Bridging TiO2 nanoparticles using graphene for use in dye‐sensitized solar cells

The use of graphene to bridge TiO₂ particles in the photoanode of dye‐sensitized solar cell for reduced electrical resistance has been investigated. The difficulty in dispersing graphene in TiO₂ paste was overcome by first dispersing graphene oxide (GO) into the TiO₂ paste. The GO was then reduced to graphene after the sintering of TiO₂. This is shown through transmission electron microscopy and X‐ray photoelectron spectroscopy analysis. Cell performance was evaluated using a solar simulator, incident photon to electron conversion efficiency, intensity modulated photocurrent/photovoltage spectroscopy under blue light, and electrochemical impedance spectroscopy. Depending on the amount of graphene in the photoanode, the cell performance was enhanced to different degrees. A maximum increase of 11.4% in the cell efficiency has been obtained. In particular, the inclusion of graphene has reduced the electron diffusion time by as much as 23.4%, i.e. from 4.74 to 3.63 ms and increased the electron lifetime by as much as 42.3%, i.e. from 19.58 to 27.85 ms. Copyright © 2014 John Wiley & Sons, Ltd.     

Coupled nanowire-based hybrid plasmonic nanocavities on thin substrates

We theoretically analyze nanowire-based hybrid plasmonic nanocavities on thin substrates at visible wavelengths. In the presence of thin suspended substrates, the hybrid plasmonic modes, formed by the coupling between a metal nanowire and a dielectric nanowire with optical gain, exhibit negligible substrate-mediated characteristics and overlap better with the gain region. Consequently, the confinement factor of the guided hybrid modes is enhanced by more than 42%. However, the presence of significant mirror loss remains the main challenge to lasing. By adding silver coatings with a sufficient thickness range on the two end facets, we show that the reflectivity is substantially enhanced to above 50%. For a coating thickness of 50 nm and cavity length of about 4 μm, the quality factor is above 100.     

Cathodoluminescence and Field-Emission Properties of β-Ga2O3 Nanobelts

β-Ga₂O₃ nanobelts were synthesized using a vapor transport process in a controlled ambient. Structural characterization revealed that the as-synthesized samples consisted of monoclinic β-Ga₂O₃ nanobelts, and the presence of gallium-associated defects was verified using cathodoluminescence (CL). The formation of gallium-associated defects was explained by the insufficiency of the supply of cations, generating gallium vacancies on the (010) facet during growth. Furthermore, field-emission measurements indicated that β-Ga₂O₃ nanobelts exhibited defect-related electron emission. The turn-on fields of β-Ga₂O₃ nanobelts increased significantly with the degree of structural defects. For a sample prepared under 15% ambient oxygen, Fowler–Nordheim (F–N) analysis revealed two distinct field-enhancement factors of 1194 and 276, respectively. A correlation between field emission and structural defects was proposed. The experimental results demonstrate the presence of gallium-associated defects, which behave as electron traps, degrading the electron field-emission properties of β-Ga₂O₃ nanobelts.     

Phototemtide A,a Cyclic Lipopeptide Heterologously Expressed from Photorhabdus temperata Meg1, Shows Selective Antiprotozoal Activity

A new cyclic lipopeptide, phototemtide A ( 1 ), was isolated from Escherichia coli expressing the biosynthetic gene cluster pttABC from Photorhabdus temperata Meg1. The structure of 1 was elucidated by HR-ESI-MS and NMR experiments. The absolute configurations of amino acids and 3-hydroxyoctanoic acid in 1 were determined by using the advanced Marfey's method and comparison after total synthesis of 1 , respectively. Additionally, three new minor derivatives, phototemtides B–D ( 2 – 4 ), were identified by detailed HPLC–MS analysis. Phototemtide A ( 1 ) showed weak antiprotozoal activity against Plasmodium falciparum, with an IC₅₀ value of 9.8 μm . The biosynthesis of phototemtides A–D ( 1 – 4 ) was also proposed.     

Spark Parameter Monitoring Feedback System for Preparation of Nanosilver Colloid in EDM

This study developed a system monitoring the electric discharge machine's (EDM) discharge energy and success rate to replace conventional oscilloscope observation. By using logic circuit, the signals are transmitted to the PC monitoring platform in order to display the discharge success times, discharge success rate, and electrode's consumption energy. The advantage of the proposed system is the capability to observe real-time discharges and record the experimental conditions, as well as optimize the discharge parameter settings. The experimental results suggest that, in the preparation of nanosilver colloid, the cost-performance of T_on–T_off at 10–100 µs is the optimal setting. The monitoring system also can take advantage of the discharge success rate to control the energy consumption of the electrode to obtain the standardization of products. The results suggest that, while discharge success rate, electrode's weight loss and wavelength of the absorption peak are considerably accurate, but concentration accuracy is relatively poor. The discharge success rate monitoring system is an innovative method that can help to realize electric discharge processing, optimize product quality, and it may be a powerful processing tool in the future.     

Design of a double microprocessor‐based on‐line process control system

Abstract

A numerical technique for integrating the full Navier‐Stokes and diffusion equations through an initial value problem has been used to investigate the time development of a line buoyant source issuing in a density‐stratified environment. The basic physical features and some structures of the interactions of the motion at the intermediate mixing region are obtained. Results show that the stratification tends to inhibit the flow development of the buoyant source and to encourage the formation of a recirculatory vortex on the lower region near the source and the upper region.     

Air pollution,economic spillovers,and urban growth in China

This paper empirically tests the interactive effects of air pollution and economic spillovers in Chinese cities from 2003 to 2010. The results show that Chinese cities benefit from the economic spillovers from surrounding cities, but bear the costs of negative air pollution externalities created by neighboring cities. We use wind direction and the administrative boundaries of provinces to disentangle possible multicollinearity between air pollution emissions and economic spillovers across cities. However, the results could not reject the growth-restricting effects of air pollution from neighboring cities. The results imply that the development of a city surrounded by polluters is likely to be constrained.