Mathematical modelling of mass transfer in the concentration polarisation layer of flat‐sheet membranes during clarification of pomegranate juice

Evaluation of membrane clarification of pomegranate juice showed that a cake layer is created at the beginning of the process. This evaluation was used as the basis for modelling the solute concentration in the concentration polarisation layer to control the fouling of the membrane. The model of changes in concentration as a function of time and distance (in its dimensionless form) was solved numerically using the Forward‐Time/Central‐Space (FTCS) method. Programming was performed using MATLAB software, and the predicted concentration on the membrane surface was compared with experimental data; the prediction fit well with the experimental data. The model showed that the solute concentration increased as distance to the membrane surface decreased, time increased, transmembrane pressure increased and velocity decreased. Also, the model matched the experimental data in that it showed the cake layer to be created in the early stages of the membrane clarification process.     

Effects of high pressure treatment on glycolytic enzymes of Lactococcus lactis subsp. lactis,Streptococcus thermophilus and Lactobacillus acidophilus

High pressure processing (HPP) reduces the glycolytic activity of lactic acid bacteria (LAB) and provides a means to control further production of acidic metabolites in fermented dairy products during storage. However, there is limited information on the effects of HPP on specific enzymes of dairy starter bacteria responsible for the metabolism of lactose. The aim of this study was to determine pressure-induced inactivation of glycolytic enzymes in Lactococcus lactis subsp. lactis C10, Streptococcus thermophilus TS1 and Lactobacillus acidophilus 2400. Cultures were grown for 16 h in M17 or MRS broth containing 5% (w/v) lactose at pH 6.5 (maintained by addition of 10 M NaOH). The cells were harvested by centrifugation, washed and resuspended in 100 mM phosphate buffer (pH 6.5) and pressure-treated at 300 and 600 MPa (≤ 22 °C, 5 min). The ability of pressure-treated resting cells of Lactococcus, incubated with 5% (w/v) lactose at 30 °C, to ferment lactose was evaluated by determining titratable acidity (TA) during incubation. The activities of phospho-β-galactosidase (P-β-gal), β-galactosidase (β-gal) and lactate dehydrogenase (LDH) were determined in cell-free extracts of untreated and pressure-treated cells. Resting cells of Lactococcus treated at 600 MPa had a substantially lower rate of acidification than the controls and those treated at 300 MPa. Both P-β-gal and β-gal were significantly inactivated (p < 0.01) in the starter cultures treated at 300 or 600 MPa. The LDH in Lactococcus and Lactobacillus was highly resistant to pressure treatment at 300 MPa. In contrast, the LDH in Streptococcus was almost completely inactivated at ≥ 300 MPa.Industrial relevanceContinuing production of acidic metabolites in fermented dairy products during storage can be a technological challenge that adversely affects product quality. The current study demonstrates that high pressure processing (HPP) offers the potential of controlling this problem by inactivation of glycolytic enzymes in various mesophilic and thermophilic starter cultures. The findings of this research will assist in establishing optimised operating parameters for HPP treatment of cultured products to extend shelf-life, by reducing acid production during storage.     

Polar compounds distribution of sunflower oil as affected by unsaponifiable matters of Bene hull oil (BHO) and tertiary-butylhydroquinone (TBHQ) during deep-frying

Total polar compounds (TPC) contents of the sunflower oil (SFO) increased linearly (R² > 0.99) with frying time. At the same concentration (100 ppm), the increase rate of the TPC content for the SFO containing the unsaponifiable matters (USM) of the Bene hull oil (BHO) was lower than that for the SFO containing the tertiary-butylhydroquinone (TBHQ). The TPC analysis by high-performance size-exclusion chromatography allowed the separation and quantification of triglyceride polymers (TGP), triglyceride dimers (TGD), oxidised triglyceride monomers (oxTGM), diglycerides (DG), and free fatty acids (FFA) during frying. The ability of the USM to resist the TGP formation was higher than that of the TBHQ. The USM and TBHQ showed lower influences on the changes in TGD and oxTGM contents, as well as there was an effectiveness better for the USM than for the TBHQ. The increase rate of DG and FFA contents more effectively decreased by the USM rather than by the TBHQ.     

