Molecular weight distribution of polyethylene catalyzed by Ziegler–Natta catalyst supported on MgCl2 doped with AlCl3

Ti‐based Ziegler–Natta catalysts supported on MgCl₂ doped with AlCl₃ were prepared by the reaction of MgCl₂/AlCl₃–ethanol adduct with TiCl₄. No AlCl₃ crystallites were found in the AlCl₃‐doped catalysts by WAXD analysis, suggesting that AlCl₃/MgCl₂ solid solution was formed. The effect of doping on the catalyst performance in ethylene polymerization was investigated. The results showed that the catalysts based on AlCl₃‐doped MgCl₂ support exhibited a slightly higher activity than did the MgCl₂‐supported catalyst and the molecular weight distribution (MWD) of polyethylene (PE) markedly increased (from 10.8 to 47.9) with the increase of AlCl₃ content in catalysts. The changes in catalyst's active center distribution were studied based on nonlinear fitting of the polymer GPC curves by multiple Flory functions. It was found that increase of types of active centers by introducing AlCl₃ into the support should be responsible for the broadening of MWD of PE. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 1768–1772, 2006     

高校教师的隐性流失

本文分析了当前高校教师的隐性流失的严重性及流失形式的多样性,认为这种现象严重浪费了教育资源,影响了教学质量,毒化了校园环境和社会环境,必须采取坚决措施才能取得成效,制止流失.     

丙交酯的合成

以DL－乳酸为原料在催化剂存在下，加热、减压脱水合成了DL－丙交酯，研究了温度、压力、反应时间等反应条件对丙交酯产率的影响，用IR等分析测试仪器对丙交酯进行了表征。     

Allelopathic Potential and Chemical Constituents of Volatile Oil from Ageratum conyzoides

Fresh leaves and volatile oil of the important weed Ageratum conyzoides in south China were highly inhibitory to seedling growth of various cultivated crops, especially in an adverse habitat. The constituents of the volatile oil were analyzed by GC-MS. Eleven components were identified and six main components, precocene I, precocene II, 3,3-dimethyl-5-tert-butylindone, -caryophyllene, -bisabolene, and fenchyl acetate, were isolated by means of column chromatography. Precocene I, precocene II, -caryophyllene, and 3,3-dimethyl-5-tert-butylindone inhibited seedling growth of acceptor plants. Inhibitory activity of the volatile oil was more intense than that of the pure components. Fenchyl acetate and -bisabolene have no inhibitory activity, but when mixed with precocene II, they increased the inhibitory activity to growth of acceptor seedling plants. Experiments show that allelopathic synergism exists among allelochemicals of Ageratum conyzoides.     

一种结合主题模型的推荐算法

针对传统协同过滤推荐算法存在的冷启动、数据稀疏以及相似度度量的准确性问题,基于LDA主题模型对文本隐式主题挖掘的有效性和KL散度在主题分布相似性度量的准确性,提出了结合LDA主题模型的矩阵分解推荐算法。首先,利用改进的LDA算法输出项目-主题分布,并用困惑度作为主题数设置的修正函数;然后分别基于余弦相似度和KL散度计算得到项目相似度矩阵,将得到的相似度矩阵结合原评分训练集输出预评分,再将预评分填充到训练集;最后将训练集输入ALS矩阵分解算法得到推荐结果。通过MovieLens数据集的实验结果表明,该算法在不同隐式参数设定下均能得到比ALS推荐算法以及更小的预测误差,并且最优预测误差小于传统推荐算法。该实验说明了通过集成LDA主题模型的ALS算法效果要优于其他推荐算法。     

基于规则网格的层次化布料动态模拟方法

在布料动态模拟仿真过程中,收敛速度和模拟效率是两个核心指标,可以很好的反应布料在动态过程中的模拟效果。针对布料动态模拟中的收敛速度慢、模拟效率低的问题,提出了一种基于规则网格的层次化模拟方法,实现了基于位置的层次化动态模拟。在该方法中,利用层次化思想在原始网格的基础上构建层次化约束网格,在这个过程中,可以采用不同的决策函数对网格进行精简,构造出更加满足目标要求的约束网格,在构造完成后利用提出的权值关联模型对各层次进行再矫正。在模拟过程中,原始网格利用层次化约束网格从最粗层到最精细层进行收敛矫正,有效避免了传统为提高收敛速度而单一的增加约束矫正迭代次数的问题。为了检验模拟性能,布料在周期钟摆风场下进行了实验。实验表明,在基于规则网格的层次化方法模拟下,能很好的解决传统模拟的约束震荡问题,并且效率高,稳定性好。     

基于CMFS-MIC特征选择的跳频电台个体识别方法

针对跳频电台细微特征集中存在冗余特征等导致电台识别时存在计算量大、识别准确率低等问题,提出了一种基于CMFS-MIC特征选择的跳频电台个体识别方法。首先计算采集到的各个跳频电台信号样本的细微特征集,然后采用关联信息熵度量特征子集的组合效应,兼顾考虑特征间的关联关系和冗余关系对各个特征进行降序排序。在此基础上,采用最大信息系数度量的近似马尔可夫毯方法删除冗余特征,实现对特征子集进行优化和降维。最后,设计了投票组合分类器实现对4部跳频电台信号的识别。仿真结果表明,本文算法具有更高的分选识别率。     

Volume phase transition of polyelectrolyte gels in dimethyl sulfoxide/ tetrahydrofuran mixtures

Copolymer gels were prepared from 2-(acrylamido)-2-methylpropanesulfonic acid (AMPS), N,N-dimethylacrylamide (DMAA, comonomer) and N,N′-methylenebis(acrylamide) (BIS). The mole fraction of AMPS were 0.2674 and 0.4318, respectively, with the same BIS mole fraction of 0.013. These gels with counterions H⁺, Na⁺, and K⁺ were swollen at 25°C in mixtures of dimethyl sulfoxide (DMSO) and tetrahydrofuran (THF). A volume phase transition was observed at the THF volume fraction of about 0.58, indicating that the volume phase transition in a polyelectrolyte gel occurs when the medium polarity decreases sufficiently for ion-pair formation. On changing the counterion, the fraction of DMSO in the solvent mixture which is required to initiate swelling decreases in the order Na⁺, H⁺, and K⁺, the same as for counterion condensation in identical gels.     

Nickel foam and carbon felt applications for sodium polysulfide/bromine redox flow battery electrodes

The first use of nickel foam (NF) as electrocatalytic negative electrode in a polysulfide/bromine battery (PSB) is described. The performance of a PSB employing NF and polyacrylonitrile (PAN)-based carbon felt (CF) as negative and positive electrode materials, respectively, was evaluated by constant current charge-discharge tests in a single cell. Charge/discharge curves of the cell, positive and negative electrodes show that the rapid fall in cell voltage is due to the drop of positive potential caused by depletion of Br₂ dissolved in the catholyte at the end of discharge. Cell voltage efficiency was limited by the relatively high internal ohmic resistance drop (iR drop). Polarization curves indicated that both NF and CF have excellent catalytic activity for the positive and negative redox reactions of PSB. The average energy efficiency of the single cell designed in this work could be as high as 77.2% at 40 mA cm⁻² during 48 charge-discharge cycles.     

用差示扫描量热法优化PVC-U异型材加工工艺

采用差示扫描量热(DSC)法测定PVC-U异型材塑化度,以其塑化度与型材物理力学性能的关系来优化PVC-U异型材的加工工艺。