Chemical modification of olive pomace by various esters and silane

The olive pomace was modified chemically to improve the interface between the polymer matrix and the cellulosic fillers. The modification was done using various ester types having the same nature, however, with different chain lengths and one silane. Before the surface treatment, the olive pomace was extracted with acetone to remove contaminants on the surface, using Soxhlet apparatus. The transesterification of olive pomace with the different ester components, i.e., vinyl acetate, vinyl propanoate, and vinyl butanoate, and the condensation reaction with dichlorodimethylsilane was confirmed by Fourier transform infrared (FTIR) analysis. Moreover, the treatment of olive pomace with vinyl acetate improves the thermal stability and the sample records higher onset temperature of degradation as measured by thermogravimetric analysis (TGA). The results obtained indicated also that the reaction between the hydroxyl groups of waste flour and the acetyl, propionyl, pivalyl, and silane groups have occurred. The modified wood flours exhibited a decrease in the hydrophilicity as supported by the lower moisture content. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Modelling systems defined by RTD curves

The RTD theory is commonly used for describing flow patterns in a large class of applications, and particularly for ventilated enclosures. Experimental RTD curves are used for modelling these premises with an application in the nuclear industry for predicting the airborne pollutant transfers in order to prevent radiological risk. An approach based on a superstructure involving interlinked elementary flow patterns such as CSTRs, PFRs, recycles and by-passes is implemented. In order to propose a generic and easy to use tool, the associated large-scale MINLP problem is solved by using the GAMS package. After a validation phase on examples with known solutions, a laboratory enclosure, called MELANIE, used in the nuclear industry is modelled. The comparison between experimental RTD curve and the ones obtained from models extracted from superstructures shows good agreement. The superstructure-based solution procedure constitutes an efficient and intermediate way between numerical simulations using CFD codes and experimental determinations of characteristic parameters, which are both difficult to implement in the case of large and cluttered systems which are typical of the nuclear industry.     

Hydrogen consumption and power density in a co-flow planar SOFC

In the present work, power density and hydrogen consumption in a co-flow planar solid oxide fuel cell (SOFC) are studied according to the inlet functional parameters; such as the operational temperature, the operational pressure, the flow rates and the mass fractions of the species. Furthermore, the effect of the cell size is investigated. The results of a zero and a one-dimensional numerical electro-dynamic model predict the remaining quantity of the fed hydrogen at the output of the anode flow channel. The remaining hydrogen quantities and the SOFC's power density obtained are discussed as a function of the inlet functional parameters, the geometrical configuration of the cell and several operating cell voltages values.     

Improvement of electrical arc furnace operation with an appropriate model

Electrical arc furnaces are commonly employed in industry to produce molten steel by melting iron and scrap steel. Furnace control is a necessary operation for production optimization. The principal parameters to be controlled are: maximum productivity requirements, minimum power off time, good power quality and safety. The aim of this study is to achieve all these objectives. Hence, because of the stochastic and dynamic behaviour of the arc during the melting process, a proposed model is checked with measurements at an industrial electrical arc furnace. How electrodes position and transformer taps can affect X and R arc function are discussed in detail. This new operating strategy has been determined taking into account Flicker, melting stages and electrode positions. It is shown that optimum efficiency can be reached by the integration of the proposed model in regulation loop.     

Modelling of a hybrid photovoltaic thermal collector based on CdTe

A few years ago, silicon photovoltaic panels had yields of 10 to 18%, which made them interesting because is not profitable enough (too expensive to energy conversion yield too low).But recently, thin film technology appears to increase the efficiency and reduce the cost. For application in hybrid collectors, various types of solar photovoltaic hybrid collectors (PVT) based on new materials for solar cells have been developed as the binary semiconductor, ternary and quaternary materials and organic. CdTe is a the most appropriate binary materials for use in photovoltaic structures in thin layers, this material can produce a high yield of about 15% and is also known by a direct band structure gap of a value of 1.45 eV and a very high absorption coefficient (>105 cm^–1 in the visible). In this work we present the modeling of a hybrid photovoltaic thermal collector based on the thin films solar cells of CdTe, and then we made the determination of the temperature levels of the various layers through the development of the energy balance sheet involves heat exchange between the different components of the collector and to study its electrical and thermal performance, and finally compare their efficiency with it of the PVT collector based on monocrystalline silicon.     