Extraction of ferulic acid from sugar beet pulp by alkaline hydrolysis and organic solvent methods

Extraction of ferulic acid from sugar beet pulp was carried out using three extraction solvents, sodium hydroxide (0.5, 1, 2 M), methanol and their mixture (alkaline methanolic solvent). The Ferulic acid extracted by each solvent was identified and quantified by HPLC method and the effects of solvent type, concentration and reaction time on ferulic acid solubilisation were assessed. There were differences in the contents of products extracted in the experiment conditions. The minimum amount of ferulic acid was obtained from methanolic extract while the highest concentrations (957.4 mg/L ferulic acid) were obtained employing the highest NaOH concentration (2 M), and reaction time (12 h), so phenolic compounds are better released with alkaline hydrolysis than in methanol conditions. Finally a simple procedure for the purification of ferulic acid from the alkaline extracts is presented and evaluated by FT-IR spectrum.     

A quantitative approach to study solid state phase coarsening in solder alloys using combined phase-field modeling and experimental observation

In the present work, a quantitative phase-field approach is introduced to study the phase-coarsening phenomena in solder alloys, Pb-Sn alloy here. The most important part of this work is to introduce a simple and versatile approach to quantify the experimental and simulation data, without putting into difficulties corresponding to the stochastic nature of phenomenon, in order to compute unknown physical data required to perform numerical simulation. For this purpose, at first, the evolution of microstructure vs. time is studied experimentally by the conventional optical microscopy. Then, unknown physical data, the interface mobility here, is computed by fitting the time evolution of the total interface perimeter of the simulation results to that of the experimental data. In fact, by this approach, the physical data is computed such that it will be applied to predict reality in the subsequent simulations, i.e., the presented method can be accounted as the calibration of the corresponding mathematical model and numerical method. The validity of the presented approach is supported by comparing simulation data to experimental ones.     

Bimetal cup hydroforming of Al/St and Cu/St composites: Adaptive finite element analysis and experimental study

Journal of Mechanical Science and Technology - An adaptive Finite element analysis (FEA) was proposed in this paper for the industrial design of bimetal conical-cylindrical cup hydroforming....     

Designing a nuclear battery based on the Mo-99 radioactive source soluble in water and aqua regia in order to use in early tests

Today, millions of electrocommunication, electric, medical, and industrial devices use battery. Batteries with long life and high energy density seem to be essential in medical, military, oil and mining, aerospace areas as well as conditions in which access is difficult and in situations where replacement or recharging of battery is costly.In this regard, the use of radiation energy resulting from radioactive materials and its conversion to electric energy can be effective in making batteries. In the present study,various Mo-99 radioisotope values with a half-life of 65.98 h were used as a soluble radioactive source in two materials of water and aqua regia. Then, by comparing the results of the Monte Carlo simulations program MCNPX for these two solutions, it was found that when the water is used instead of aqua regia(for idealization), the values of the superficial current of electrons, the volumetric flux of electrons, and the deposited energy in the volume containing the radioactive solution increased by 10.80, 4.10,and 13.80%, respectively. Also, the short-circuit current and energy conversion efficiency of this battery with a concentration of 0.01 molar, Mo-99 dissolved in the aqua regia are 0.79μA and 16.47%, respectively.     

Reducing of heat loss of rubber compound using natural zeolite filler: effect of partially substitution of fillers on compound properties

The main objective of this work was reducing the heat loss of styrene butadiene rubber by partial substitution of carbon black with natural zeolite as a filler. Reducing the usage of carbon black in the rubber industry is a good strategy to decrease fossil fuel usage and global warming. There are different mineral fillers like silica and clay to be used instead of carbon black. Effect of application of natural zeolite on reducing the heat loss of rubber compound based on SBR was investigated by melt mixing of natural zeolite in rubber matrix in an internal mixer. Natural zeolite was selected as 5, 10, 15, and 20 phr. Carbon black was partially substituted with zeolite and the effect of natural zeolite content and structure on different aspects of the compound including heat buildup, hardness, elongation, and modulus were evaluated. It was shown that although cross-link density and mechanical properties of the compounds decreased a little, but a significant improvement was observed in the fatigue resistance of the compounds beside a favorable decrease in the heat buildup and abrasion loss with an increase in the natural zeolite loading. The rate of improvement in properties was slowed down at zeolite contents higher than 5 phr.