Fine Patterning and Characterization of Gel Films Derived from Methyltriethoxysilane and Tetraethoxysilane

Pregrooves of 1.6 µm pitch for optical data storage have been embossed successfully by pressing a stamper against x CH₃Si(OC₂H₅)₃(100 - x )Si(OC₂H₅)₄-derived gel films (60 ≤ x ≤ 100 mol%) on glass-disk substrates of 130 mm diameter. When x is <40 mol%, the resultant films are too hard to emboss patterns uniformly. The shrinkage of the patterns is ∼4% for all the films when 60 lessthan equal to x lessthan equal to 100 mol%, even after heat treatment at 350°C, so that the nearly net negative shape of the stamper is preserved. The methyl groups in the films decompose at temperatures from 500° to 600°C.     

Gene duplication and multiplicity of collagenases in Clostridium histolyticum

Clostridium histolyticum collagenase contains a number of different active components. Previously we have shown that colH encodes a 116-kDa collagenase (ColH) and a 98-kDa gelatinase. We purified a different 116-kDa collagenase (ColG) from the culture supernatant and sequenced its gene (colG). We also identified four other gelatinases (105, 82, 78, and 67 kDa) and determined their N-terminal amino acid sequences, all of which coincided with that of either ColG or ColH. Hybridization experiments showed that each gene is present in a single copy and each gene is transcribed into a single mRNA. These results suggest that all the gelatinases are produced from the respective full-length collagenase by the proteolytic removal of C-terminal fragments. The substrate specificities of the enzymes suggest that colG and colH encode class I and class II enzymes, respectively. Analysis of their DNA locations by pulsed-field gel electrophoresis and nucleotide sequencing of their surrounding regions revealed that the two genes are located in different sites on the chromosome. C. histolyticum colG is more similar to C. perfringens colA than to colH in terms of domain structure. Both colG and colA have a homologous gene, mscL, at their 3' ends. These results suggest that gene duplication and segment duplication have occurred in an ancestor cell common to C. histolyticum and C. perfringens and that further divergence of the parent gene produced colG and colA.     

Effect of Ga2O3 on Sintering and Phase Stability of Sc2O3‐Doped Tetragonal Zirconia Prepared via Aqueous Solution Route

The effects of the presence of Ga₂O₃ on low‐temperature sintering and the phase stability of 4, 5, and 6 mol% Sc₂O₃‐doped tetragonal zirconia ceramics (4ScSZ, 5ScSZ, and 6ScSZ, respectively) were investigated. A series of zirconia sintered bodies with compositions (ZrO₂)_0.99?x(Sc₂O₃)_x(Ga₂O₃)_0.01, x = 0.04, 0.05, and 0.06 was fabricated by sintering at 1000°C to 1500°C for 1 h using fine powders that were prepared via the combination of homogeneous precipitation method and hydrolysis technique using monoclinic zirconia sols synthesized through the forced hydrolysis of an aqueous solution of zirconium oxychloride at 100°C for 168 h. The presence of 1 mol% Ga₂O₃ was effective in reducing sintering temperature necessary to fabricate dense bodies and enabled to obtain dense sintered bodies via sintering at 1100°C for 1 h. The phase stability, that is, low‐temperature degradation behavior of the resultant zirconia ceramics was determined under hydrothermal condition. The zirconia ceramics codoped with 1 mol% Ga₂O₃ and 6 mol% Sc₂O₃ (1Ga6ScZ) fabricated via sintering at 1300°C for 1 h showed high phase stability without the appearance of monoclinic zirconia phase, that is the tetragonal‐to‐monoclinic phase transformation was not observed in the 1Ga6ScZ after treatment under hydrothermal condition at 150°C for 30 h.     

Water permeation properties of SiO2-RSiO3/2 (R = methyl,vinyl, phenyl) thin films prepared by the sol-gel method on nylon-6 substrate

Nylon-6 substrates were coated with SiO₂-RSiO_3/2 (R = methyl, vinyl, phenyl) thin films by the sol-gel method, and their water permeability was evaluated Tetraethoxysilane (TEOS) and trifunctional alkoxides such as methyltriethoxysilane (MTES), vinyltriethoxysilane (VTES), and phenyltriethoxysilane (PhTES) were used as starting materials. Water permeability coefficients of the nylon-6 substrates coated with these SiO₂-RSiO_3/2 thin films were increased with an increase in the content of these trialkoxysilanes in the films. The water permeability coefficients of these coated nylon-6 substrates were smaller in the order of the systems TEOS-PhTES < TEOS-VTES < TEOS-MTES in the relatively low content of the trialkoxysilanes. © 1996 John Wiley & Sons, Inc.     