Analysis of intermetallic swelling on the behavior of a hybrid solution for compressed hydrogen storage – Part I: Analytical modeling

This study focuses on the mechanical response of a hybrid solution dedicated to gaseous hydrogen storage. This solution is made of a carbon/epoxy composite overwrapped on a metal liner first coated with intermetallic material. The composite helps to reinforce the structure, while the liner prevents it from any leakage. In case of deficiency, the intermetallic material behaves as a sponge and interrupts the leakage by absorption and micro-cracks reduction. This hybrid solution or this specific use of intermetallic material has never been presented before. The laminate composite is anisotropic, whereas the liner is an elastic–plastic material. The intermetallic is purely thermo elastic and its study is limited to its mechanical contribution. Using these hypotheses, the suggested analytical model provides an exact solution for stresses and strains on the cylindrical section of the hybrid solution submitted to thermomechanical static loading and hydrogen leakage. The swelling effect of the intermetallic on the behavior of the structure is then investigated.     

Chemico-physical modifications induced by plasma and ozone sterilizations on shape memory polyurethane foams

Thermally activated shape memory polyurethane foams are promising materials for minimally invasive surgical procedures. Understanding their physical and chemical properties, in vitro response and effects of sterilization is mandatory when evaluating their potential as biomaterials. In this work, we report on the characterization of two Cold Hibernated Elastic Memory (CHEM) foams before and after two novel low-temperature sterilization techniques (plasma and ozone). Foams have different transition temperatures (T_trans), as determined by Tanδ peaks in DMA tests, that depend on their chemical composition: both foams possess excellent shape recovery ability (Recovery Rate up to 99%) in conventional shape recovery tests. Plasma sterilization (Sterrad^® sterilization system) resulted in a slight increase of open porosity, but no effects on bulk chemical and thermo-mechanical properties were observed. Ozone sterilization had a stronger effect on foams morphology, both in terms of an evident rupture of pore walls and surface oxidation. These modifications affected both thermomechanical and shape recovery behavior. Furthermore, plasma sterilized foams cytocompatibility was investigated with L929 fibroblast cell line in vitro, showing a good adhesion and proliferation, as confirmed by SEM observation and Alamar blue assay. The obtained results contribute to define the role of shape memory foams as biomaterials and open novel questions on the role of sterilization technique effects on cellular solids.     

Fracture of elastomers under static mixed mode: the strain-energy-density factor

This work deals with the fracture of rubbers under a mixed mode loading (I + II) and it is an extension of our previous papers on that subject [Aït Hocine N, Naït Abdelaziz M, Imad A (2002) Int J Fract 117:1–23; Aït Hocine N, Naït Abdelaziz M (2004) In: Sih GC, Kermanidis B, Pantelakis G (eds) 6th international conference for mesomechanics. Patras (Greece), May 31–June 4, pp 381–385]. An experimental and a numerical analysis were carried out using a Styrene Butadiene Rubber (SBR) filled with 20 and 30% of carbon black. Sheets with an initial central crack (CCT specimens) inclined with a given angle compared to the loading direction were used. The J-integral and its critical values J _c (fracture surface energy) were determined by combining experimental data and finite element results. These critical values, determined at the onset of crack growth, were found to be quite constant for each elastomer tested, which suggests that J _c represents a reasonable fracture criterion of such materials. Then, the strain–stress field and the strain-energy-density factor S, earlier introduced by Sih [Sih GC (1974) Int J Fract 10(3):305–321; Sih GC (1991) Mechanics of fracture initiation and propagation. Kluwer Academic Publishers, Dordrecht, 428 pp] were numerically calculated around the crack tip. According to the experimental observations, the plan of crack propagation is perpendicular to the direction of the maximum principal stretch. Moreover, as suggested by Sih in the framework of linear elastic fracture mechanics (LEFM), the minimum values S ^min of the factor S are reached at the points corresponding to the crack propagation direction. These results suggest that the concept of the maximum principal stretch and the one of the strain-energy-density factor can be used as indicators of the crack propagation direction.     

Study and characterization of composites materials based on polypropylene loaded with olive husk flour

In Algeria, a significant quantities of olive husk are rejected to nature causing by the way major nuisances to environment, to give us a reason for which our work is focused on the valorization of this waste by its incorporation in a polypropylene matrix. The hydrophilic nature of natural fibers affects negatively its adhesion to hydrophobic polymeric matrix. To improve interfacial adhesion, two modes of chemical treatments were done using vinyltriacetoxysilane (VTAS) and maleic‐anhydride‐polypropylene (PPMA) compatibilisant agent. Several formulations of PP filled with 10 and 20% by mass of olive husk flour treated (OHFT) and untreated (OHFUT) were prepared. The chemical modification of olive husk flour was studied by Fourier transform infrared (FTIR) spectroscopy. The tensile properties, the water‐absorption behavior, the thermal degradation properties, and crystallinity of the composites were investigated. It was found that, the incorporation of the treated and untreated OHF improves the thermal stability of the composites. However, the use of the compatibilizer agent PPMA leads to a better thermal stability compared with the treatment of the OHF by the VTAS and the OHFUT. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011