Biocompatible Cubic Boron Nitride: A Noncytotoxic Ultrahard Material

Cubic boron nitride (c-BN) has an ultrahardness and a large bandgap energy like diamond. In the last 30 years, most of the attention has been directed towards the mechanical and electronic applications of c-BN, while its biological potential has been overlooked. The authors report in vitro biocompatibility of high-quality c-BN films prepared by plasma-enhanced chemical vapor deposition using the chemistry of fluorine. c-BN films become superhydrophilic when chemical-treated in hydrogen and nitrogen plasmas with or without the impact of low-energy ions due to a marked increase in polar part of the surface free energy by removal of the fluorine atoms terminating c-BN surfaces. Satisfactory proliferation and differentiation of osteoblastic cells comparable with a control sample and a superhydrophilic nanocrystalline diamond film, and the formation of mineral deposits by biomineralization are confirmed on the superhydrophilic c-BN films with negative values of zeta potential. The results demonstrate a high potential of c-BN as a noncytotoxic ultrahard coating material for biological and biomedical applications.     

High-Density Frenkel Defects as Origin of N-Type Thermoelectric Performance and Low Thermal Conductivity in Mg3Sb2-Based Materials

Mg₃Sb₂-based intermetallic compounds with exceptionally high thermoelectric performance exhibit unconventional n-type dopability and anomalously low thermal conductivity, attracting much attention to the underlying mechanisms. To date, investigations have been limited to first-principle calculations and thermodynamic analysis of defect formation, and detailed experimental analysis on crystal structure and phonon modes has not been achieved. Here, a synchrotron X-ray diffraction study clarifies that, against a previous view of a simple crystal structure with a small unit cell, Mg₃Sb₂ is inherently a heavily disordered material with Frenkel defects, charge-neutral defect complexes of cation vacancies and interstitials. Ionic charge neutrality preserved in Mg₃Sb₂ is responsible for exotic n-type dopability, which is unachievable for other Zintl phase materials. The thermal conductivity of Mg₃Sb₂ exhibits deviation from the standard T⁻¹ temperature dependency with strongly limited phonon transport due to a strain field. Inelastic X-ray scattering measurement reveals enhanced phonon scattering induced by disorder. The results will draw renewed attention to crystal defects and disorder as means to explore new high-performance thermoelectric materials.     

Engineering the Interlayer Spacing by Pre-Intercalation for High Performance Supercapacitor MXene Electrodes in Room Temperature Ionic Liquid

MXenes exhibit excellent capacitance at high scan rates in sulfuric acid aqueous electrolytes, but the narrow potential window of aqueous electrolytes limits the energy density. Organic electrolytes and room-temperature ionic liquids (RTILs) can provide higher potential windows, leading to higher energy density. The large cation size of RTIL hinders its intercalation in-between the layers of MXene limiting the specific capacitance in comparison to aqueous electrolytes. In this work, different chain lengths alkylammonium (AA) cations are intercalated into Ti₃C₂T_x, producing variation of MXene interlayer spacings (d-spacing). AA-cation-intercalated Ti₃C₂T_x (AA-Ti₃C₂), exhibits higher specific capacitances, and cycling stabilities than pristine Ti₃C₂T_x in 1 m 1-ethly-3-methylimidazolium bis-(trifluoromethylsulfonyl)-imide (EMIMTFSI) in acetonitrile and neat EMIMTFSI RTIL electrolytes. Pre-intercalated MXene with an interlayer spacing of ≈2.2 nm, can deliver a large specific capacitance of 257 F g⁻¹ (1428 mF cm⁻² and 492 F cm⁻³) in neat EMIMTFSI electrolyte leading to high energy density. Quasi elastic neutron scattering and electrochemical impedance spectroscopy are used to study the dynamics of confined RTIL in pre-intercalated MXene. Molecular dynamics simulations suggest significant differences in the structures of RTIL ions and AA cations inside the Ti₃C₂T_x interlayer, providing insights into the differences in the observed electrochemical behavior.     

Study on the device characteristics of a quasi-SOI power MOSFETfabricated by reversed silicon wafer direct bonding

The device characteristics of a quasi-SOI power MOSFET were investigated to obtain its optimum device structure. The oxide at the original bottom surface of the bulk power MOSFET of the quasi-SOI power MOSFET formed by reversed silicon wafer direct bonding acts as the buried oxide of the conventional SOI power MOSFET. The short channel effect of the quasi-SOI power MOSFET was larger than that in the conventional SOI power MOSFET. It was suppressed by increasing the width of the oxide in the body region, and the parasitic bipolar effect was suppressed by decreasing it. We also propose a new device structure which can suppress the short channel effect and parasitic bipolar effect of a quasi-SOI power MOSFET based on the results of these experiments     

