Mechano-electrochemistry of a passive surface using an in situ micro-indentation test

Depassivation–repassivation of iron surfaces in boric–borate solutions were investigated by using the micro-indentation test. A pair of current peaks due to repair of the passive film following rupture of the film were observed during a series of indenter drives, i.e., loading and unloading of the indenter. The shape of the current peak depended on environmental conditions (conductivity and pH of the solution) and substrate conditions (mechanical processing history, alloyed element) as well as indentation conditions (repetition, maximum depth, and maximum load). Plastic deformation of the surface was accompanied by surface depassivation, while no depassivation occurred during the elastic deformation, indicating that the passive film on iron has a ductile property. The solution conditions did not affect the scale of depassivation but affected the rate of repassivation. Dislocations in the substrate made surface depassivation difficult but enhanced reactivity during the repassivation. The test also revealed that type-312L stainless steel has high corrosion resistance in a concentrated NaCl solution.     

Output power dispatch control for a wind farm in a small power system

Nowadays, a wind turbine generator (WTG) is required to provide control capabilities as the output power of WTG fluctuates. Under this scenario, this paper proposes an output power control method of a wind farm (WF) connected to a small power system using pitch angle control. In this control approach, the WF output power control is achieved by two control levels: central and local. In the central control, the WF output power command is determined by considering the frequency deviations and wind speeds using a fuzzy function. Then, the local output power commands for each of the WTGs are based on the proposed dispatch control. In the proposed dispatch control, the output commands of each WTG are determined by considering wind conditions for each of the WTGs. The simulation results by using an actual detailed model for the wind power system show the effectiveness of the proposed method. Copyright © 2010 John Wiley & Sons, Ltd.     

Quantitative Visualization of the Interaction between Complement Component C1 and Immunoglobulin G: The Effect of CH1 Domain Deletion

Immunoglobulin G (IgG) adopts a modular multidomain structure that mediates antigen recognition and effector functions, such as complement-dependent cytotoxicity. IgG molecules are self-assembled into a hexameric ring on antigen-containing membranes, recruiting the complement component C1q. In order to provide deeper insights into the initial step of the complement pathway, we report a high-speed atomic force microscopy study for the quantitative visualization of the interaction between mouse IgG and the C1 complex composed of C1q, C1r, and C1s. The results showed that the C1q in the C1 complex is restricted regarding internal motion, and that it has a stronger binding affinity for on-membrane IgG2b assemblages than C1q alone, presumably because of the lower conformational entropy loss upon binding. Furthermore, we visualized a 1:1 stoichiometric interaction between C1/C1q and an IgG2a variant that lacks the entire C_H1 domain in the absence of an antigen. In addition to the canonical C1q-binding site on Fc, their interactions are mediated through a secondary site on the C_L domain that is cryptic in the presence of the C_H1 domain. Our findings offer clues for novel-modality therapeutic antibodies.     

Monte Carlo uncertainty quantification of the effective delayed neutron fraction

The applicability of Monte Carlo techniques, namely the Monte Carlo sensitivity method and the random-sampling method, for uncertainty quantification of the effective delayed neutron fraction β_eff is investigated using the continuous-energy Monte Carlo transport code, MCNP, from the perspective of statistical convergence issues. This study focuses on the nuclear data as one of the major sources of β_eff uncertainty. For validation of the calculated β_eff, a critical configuration of the VENUS-F zero-power reactor was used. It is demonstrated that Chiba's modified k-ratio method is superior to Bretscher's prompt k-ratio method in terms of reducing the statistical uncertainty in calculating not only β_eff but also its sensitivities and the uncertainty due to nuclear data. From this result and a comparison of uncertainties obtained by the Monte Carlo sensitivity method and the random-sampling method, it is shown that the Monte Carlo sensitivity method using Chiba's modified k-ratio method is the most practical for uncertainty quantification of β_eff. Finally, total β_eff uncertainty due to nuclear data for the VENUS-F critical configuration is determined to be approximately 2.7% with JENDL-4.0u, which is dominated by the delayed neutron yield of ²³⁵U.     

