are concentrated on a rupture zone ranging from a few meters up to ～500 m in width. The offsets measured along individual shear faults or crack are typically 2–7 m, but up to >10 m in several locations. Our results show that high resolution remote sensing imagery provides a powerful tool for measuring coseismic strike‐slip offsets and detecting the ground deformation produced by a large earthquake in the remote and high mountain Tibet region.     

Fast Labelling of Natural Scenes Using Enhanced Knowledge

A new technique for labelling natural scenes is proposed. This technique labels disjoint regions on an image of a natural scene on the basis of knowledge about the relationship among objects. The proposed technique consists of three stages: (1) segmentation, (2) initial labelling, and (3) label improvement. One of the most promising previous techniques uses simulated annealing to find the solution, while our technique uses local hill-climbing with enhanced knowledge for speeding up the processing. Local hill-climbing is known to be easy to be captured by a local minimum. We solved this problem by enhancing the knowledge being used as constraints for the search. Our knowledge represents 1-to-n relationships among regions, pair-wise relationships of regions, and relative locations of the regions to the image. In addition, we introduced two region features: an entropy in intensity; and a linearity of contours of each region. The linearity evaluation aims to distinguish artificial objects from natural objects. The validity of the technique is supported by some experiments. These experiments showed that the proposed technique is much faster with the almost same accurate.     

Forced convective heat transfer to supercritical water flowing in tubes

Experimental investigations were made of heat transfer to supercritical water flowing in a horizontal tube and vertical tubes. A comprehensive set of data was obtained for pressures from 226 to 294 bar, bulk temperatures from 230 to 540°C, heat fluxes from 116 to 930 kW/m² and mass velocities from 310 to 1830 kg/m²s. Because the physical properties of supercritical fluids change rapidly with temperature in the pseudocritical region, the heat transfer coefficients show unusual behavior depending upon the heat flux. At low or modetate heat fluxes relatively to the flow rate, a satisfactory correlation was obtained, which predicts reasonably well the enhanced heat transfer coefficients near the pseudocritical point. The several characteristics of the deterioration in heat transfer which occurs at high heat fluxes were clarified, and the limit heat flux for the occurrence of the deterioration was determined in connection with the flow rate.     

A new recovery process of carbon dioxide from alkaline carbonate solution via electrodialysis

Bipolar membrane electrodialysis is applied to CO₂ recovery from alkaline carbonate solution. CO₂ in flue gas is captured by an alkaline hydroxide absorbing solution to form an alkaline carbonate solution. The captured CO₂ is recovered from the alkaline carbonate solution via bipolar membrane electrodialysis, and the alkaline solution is regenerated simultaneously. To reduce the power requirement for CO₂ recovery, this study considers optimal design and operation. Three membrane arrangements were compared, and the results indicate the membrane arrangement comprising a bipolar membrane and cation exchange membrane is the most energy saving. With further optimization of operation conditions, the minimum power requirement for CO₂ recovery was reduced to 2.1 MJ/kg‐CO₂ (or 2.1 GJ/t‐CO₂). © 2009 American Institute of Chemical Engineers AIChE J, 2009     

Single-step synthesis and characterization of single-walled carbon nanohorns hybridized with Pd nanoparticles using N2 gas-injected arc-in-water method

Single-walled carbon nanohorns (SWCNHs) hybridized with palladium (Pd) nanoparticles were synthesized by a single-step gas-injected arc-in-water method (GI-AIW) with a Pd wire inserted inside the anode hole. In the arc zone, carbon and Pd were vaporized simultaneously, leading to the formation of hybrid material of SWCNHs and Pd nanoparticles due to effective quenching. Based on TEM and CO chemisorption analyses, Pd nanoparticles were found to be embedded inside SWCNH aggregates. The size of Pd nanoparticles, determined by X-ray diffraction, was in the range of 3–6 nm when Pd wires with diameters of 0.1 and 0.3 mm were used. Using a Pd wire with a diameter larger than 0.5 mm results in larger Pd nanoparticles which tend to be exposed to the outer surface of the hybrid material. According to thermogravimetric analyses, the weight fraction of Pd nanoparticles is increased by increasing the Pd wire diameter although the yield of Pd nanoparticles decreased. SWCNHs hybridized with dispersed Pd nanoparticles, synthesized with 0.1 mm Pd wire, exhibited strong anti-oxidation resistance with a highly graphitic structure.     

Solid-state characterization of polyethylene reactor powders and their structural changes upon annealing

Polyethylene reactor powders prepared under different conditions were characterized using transmission electron microscopy, ¹H nuclear magnetic resonance and X-ray diffraction techniques. The molecular weight of the polyethylene reactor powders was around 1 × 10⁵. A unique domain morphology, quite different from the usual melt- or solution-crystallized lamellar structure, was observed, independent of polymerization temperature (T_poly). Annealing of reactor powders caused the aggregation of these crystalline domains, due to the significant molecular motion of the amorphous chains, before melting. The critical temperature was 20 °C higher than each T_poly, and corresponded to the temperature at the active catalyst site producing the chain growth. The morphologies of powders prepared at the lower T_poly contained smaller crystals that exhibited a constrained monoclinic form. In contrast, only usual orthorhombic crystals of larger size were found within the powder prepared at the higher T_poly. These results suggest that the competitive processes of chain propagation and crystal growth upon polymerization may lead to unique variations of the crystalline and amorphous phases, but with similar intermediate components in the phase that connects them.