Characteristics of thermally expanded core fiber

Thermally expanded core (TEC) fiber is expected to reduce fiber-to-fiber and fiber-to-laser diode connection loss. This paper describes the characteristics of TEC fiber theoretically and experimentally. We reveal theoretically that when fabricating TEC fiber the mode field diameter (MFD) is enlarged more effectively by increasing the heating temperature rather than the heating time. In the 1300-1600°C temperature range with heating times between 0 and 60 min, it is necessary to control the temperature accurately so that no deviation from the target temperature is more than ±30°C. This is in order to ensure that any connection loss caused by MFD mismatch is less than 0.1 dB. We show experimentally that the propagation loss of TEC fiber is dependent on the heating region and wavelength by using a micro burner with a propane/oxygen flame. Based on the relationship between the loss characteristics and the expanded MFD, we suggest a method for nondestructively measuring the MFD in TEC fibers     

Oxidation of Fe (II) in sulfuric acid solutions with dissolved molecular oxygen

The oxidation of Fe(II) with dissolved molecular oxygen was studied in sulfuric acid solutions containing 0.2 mol . dm^-3 FeSO₄ at temperatures ranging from 343 to 363 K. In solutions of sulfuric acid above 0.4 mol . dm^-3, the oxidation of Fe (II) was found to proceed through two parallel paths. In one path the reaction rate was proportional to both [Fe²⁺]² and po₂, exhibiting an activation energy of 51.6 . kJ mol^-1. In another path the reaction rate was proportional to [Fe²⁺]², [SO_4-], and po₂ with an activation energy of 144.6 kJ . mol^-1. A reaction mechanism in which the SO_4- ions play an important role was proposed for the oxidation of Fe(II). In dilute solutions of sulfuric acid below 0.4 mol . dm^-3, the rate of the oxidation reaction was found to be proportional to both [Fe(II)]² and Po₂, and was also affected by [H⁺] and [SO_2- ⁴]. The decrease in [H⁺] resulted in the increase of reaction rate. The discussion was further extended to the effect of Fe (III) on the oxidation reaction of Fe (II).     

Realistic image synthesis of a deformable living thing based on motion understanding

This paper describes a system that can synthesize realistic sequential images of moving goldfish based on the image understanding result of real goldfish. To analyze and synthesize images in real-time, we have constructed a hardware system that consists of 32 paralell transputers with a high-speed visual-data interface called VIT (Visual Interface for Transpputer Network). The system is very flexible and powerful for various types of image processing because it can be extended according to the required computational cost. In the understanding process, we assume that the target object, a goldfish in this case, deforms its shape pliably in 3-D space and moves only in a two-dimensional direction. A modeling, called the Bone-Structured Solid Modeler, which is suitable for representing deformable objects such as living things, plays an important role in the understanding and synthesis processes of the deformable object. Three types of constraints for motion, namely, static, dynamic, and object, are utilized to verify the estimated pose and orientation of the object. In the motion synthesis process, realistic moving images are synthesized by controlling the model employing the motion understanding result. Simulation results are presented to show the effectiveness of the system. The technology discussed in this paper is expected to play a key role in the realization of future visual human interfaces.     

Polarisation-insensitive high-isolation nonreciprocal device for optical circulator application

A novel high-isolation structure for a polarisation-insensitive nonreciprocal device intended for optical circulator application is proposed. It consists of birefringent crystals and polarisation rotators. Experimental demonstration shows an isolation of over 42 dB and an insertion loss of under 1.5 dB.<>     

The operation mechanism of a charge modulation device (CMD) imagesensor

The operational mechanism of the charge modulation device (CMD) as an image sensor is presented. A newly developed device simulator, the transistor analysis program for imagers calculating non-steady-state equations (TRINE) is used in this analysis. Comparison of the calculated results with measured data shows that the model predictions are consistent with measured electrical and optical characteristics within a range of 20%. The operational mechanism has been clarified, and the accuracy of the method proves that it is effective in quantitative device design. The discretization scheme of the cylindrical coordinate system used is also shown     

A small pixel CMD image sensor

A charge modulation device (CMD) imager with pixel dimensions of 7.3 μm(H)×7.6 μm(V) was designed, fabricated, and examined. These pixel dimensions are suitable for an HDTV imager with a 1-in image format. The optical aperture ratio is 34%. The effective number of pixels in the imager is 660 horizontal and 492 vertical. The saturation signal current is 17 μA/pixel at an exposure of 1 lx-s with good linearity of photoconversion characteristics. The peak of its spectral response occurs at a wavelength of 575 nm. The blooming suppression ratio of the CMD was measured to be -122 dB. The sensor produces a high-quality image with no degradation in spatial resolution and no image lag. These features show that the CMD imager is eminently suitable for a further high-resolution imager sensor