Interactive lectures: Effective teaching and learning in lectures using wireless networks

Among the severe instructional shortcomings of lectures is their lack of interactivity. To overcome these problems, the learning environment of the interactive lecture is introduced, in which students and lecturer interact by using mobile computers in a wireless network. In an experimental study, 44 students participated in interactive and in conventional lecture meetings. A quiz service that allowed question to be posted, students’ answers to be evaluated, and the results to be presented graphically, was implemented on mobile computers. The participants rated the interactive condition better, also reporting higher levels of attention, activity and perceived learning success for this condition. Objective measures indicated a slight but insignificant difference toward better learning results in the interactive condition.     

Measurement of CH4-concentration in HMDSO-containing process plasmas by quantum cascade laser absorption spectroscopy

For thin film deposition or plasma etching often organic precursors are used in the process plasma and related transient species are formed. In general it is not possible to measure the converted quantity of these precursors directly. In the present work we have used a special laser absorption spectroscopy to investigate characteristic molecular lines in the plasma to determine the concentration of stable organic molecules. Quantum cascade laser absorption spectroscopy (QCLAS) is a rather new technique for the precise measurement of absolute molecule concentrations. QCL’s can be operated at room temperature. They emit light within the mid infrared and have similar spectroscopic characteristics to Tunable Diode Lasers (TDL). The commercially available system Q-MACS (Quantum Cascade Laser Measurement and Control System) offers a solid platform for the measurement of absolute molecule concentrations in plasmas and gas mixtures. The used Q-MACS is due to its laser characteristics particularly well suitable for determination of the concentrations of acetylene and methane. Molecular concentrations of methane were measured in hexamethyldisiloxane (HMDSO) containing plasmas, too. The methane concentration was found to depend on rf power and HMDSO flow.     

PtRu nanoparticles supported on nitrogen-doped multiwalled carbon nanotubes as catalyst for methanol electrooxidation

Nitrogen-doped carbon nanotubes (N-CNT) obtained by plasma treatment were compared to the conventional acid-treated carbon nanotubes (O-CNT) as catalyst support for platinum-ruthenium (PtRu) nanoparticles in the anodic oxidation of methanol in direct methanol fuel cells. PtRu catalysts were prepared by an impregnation-reduction method from chloride precursors with metal loadings of 20 wt.%, and were characterised by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy and electrochemical methods. Voltammetry and chronoamperometry studies showed that the performance of PtRu/N-CNT was significantly higher compared to PtRu/O-CNT and also to the commercial E-TEK PtRu/C catalyst, indicating that N-CNT are an interesting support material for fuel cell electrocatalyst. Nitrogen plasma treatment produced pyridinic and pyrrollic species on the CNT surface, which acts as the anchoring sites for the deposition of PtRu particles. A mechanism for the deposition of PtRu on N-CNT is tentatively proposed and discussed.     

Characterization of polymer inks for drop-on-demand printing systems

This paper presents a detailed study on the properties of different polymer inks based on poly(3,4ethylenedioxythiophene)/polystyrenesulfonate regarding their processability in an experimental piezo driven drop-on-demand (DoD) micro-feeding system. Based on the rheological properties of the used inks and the mechanical properties of the printing system characteristic values are derived which allow to predict the processability of polymer inks in a given printing system. Beside the printability the influence of different polymer inks on the electrical characteristics of printed organic field effect transistors is investigated.     

Spatially resolved thermal probe measurement for the investigation of the energy influx in an rf-plasma

The total energy influx for a typical radiofrequency process plasma has been measured by means of a simple thermal probe. The procedure is based on the measurement of temporal slope of the substrate temperature during the plasma process. A substrate dummy which is thermally isolated and inserted into the plasma at substrate position served as thermal probe. It can be moved in vertical and horizontal directions in order to measure the different energy influxes and their topology in the reactor vessel. The knowledge of the spatial distribution is important for coating or sputtering processes.Different contributions to the total energy influx can be identified by different orientation of the thermal probe. If the thermal probe is orientated to the rf-electrode (“down”) the energy influx is much higher than in the opposite direction. This difference can be explained by an additional influx due to the secondary electron emission from the powered rf-electrode.     

Simple new formulae for efficiency and mean temperature difference in heat echangers

The well-known formulae for efficiency and mean temperature difference of a heat exchanger as functions of its numbers of transfer units, or dimensionless lengths, can be written in a more compact form by introducing the auxiliary function φ(x) = x/(1 – e^?x). The resulting new formulae show a number of advantages: They are shorter, easier to memorize, and in many cases the limiting values can be seen more directly. They may therefore contribute to easier and faster heat exchanger design, and to reduced probability of errors in the relevant calculations.     

Aminofunctional polyethers: smart materials for applications in solution and on surfaces

In recent years, biocompatible polyethers with multi‐aminofunctionality have been used for a variety of applications in different fields. Both established and recently developed synthesis strategies for such polymers and applications as stimuli‐responsive materials, non‐viral vectors, shell crosslinked micelles and for surface functionalization are reviewed. The intriguing potential of such materials is due to both polyether and polyamine components and can thus be readily tuned by the copolymer microstructure and composition. © 2013 Society of Chemical Industry