Performance Evaluation of Magnetostrictive Small Wind Turbines Using Fe–Co Alloy–Based Clad Sheets

In this study, the Fe–Co alloy is combined with cobalt ferrite (CoFe₂O₄) and nickel (Ni) to form Fe–Co/CoFe₂O₄ and Fe–Co/Ni clad sheets and their energy-harvesting performance is evaluated. The Fe–Co/CoFe₂O₄ clad sheet exhibits an output voltage of 4.229 mV and an output power of 6.89 nW at a wind speed of 10 m s⁻¹. The energy-harvesting performance of both these clad sheets cannot be quantitatively compared owing to their different thicknesses, which result in varying volume and distance from the neutral plane. Nevertheless, the values of output voltage and power for Fe–Co/CoFe₂O₄ are higher than those for Fe–Co/Ni (2.107 mV and 0.294 nW).     

Anisotropic electroabsorption and optical modulation in InGaAs/InAlAs multiple quantum well structures

The first measurements to be made of large anistropic electroabsorption and modulation of long-wavelength light propagating along the plane of InGaAs/InAlAs multiple quantum well (MQW) structures grown by molecular beam epitaxy (MBE) are reported. Photocurrent response of waveguide p-i-n diodes is studied for incident light polarization parallel and perpendicular to the MQW layers. Photocurrent increase with reverse bias throughout the entire photoresponse spectrum is observed for both polarizations. The MQW p-in optical modulator shows a capacitance-limited pulse response of 250 ps and the modulation depth is 14 percent.     

Preparation and electrooptical properties of liquid crystal dispersed film by electron-beam irradiation

Polymer films consisting of nematic liquid crystal (LC) droplets and polymer networks were prepared by using a low-energy electron beam to irradiate a homogeneous mixture of nematic LC and bifunctional methacrylate monomer. Influences of such polymerization conditions as polymerization temperature, monomer concentration, and radiation energy on electrooptical properties of the compound films were examined. The polymer yield, affecting to a large extent the film properties, depended on the monomer concentration and the radiation energy. Compound films, which have a switching function from the scattering state to transparency by applying approximately 20–30 V between the two sides of the film, were obtained. In addition, it was found that a compound film with excellent electrooptical properties was prepared by changing impure LC in the droplets into pure LC. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 65:1675–1681, 1997     

Grazing-incidence wide-angle X-ray diffraction study on molecular aggregation state of imprinted polyimide film before and after hard baking

Nanoimprint lithography (NIL) was carried out on precursor of polyimide (PI), poly(amic acid) film, and then hard baking to obtain imprinted PI film. The molecular aggregation states of imprinted PI films before and after hard baking were investigated by grazing-incidence wide-angle X-ray diffraction comparing with the one of flat PI film. It was found that NIL and hard baking can strongly affect the molecular aggregation states of PI film. Before hard baking, PI chain is aligned parallel to the line direction on the line. After hard baking, the alignment in ordered domain was changed to that the PI molecule of which chain axis is perpendicular to the line direction is significantly increased, while, PI molecule of which chain axis is parallel to the line direction is decreased after hard baking. Through comparing with the flat PI, crystallinity of imprinted PI film has been significantly enhanced.     

Humido-sensitive conducting polymer films and applications to linear actuators

Free-standing films made of poly(3,4-ethylenedioxythiophene) doped with poly(4-styrenesulfonate) (PEDOT/PSS) with various PSS contents were newly prepared by casting water dispersion of the PEDOT/PSS colloidal particles in the presence of an extra PSS. Electrical conductivity, morphology, water vapor sorption, and electro-active polymer actuating behavior of the resulting films were investigated by means of four-point method, atomic force microscope (AFM), sorption isotherm, and electromechanical analyses. The maximum contraction of the film by application of an electric field increased with increasing both PSS content and relative humidity (RH), where the value attained 7% at 70% RH for the film with 93% of PSS. Since the isothermal sorption curve of the film was less dependent on the PSS content, the significant increase of the film contraction was explained by two mechanisms: (i) the extra PSS prevented from hydrogen bonding between adjacent PEDOT/PSS particles that suppressed dimensional changes of the film; and (ii) the higher the RH, the larger the degree of water vapor sorption, which led to the large film contraction by desorption of water vapor via Joule heating. On the basis of this phenomenon linear actuators utilizing PEDOT/PSS films were successfully developed and applied to leverage actuator and Braille cell.