Parallel BDD-based monolithic approach for acoustic fluid-structure interaction

Parallel BDD-based monolithic algorithms for acoustic fluid-structure interaction problems are developed. In a previous study, two schemes, NN-I + CGC-FULL and NN-I + CGC-DIAG, have been proven to be efficient among several BDD-type schemes for one processor. Thus, the parallelization of these schemes is discussed in the present study. These BDD-type schemes consist of the operations of the Schur complement matrix-vector (Sv) product, Neumann-Neumann (NN) preconditioning, and the coarse problem. In the present study, the Sv product and NN preconditioning are parallelized for both schemes, and the parallel implementation of the solid and fluid parts of the coarse problem is considered for NN-I + CGC-DIAG. The results of numerical experiments indicate that both schemes exhibit performances that are almost as good as those of single solid and fluid analyses in the Sv product and NN preconditioning. Moreover, NN-I + CGC-DIAG appears to become more efficient as the problem size becomes large due to the parallel calculation of the coarse problem.     

Supercritical hydrothermal synthesis and in situ organic modification of indium tin oxide nanoparticles using continuous-flow reaction system

ITO nanoparticles were synthesized hydrothermally and surface modified in supercritical water using a continuous flow reaction system. The organic modification of the nanoparticles converted the surface from hydrophilic to hydrophobic, making the modified nanoparticles easily dispersible in organic solvent. The addition of a surface modifier into the reaction system impacted the crystal growth and particle size as well as dispersion. The particle size was 18 nm. Highly crystalline cubic ITO with a narrow particle size distribution was obtained. The advantages of short reaction time and the use of a continuous reaction system make this method suitable for industrial scale synthesis.     

Analysis of Cs-adsorption behavior using a column filled with microcapsule beads of potassium copper hexacyanoferrate

Ash-washing technology is a crucially important technology for removing radioactive Cs from contaminated ash. For that technology, Cs⁺ removal from the ash-washing solution by the adsorbent is necessary. This study was conducted to establish rapid preparation of appropriate adsorption columns for Cs⁺ uptake. A one-site model was not used for analysis because the model cannot accommodate sites with different adsorption speed. Results demonstrated that the adsorption behavior of the column filled with the granules of potassium copper hexacyanoferrate was well reproduced by a two-site adsorption model with parameters chosen through analysis of batch adsorption test results.     

Bionic tracking method by hand & eye-vergence visual servoing

Animals rotate their eyes to gaze at the target prey, enhancing the ability of measuring the distance to the target precisely for catching it. These animals, visual tracking includes the triangular eye-vergence control and their body's motion control by visual servoing. The research aims to realize a bionic robot tracking performance, in which the body links moves together with eyes' view orientation. This paper proposed a hand & eye-vergence dual control system which included two feedback loops: an outer loop for conventional visual servoing to direct a manipulator toward a target object and an inner loop for active motion control of binocular cameras to change the viewpoint along with the moving object to give an accurate and broad observation. This research also foused on how to compensate a fictional motion of the target seen by camera images in an eye-in-hand system, where the camera was fixed on the end-effector and moved together with the hand motion. A robust motion-feedforward (MFF) recognition method is proposed to compensate the fictional motion of the target based on the manipulator's joint velocity, then the real motion of the target seen by camera images is extracted, which can improve the feedback image sensing unit to make the whole servoing system dynamically stable. The effectiveness of the proposed hand & eye-vergence visual servoing method is shown by tracking experiments using a 6-DoF robot manipulator and a 3-DoF binocular vision system.     

Investigation of tribo-chemistry by means of stable isotopic tracers: Mechanism for durability of monomolecular boundary film

A monomolecular film of octadecanoic acid on a Si(1 0 0) surface was prepared using a computer-controlled Langmuir trough. The tribological properties were acquired by a ball-on-flat type tribo-tester under reciprocating motion. Considerable effects of ball material on lifetime for low friction were observed; a glass ball was excellent while a steel ball was poor. The rubbed surfaces on ball and flat were studied by time-of-flight secondary ion mass spectroscopy. Transfer of the carboxylic acid and silicon onto the ball surface from the flat specimen was found. The role of the transferred acid that prolongs the lifetime of low friction was proposed. It should be emphasized that deuterium-labeled carboxylic acid makes the target of TOF-SIMS analysis clear.